4,4′-(Ethene-1,2-diyl)dipyridinium bis­[4-(2-carboxy­benzo­yl)benzoate]

In the crystal structure of the title compound, C12H12N2 2+·2C15H9O5 −, the cation has site symmetry with the mid-point of C=C bond located on an inversion center. The two benzene rings of the anion are oriented at a dihedral angle 85.87 (6)°. In the crystal, inter­molecular O—H⋯O and N—H⋯O hydrogen bonds link the cations and anions into supra­molecular double chains, which are further connected into a three-dimensional network through inter­molecular C—H⋯O and π–π stacking between parallel pyridine rings [centroid–centroid distance = 3.4413 (12)Å] and between parallel benzene rings [centroid–centroid distance = 3.6116 (14)Å]

Local ventilation and wear response of working jackets with different fabric permeability

Purpose – An experimental study was conducted to investigate the local ventilation (the right arm, the chest and the back) and wear response of three types of working jackets in different conditions. The relationship between the local ventilation and its related wear response was also explored. The paper aims to discuss these issues. Design/methodology/approach – A clothing local ventilation measuring system was developed based on the steady state method to measure the local ventilation of the right arm, the chest and the back. Separate wear trials were conducted to determine the local skin temperature, local microclimate temperature and humidity, clothing local surface temperature, heart rate (HR), eardrum temperature and subjective perceptions. Findings – The results indicated that the back part of the jacket had the highest ventilation, followed by the chest and the arm. Fabric permeability affected the local ventilation of the arm and the chest more than on the back. Clothing local surface temperature was significantly related to garment regions but not to fabric permeability. Back ventilation and back surface temperature, arm or chest ventilation and local microclimate humidity of the arm or chest, HR and back ventilation, local ventilation of the arm or the chest and its related thermal sensation, had significant linear relationships. Originality/value – The research will help to understand the relationship between the air exchange of the microclimate and the wear response, and thus gives some suggestions on garment design or selection, especially for the working garments

Aqua­(2,2′-bipyrimidine-κ2 N,N′)(succin­ato-κ2 O 1,O 4)copper(II) dihydrate

In the crystal structure of the title compound, [Cu(C4H4O4)(C8H6N4)(H2O)]·2H2O, the CuII atom is chelated by a 2,2′-bipyrimidine (bpm) ligand and a succinate anion in the basal plane; a water mol­ecule in the apical position completes the slightly distorted square-pyramidal coordination geometry. Another carboxyl­ate O atom from an adjacent complex is located in the opposite apical direction, with a Cu⋯O distance of 2.706 (3) Å, and is not considered as a bridging atom. Extensive O—H⋯O and O—H⋯N hydrogen bonding is present in the crystal structure