VO₂/ZnO bilayer films with enhanced thermochromic property and durability for smart windows

VO_{2} films are widely considered as one of the most suitable material to act as smart windows. Although this system is able to function, the durability of the film has been an issue as the surface of the films may oxidize by converting V^{4+} to V^{5+}. To overcome this problem, attempt is made to coat the VO_{2} film with ZnO, which can assist by creating a resistance layer to prevent further oxidation of VO_{2}. Here, VO_{2}/ZnO bilayer film was prepared by a facile method comprised of spin-coating and dip-coating process and shows excellent durability, and in particular. the solar modulation efficiency (△T_{sol}) maintaining ca 89.9% (from 17.8% to 16.0%) after 300 days in a humid environment, however, the △T_{sol} of pure VO_{2} film is decreased from 11.8% to 4.1%. Also, the VO2/ZnO bilayer exhibits an enhanced thermochromic property of visible transmittance (T_{lum} = 55.7 ± 2.1%) and △T_{sol} (17.1 ± 1.4%) which is 1.49 times higher than that of pure VO2 film (△T_{sol} = 11.5 ± 0.4%). The enhancement in the thermochromic performance and durability is probably attributed to the anti-reflection and protection of ZnO layer. Therefore, this work can provide an effective way to optimize thermochromic property for practical application of VO_{2}-based smart windows

Fabrication and characteristics of flexible normally-off AlGaN/GaN HEMTs

In this paper, we present a method for removing a high electron mobility transistor (HEMT) silicon substrate using mechanical grinding and deep silicon etching technology and successfully transferred the epitaxial wafer to a PET substrate to achieve the flexible normally-off HEMT. By testing the output characteristics and transfer characteristics of the Si-substrate HEMT and PET-substrate HEMT, we have demonstrated that the PET-substrate HEMT has excellent performance and successfully achieved the mechanical flexibility. Furthermore, we analyzed the physical mechanisms of the change in PET-substrate and Si-substrate HEMT characteristics, as well as flexible HEMT performance under bent and flattened states. The flexible HEMT array demonstrates significant potential in integration with other flexible devices, such as GaN-based micro-LED arrays

Ginsenoside Rb1 Prevents H2O2-Induced HUVEC Senescence by Stimulating Sirtuin-1 Pathway

We have previously reported that Ginsenoside Rb1 may effectively prevent HUVECs from senescence, however, the detailed mechanism has not demonstrated up to now. Recent studies have shown that sirtuin-1 (Sirt1) plays an important role in the development of endothelial senescence. The purpose of this study was to explore whether Sirt1 is involved in the action of Ginsenoside Rb1 regarding protection against H2O2-induced HUVEC Senescence.Senescence induced by hydrogen peroxide (H2O2) in human umbilical vein endothelial cells (HUVECs) was examined by analyzing plasminogen activator inhibitor-1 (PAI-1) expression, cell morphology, and senescence-associated beta-galactosidase (SA-β-gal) activity. The results revealed that 42% of control-treated HUVECs were SA-β-gal positive after treatment by 60 µmol/L H2O2, however, this particular effect of H2O2 was decreased more than 2-fold (19%) in the HUVECs when pretreated with Rb1 (20 µmol/L) for 30 min. Additionally, Rb1 decreased eNOS acetylation, as well as promoted more NO production that was accompanied by an increase in Sirt1 expression. Furthermore, upon knocking down Sirt1, the effect of Rb1 on HUVEC senescence was blunted.The present study indicated that Ginsenoside Rb1 acts through stimulating Sirt1 in order to protect against endothelial senescence and dysfunction. As such, Sirt1 appears to be of particular importance in maintaining endothelial functions and delaying vascular aging

Atmosphere-Dependent Electron Relaxation of the Ag-Decorated TiO₂ and the Relations with Photocatalytic Properties

In the current research, the atmosphere effects on the photoinduced electron relaxations of the undecorated TiO2 and Ag-decorated TiO2 (Ag/TiO2) were carefully studied by means of the in situ photoconductance and diffuse reflection measurements. In pure N2 atmosphere, the results showed that the electron relaxation mainly occurs through the transfer to the residual O2, and the Ag nanoparticles form a fast electron transfer pathway. It was seen that the apparent activation energy of the electron transfer to O2 was greatly reduced by the Ag decoration. In the methanol-containing N2 atmosphere, the electron relaxation can still occur via the transfer to residual O2 in the case of the undecorated TiO2, while the relaxation mechanism changes for the Ag/TiO2 as the relaxations are decreased with the temperatures. It is possible that the methanol molecule adsorbed on the Ag/TiO2 perimeters could act as the bridge for the recombination of the holes and the electrons stored in the Ag nanoparticles. Reducing the Ag nanoparticle size from 15 nm to 3 nm can greatly increase the electron relaxations due to the increase in Ag dispersion and Ag/TiO2 interconnection. Although the electron transfer to O2 was increased, both the photocatalytic oxidations of acetone and isopropanol showed a decrease after the Ag decoration. The results indicated that the photocatalytic oxidation was not limited by the electron transfer to O2. The increased electron transfer to O2 contributed to the recombination around the Ag/TiO2 perimeters, and the photocatalytic activities were decreased

