2,614 research outputs found
Radiation Damping in the Photoionization of Fe^{14+}
A theoretical investigation of photoabsorption and photoionization of
Fe^{14+} extending beyond an earlier frame transformation R-matrix
implementation is performed using a fully-correlated, Breit-Pauli R-matrix
formulation including both fine-structure splitting of strongly-bound
resonances and radiation damping. The radiation damping of
resonances gives rise to a resonant photoionization cross section that is
significantly lower than the total photoabsorption cross section. Furthermore,
the radiation-damped photoionization cross section is found to be in good
agreement with recent experimental results once a global shift in energy of
eV is applied. These findings have important implications.
Firstly, the presently available synchrotron experimental data are applicable
only to photoionization processes and not to photoabsorption; the latter is
required in opacity calculations. Secondly, our computed cross section, for
which the L-shell ionization threshold is aligned with the NIST value, shows a
series of Rydberg resonances that are uniformly 3-4 eV
higher in energy than the corresponding experimental profiles, indicating that
the L-shell threshold energy values currently recommended by NIST are likely in
error.Comment: 4 pages, 1 figures, and 2 table
Isotope effect in quasi-two-dimensional metal-organic antiferromagnets
Although the isotope effect in superconducting materials is well-documented,
changes in the magnetic properties of antiferromagnets due to isotopic
substitution are seldom discussed and remain poorly understood. This is perhaps
surprising given the possible link between the quasi-two-dimensional (Q2D)
antiferromagnetic and superconducting phases of the layered cuprates. Here we
report the experimental observation of shifts in the N\'{e}el temperature and
critical magnetic fields (; ) in a Q2D organic molecular antiferromagnets on
substitution of hydrogen for deuterium. These compounds are characterized by
strong hydrogen bonds through which the dominant superexchange is mediated. We
evaluate how the in-plane and inter-plane exchange energies evolve as the
hydrogens on different ligands are substituted, and suggest a possible
mechanism for this effect in terms of the relative exchange efficiency of
hydrogen and deuterium bonds
Unusual magnetic-field dependence of partially frustrated triangular ordering in manganese tricyanomethanide
Manganese tricyanomethanide, Mn[C(CN)3]2, consists of two interpenetrating
three-dimensional rutile-like networks. In each network, the tridentate C(CN)3-
anion gives rise to superexchange interactions between the Mn2+ ions (S=5/2)
that can be mapped onto the "row model" for partially frustrated triangular
magnets. We present heat capacity measurements that reveal a phase transition
at T_N = 1.18K, indicative of magnetic ordering. The zero-field magnetically
ordered structure was solved from neutron powder diffraction data taken between
0.04 and 1.2 K. It consists of an incommensurate spiral with a temperature
independent propagation vector Q=(2Q 0 0)=(+/-0.622 0 0), where different signs
relate to the two different networks. This corresponds to (+/-0.311 +/-0.311 0)
in a quasi-hexagonal representation. The ordered moment mu=3.3mu_B is about 2/3
of the full Mn2+ moment. From the values of T_N and Q, the exchange parameters
J/k = 0.15 K and J'/J = 0.749 are estimated. The magnetic-field dependence of
the intensity of the Bragg reflection, measured for external fields
H||Q, indicates the presence of three different magnetic phases. We associate
them with the incommensurate spiral (H < 13.5 kOe), an intermediate phase (13.5
kOe 16 kOe)
proposed for related compounds. For increasing fields, Q continuously
approaches the value 1/3, corresponding to the commensurate magnetic structure
of the fully frustrated triangular lattice. This value is reached at H_c = 19
kOe. At this point, the field-dependence reverses and Q adopts a value of 0.327
at 26 kOe, the highest field applied in the experiment. Except for H_c, the
magnetic ordering is incommensurate in all three magnetic phases of
Mn[C(CN)3]2.Comment: accepted for publication in J. Phys.: Condens. Matte
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