6 research outputs found
Unprecedented Transformation of a Vinylidene Ligand. Synthesis and ESR Characterization of a Paramagnetic Sigma-acetylide Complex of Rhodium(II)
No full textNucleophilic Properties and Electrochemistry of Five-coordinate Rhodium(I) Sigma-cyanide Complexes. Synthesis and Characterization of Stable Cis Hydride Cyanide Complexes of Rhodium(III)
No full textElectrochemistry as a Diagnostic Tool to Discriminate Between Classical M-(H2) and Nonclassical M-(H2) Structures Within a Famili of Dihydride and Dihydrogen Metal Complexes
No full textSigma-acetylide Complexes of Rhodium(I), Rhodium(II) and Rhodium(III). Correlation Between Electrochemical and Spectroscopic Parameters and d(Metal) *(Acetylide) Transfer
No full textUnprecedent solar photoextrusion of molecular hydrogen fron octahedral ruthenium (II) dihydrides: un easy acces to ortho-metalated species.
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SYNTHESIS, CHARACTERIZATION, AND ELECTROCHEMICAL BEHAVIOR OF MONO- AND BIMETALLIC RUTHENIUM AND RHENIUM ALLENYLIDENES BEARING MULTICONJUGATED ORGANIC SPACERS
No full textNovel monoallenylidenes of Ru and Re and homobimetallic Ru/Ru and heterobimetallic Ru/Re complexes bridged by multiconjugated aromatic organic spacers such as bianthracenylidene and biphenylene were obtained and characterized by conventional spectroscopic techniques and elemental analysis. Electrochemical measurements coupled to spectroelectrochemistry and EPR spectroscopy proved that in the bis(allenylidene) complexes an electronic communication is present between either the two allenylidene bridges or the two metal centers, enticing extended intramolecular electronic mobility