Spatially Varying Relationships between Land Subsidence and Urbanization: A Case Study in Wuhan, China

Land subsidence has become an increasing global concern over the past few decades due to natural and anthropogenic factors. However, although several studies have examined factors affecting land subsidence in recent years, few have focused on the spatial heterogeneity of relationships between land subsidence and urbanization. In this paper, we adopted the small baseline subset-synthetic aperture radar interferometry (SBAS-InSAR) method using Sentinel-1 radar satellite images to map land subsidence from 2015 to 2018 and characterized its spatial pattern in Wuhan. The bivariate Moran’s I index was used to test and visualize the spatial correlations between land subsidence and urbanization. A geographically weighted regression (GWR) model was employed to explore the strengths and directions of impacts of urbanization on land subsidence. Our findings showed that land subsidence was obvious and unevenly distributed in the study area, the annual deformation rate varied from −42.85 mm/year to +29.98 mm/year, and its average value was −1.0 mm/year. A clear spatial pattern for land subsidence in Wuhan was mapped, and several apparent subsidence funnels were primarily located in central urban areas. All urbanization indicators were found to be significantly spatially correlated with land subsidence at different scales. In addition, the GWR model results showed that all urbanization indicators were significantly associated with land subsidence across the whole study area in Wuhan. The results of bivariate Moran’s I and GWR results confirmed that the relationships between land subsidence and urbanization spatially varied in Wuhan at multiple spatial scales. Although scale dependence existed in both the bivariate Moran’s I and GWR models for land subsidence and urbanization indicators, a “best” spatial scale could not be confirmed because the disturbance of factors varied over different sampling scales. The results can advance the understanding of the relationships between land subsidence and urbanization, and they will provide guidance for subsidence control and sustainable urban planning

Spatially Varying Relationships between Land Subsidence and Urbanization: A Case Study in Wuhan, China

Land subsidence has become an increasing global concern over the past few decades due to natural and anthropogenic factors. However, although several studies have examined factors affecting land subsidence in recent years, few have focused on the spatial heterogeneity of relationships between land subsidence and urbanization. In this paper, we adopted the small baseline subset-synthetic aperture radar interferometry (SBAS-InSAR) method using Sentinel-1 radar satellite images to map land subsidence from 2015 to 2018 and characterized its spatial pattern in Wuhan. The bivariate Moran’s I index was used to test and visualize the spatial correlations between land subsidence and urbanization. A geographically weighted regression (GWR) model was employed to explore the strengths and directions of impacts of urbanization on land subsidence. Our findings showed that land subsidence was obvious and unevenly distributed in the study area, the annual deformation rate varied from −42.85 mm/year to +29.98 mm/year, and its average value was −1.0 mm/year. A clear spatial pattern for land subsidence in Wuhan was mapped, and several apparent subsidence funnels were primarily located in central urban areas. All urbanization indicators were found to be significantly spatially correlated with land subsidence at different scales. In addition, the GWR model results showed that all urbanization indicators were significantly associated with land subsidence across the whole study area in Wuhan. The results of bivariate Moran’s I and GWR results confirmed that the relationships between land subsidence and urbanization spatially varied in Wuhan at multiple spatial scales. Although scale dependence existed in both the bivariate Moran’s I and GWR models for land subsidence and urbanization indicators, a “best” spatial scale could not be confirmed because the disturbance of factors varied over different sampling scales. The results can advance the understanding of the relationships between land subsidence and urbanization, and they will provide guidance for subsidence control and sustainable urban planning

Electrospinning Preparation and Photocatalytic Activity of Porous TiO2 Nanofibers

Porous TiO2 nanofibers were prepared via a facile electrospinning method. The carbon nanospheres were mixed with the ethanol solution containing both poly(vinylpyrrolidone) and titanium tetraisopropoxide for electrospinning; and subsequent calcination of as-spun nanofibers led to thermal decomposition of carbon nanospheres, leaving behind pores in the TiO2 nanofibers. The morphology and phase structure of the products were investigated with scanning electron microscopy (SEM), transmission electron microscopy (TEM), and X-ray diffraction (XRD). Furthermore, the photocatalytic activity of porous TiO2 nanofibers was evaluated by photodecomposition of methylene blue under UV light. Results showed that the porous TiO2 nanofibers have higher surface area and enhanced photocatalysis activity, compared to nonporous TiO2 nanofibers