Adsorption of Self-Assembled Rigid Rods on Two-Dimensional Lattices

Monte Carlo (MC) simulations have been carried out to study the adsorption on square and triangular lattices of particles with two bonding sites that, by decreasing temperature or increasing density, polymerize reversibly into chains with a discrete number of allowed directions and, at the same time, undergo a continuous isotropic-nematic (IN) transition. The process has been monitored by following the behavior of the adsorption isotherms for different values of lateral interaction energy/temperature. The numerical data were compared with mean-field analytical predictions and exact functions for noninteracting and 1D systems. The obtained results revealed the existence of three adsorption regimes in temperature. (1) At high temperatures, above the critical one characterizing the IN transition at full coverage Tc(\theta=1), the particles are distributed at random on the surface and the adlayer behaves as a noninteracting 2D system. (2) At very low temperatures, the asymmetric monomers adsorb forming chains over almost the entire range of coverage, and the adsorption process behaves as a 1D problem. (3) In the intermediate regime, the system exhibits a mixed regime and the filling of the lattice proceeds according to two different processes. In the first stage, the monomers adsorb isotropically on the lattice until the IN transition occurs in the system and, from this point, particles adsorb forming chains so that the adlayer behaves as a 1D fluid. The two adsorption processes are present in the adsorption isotherms, and a marked singularity can be observed that separates both regimes. Thus, the adsorption isotherms appear as sensitive quantities with respect to the IN phase transition, allowing us (i) to reproduce the phase diagram of the system for square lattices and (ii) to obtain an accurate determination of the phase diagram for triangular lattices.Comment: Langmuir, 201

Mathematical Models for Estimating the Risk of vCJD Transmission

We present two different simple models for vCJD transmission by blood transfusion. Both models indicate that transfusions alone are unlikely to cause more than a few infections, unless the number of primary cases increases. To improve our models, future work should pursue data collection, empirical estimation of the model parameters, and examination of the underlying assumptions of our frameworks. Further improvements could also include examining susceptibility to vCJD infection by age group and iatrogenic infections introduced through surgical instruments. Regarding the latter, it may be worthwhile to conduct experiments to quantify the transmission of prions from an infected surgical instrument after repeated sterilization procedures

Forecasting Agricultural Commodity Prices with Asymmetric-Error GARCH Models

The performance of a proposed asymmetric-error GARCH model is evaluated in comparison to the normal-error- and Student-t-GARCH models through three applications involving forecasts of U.S. soybean, sorghum, and wheat prices. The applications illustrate the relative advantages of the proposed model specification when the error term is asymmetrically distributed, and provide improved probabilistic forecasts for the prices of these commodities.GARCH, nonnormality, skewness, time-series forecasting, U.S. commodity prices, Demand and Price Analysis,

Oxygen Abundances in Nearby FGK Stars and the Galactic Chemical Evolution of the Local Disk and Halo

Atmospheric parameters and oxygen abundances of 825 nearby FGK stars are derived using high-quality spectra and a non-LTE analysis of the 777 nm O I triplet lines. We assign a kinematic probability for the stars to be thin-disk (P1), thick-disk (P2), and halo (P3) members. We confirm previous findings of enhanced [O/Fe] in thick-disk (P2>0.5) relative to thin-disk (P1>0.5) stars with [Fe/H]<-0.2, as well as a "knee" that connects the mean [O/Fe]-[Fe/H] trend of thick-disk stars with that of thin-disk members at [Fe/H]>-0.2. Nevertheless, we find that the kinematic membership criterion fails at separating perfectly the stars in the [O/Fe]-[Fe/H] plane, even when a very restrictive kinematic separation is employed. Stars with "intermediate" kinematics (P1<0.7, P2<0.7) do not all populate the region of the [O/Fe]-[Fe/H] plane intermediate between the mean thin-disk and thick-disk trends, but their distribution is not necessarily bimodal. Halo stars (P3>0.5) show a large star-to-star scatter in [O/Fe]-[Fe/H], but most of it is due to stars with Galactocentric rotational velocity V-200 km/s follow an [O/Fe]-[Fe/H] relation with almost no star-to-star scatter. Early mergers with satellite galaxies explain most of our observations, but the significant fraction of disk stars with "ambiguous" kinematics and abundances suggests that scattering by molecular clouds and radial migration have both played an important role in determining the kinematic and chemical properties of solar neighborhood stars.Comment: ApJ, in press. Complete tables 2-6 are available in the source (Download: Other formats -> Source

