Single Crystal Growth at High Pressure (SOLID STATE CHEMISTRY-Multicomponent Materials)

Single crystals of a spin-1/2 Heisenberg alternating chain compound, high pressure phase of (VO)2P2O7 , was grown by slowly cooling the melt at 3 GPa. Powder XRD study at high pressure using synchrotron radiation was performed in advance to observe the formation and the melting of this compound

First emergence of cold accretion and supermassive star formation in the early universe

We investigate the first emergence of the so-called cold accretion, the accretion flows deeply penetrating a halo, in the early universe with cosmological N-body/SPH simulations. We study the structure of the accretion flow and its evolution within small halos with $\lesssim 10^8~{\rm M}_\odot$ with sufficiently high spatial resolutions down to $\sim 1 \ {\rm pc}$ scale. While previous studies only follow the evolution for a short period after the primordial cloud collapse, we follow the long-term evolution until the cold accretion first appears, employing the sink particle method. We show that the cold accretion emerges when the halo mass exceeds $\sim 2.2\times 10^7 \ {\rm M}_\odot\left\{\left(1+z\right)/15 \right\}^{-3/2}$, the ${\it minimum}$ halo masses above which the accretion flow penetrates halos. We further continue simulations to study whether the cold accretion provides the dense shock waves, which have been proposed to give birth to supermassive stars (SMSs). We find that the accretion flow eventually hits a compact disc near the halo centre, creating dense shocks over a wide area of the disc surface. The resulting post-shock gas becomes dense and hot enough with its mass comparable to the Jeans mass $M_{\rm J}\sim 10^{4-5} \ {\rm M}_\odot$, a sufficient amount to induce the gravitational collapse, leading to the SMS formation.Comment: 17 pages, 17 figures, MNRAS submitte

Anomalous momentum dependence of the multiband electronic structure of FeSe_1-xTe_x superconductors induced by atomic disorder

When periodicity of crystal is disturbed by atomic disorder, its electronic state becomes inhomogeneous and band dispersion is obscured. In case of Fe-based superconductors, disorder of chalcogen/pnictogen height causes disorder of Fe 3d level splitting. Here, we report an angle-resolved photoemission spectroscopy study on FeSe_1-xTe_x with the chalcogen height disorder, showing that the disorder affects the Fe 3d band dispersions in an orbital-selective way instead of simple obscuring effect. The reverse of the Fe 3d level splitting due to the chalcogen height difference causes the splitting of the hole band with Fe 3d x^2-y^2 character around the Gamma point.Comment: 5 pages, 4 figure