Particle to Gas Heat Transfer in a Circulating Fluidized Bed Riser

The main objective of this study was to measure the heat transfer from particle to gas in a dilute CFB riser ( 0.8 ) and to derive a predictive equation for the local particle-gas heat transfer coefficient. This coefficient was found to be a strong function of the particle velocity, concentration and length of the heat transfer section. Accordingly, a new correlation in terms of these parameters is proposed

Mass transfer coefficient for drying of moist particulate in a bubbling fluidized bed

Experiments on drying of moist particles by ambient air were carried out to measure the mass transfer coefficient in a bubbling fluidized bed. Fine glass beads of mean diameter 125?µm were used as the bed material. Throughout the drying process, the dynamic material distribution was recorded by electrical capacitance tomography (ECT) and the exit air condition was recorded by a temperature/humidity probe. The ECT data were used to obtain qualitative and quantitative information on the bubble characteristics. The exit air moisture content was used to determine the water content in the bed. The measured overall mass transfer coefficient was in the range of 0.0145–0.021?m/s. A simple model based on the available correlations for bubble-cloud and cloud-dense interchange (two-region model) was used to predict the overall mass transfer coefficient. Comparison between the measured and predicted mass transfer coefficient have shown reasonable agreement. The results were also used to determine the relative importance of the two transfer regions

Characteristics of sewage sludge biochar produced at a wide range of pyrolysis temperatures

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Mass transfer in fluidized bed drying of moist particulate

Bubbling fluidized bed technology is one of the most effective mean for interaction between solid and gas flow, mainly due to its good mixing and high heat and mass transfer rate. It has been widely used at a commercial scale for drying of grains such as in pharmaceutical, fertilizers and food industries. When applied to drying of non-pours moist solid particles, the water is drawn-off driven by the difference in water concentration between the solid phase and the fluidizing gas. In most cases, the fluidizing gas or drying agent is air. Despite of the simplicity of its operation, the design of a bubbling fluidized bed dryer requires an understanding of the combined complexity in hydrodynamics and the mass transfer mechanism. On the other hand, reliable mass transfer coefficient equations are also required to satisfy the growing interest in mathematical modelling and simulation, for accurate prediction of the process kinetics. This chapter presents an overview of the various mechanisms contributing to particulate drying in a bubbling fluidized bed and the mass transfer coefficient corresponding to each mechanism. In addition, a case study on measuring the overall mass transfer coefficient is discussed. These measurements are then used for the validation of mass transfer coefficient correlations and for assessing the various assumptions used in developing these correlations

A hydrodynamic model for biomass gasification in a circulating fluidized bed riser

This study presents a three-dimensional Computational Fluid Dynamic (CFD) model and experimental measurements of the hydrodynamics in the riser section of a Circulating Fluidized Bed (CFB) biomass gasifier consisting of a binary mixture of polydisperse particles. The model is based on multi-fluid (Eulerian-Eulerian) approach with constitutive equations adopted from the Kinetic Theory of Granular Flow (KTGF). The study first presents an assessment of the various options of the constitutive and closure equations for a binary mixture followed by sensitivity analysis of the model to the solution time step, cell size, turbulence and the alternative formulations of the granular energy equation. Accordingly, a robust and reliable hydrodynamic model is recommended and validated using conventional pressure measurements and Positron Emission Particle Tracking (PEPT) technique. Furthermore, the model predictions and experiments revealed evidence of the particle re-circulation within the lower part of the riser, which is an important feature contributing to rapid mass and heat transfer in a CFB gasifier. The present hydrodynamic model can be further developed; by incorporating appropriate reactions and heat transfer equations, in order to fully predict the performance and products of a CFB biomass gasifier

Management and potential application of desalination brine reject in CO2 capture and catalytic conversion processes

The current estimate of the worldwide production of desalination brine reject is 141.5 million m3 per day. Given its adverse environmental effects, research is underway to develop effective management methods. Resource recovery from brine is an option for reducing desalination costs, particularly when coupled with carbon dioxide capture to enhance profitability and environmental sustainability. This review assesses various brine management options, disposal costs, environmental impacts, state-of-the-art technologies for extracting valuable metals, and future research directions. The potential of combining mineral extraction with carbon dioxide sequestration is explored, with a view toward sustainable brine management. It is found that, while providing valuable mineral sources, global brine rejects could annually capture 236 million tons of CO2 through carbonation of Mg and Ca, equivalent to a 300 % reduction in current desalination-related CO2 emissions. The catalytic properties of desalination brine and its extract in the form of Mg and Ca carbonates or oxides offer another potential application of brine reject in industries such as biomass conversion, potentially generating additional income from the desalination process

Adsorption of dimethyl ether (DME) on zeolite molecular sieves

In recent years there has been growing interest in the use of dimethyl ether (DME) as an alternative fuel. In this study, the adsorption of DME on molecular sieves 4Å (Mol4A) and 5Å (Mol5A) has been experimentally investigated using the volumetric adsorption method. Data on the adsorption isotherms, heats of adsorption, and adsorption kinetic have been obtained and used to draw conclusions and compare the performance of the two adsorbents. Within the conditions considered, the adsorption capacity of Mol5A was found to be around eight times higher than the capacity of Mol4A. Low temperature adsorption and thermal pre-treatment of the adsorbents in vacuum were observed to be favourable for increased adsorption capacity. The adsorption isotherms for both adsorbent were fitted to the Freundlich model and the corresponding model parameters are proposed. The adsorption kinetic analysis suggest that the DME adsorption on Mol5A is controlled by intracrystalline diffusion resistance, while on Mol4A it is mainly controlled by surface layering resistance with the diffusion only taking place at the start of adsorption and for a very limited short time. The heats of adsorption were calculated by a calorimetric method based on direct temperature measurements inside the adsorption cell. Isosteric heats, calculated by the thermodynamic approach (Clasius-Clapeyron equation), have consistently shown lower values. The maximum heat of adsorption was found to be 25.9kJmol-1 and 20.1kJmol-1 on Mol4A and Mol5A, respectively; thus indicating a physisorption type of interactions