Black Hole Formation in Fallback Supernova and the Spins of LIGO Sources

Here we investigate within the context of field binary progenitors how the the spin of LIGO sources vary when the helium star-descendent black hole (BH) is formed in a failed supernova (SN) explosion rather than by direct collapse. To this end, we make use of 3d hydrodynamical simulations of fallback supernova in close binary systems with properties designed to emulate LIGO sources. By systematically varying the explosion energy and the binary properties, we are able to explore the effects that the companion has on redistributing the angular momentum of the system. We find that, unlike the mass, the spin of the newly formed BH varies only slightly with the currently theoretically unconstrained energy of the SN and is primarily determined by the initial binary separation. In contrast, variations in the initial binary separation yield sizable changes on the resultant effective spin of the system. This implies that the formation pathways of LIGO sources leading to a particular effective spin might be far less restrictive than the standard direct collapse scenario suggests.Comment: 7 pages, 5 figures, submitted to ApJ Letter

Diamagnetic Interactions in Disordered Suspensions of Metastable Superconducting Granules

The simulation of the transition sequence of superheated Type I superconducting granules (SSG) in disordered suspensions when an external magnetic field is slowly increased from zero has been studied. Simulation takes into account diamagnetic interactions and the presence of surface defects. Results have been obtained for the transition sequence and surface fields distribution covering a wide range of densities. These results are compared with previous analytical perturbative theory, which provides qualitative information on transitions and surface magnetic fields during transitions, but with a range of validity apparently limited to extremely dilute samples. Simulations taking into account the complete diamagnetic interactions between spheres appear to be a promising tool in interpreting SSG experiments, in applications such as particle detectors, and in some fundamental calculations of Solid State Physics.Comment: 25 pages, 11 figures, accepted for publication in European Physics Journal

Social enterprise – a new phenomenon in the field of economic and social welfare?

Drawing upon insights from historical institutionalism, this article critically examines the origins of social enterprise and its emergence into the mainstream policy arena. It begins by relating the social enterprise idea to major non-state/non-private institutional traditions, including the European social economy, US non-profits and the UK charitable sector, and places it within the specific field of economic and social welfare. In so doing, the article contests the idea that social enterprise is a new phenomenon in the social welfare field and proposes instead that the supposed ‘novelty’ of social enterprise as an organizational form and a subject of public policy lies primarily in the nature of the socio-political and economic context of the 1980s–1990s, during which time it became ‘en vogue’. The process of institutionalization of social enterprise and its ascension into the mainstream policy arena is examined in more detail in the case of England during the time New Labour was in office and beyond, and lessons are drawn from this experience concerning both the role that social enterprise plays or is expected to play as a vehicle to address economic and social needs, and how this is intertwined with both a dominant neo-liberal discourse, as well as alternative perspectives that emphasize more equalitarian and sustainable development paths. The article concludes with some reflections in relation to the apparent consensus that seems to exist around social enterprise as a legitimate subject of public policy and the resulting social enterprization of public services which is currently taking place in England

Outsider missing link or panacea? Some Reflections about the place of social enterprise (with)in and in relation to the Third Sector.

The paper argues that visions of social enterprise and its relationship with the third sector vary significantly from those that loudly or silently see social enterprise as conventional businesses and therefore as ‘outsiders’ to the third sector to those that see them as the ‘missing link’ between the third sector and markets and even as a ‘panacea’ to solve social problems. The paper critically examines these views in the UK context and concludes with some policy considerations in relation to the place of social enterprise within the third sector and future policy scenarios