Use of lead isotopic ratios as geographical tracer for Lambrusco PDO wines

In this study, the lead isotope signature was tested with the aim to verify its potential as geographic tracer for wine production and particularly for the Lambrusco PDO wines of the province of Modena (Italy). A solid phase extraction procedure, for separating lead from the investigated matrices, soil and wine, was optimized. Furthermore, different mathematical models, based on an exponential law and internal or external correction approach, were evaluated for the correction of instrumental mass dependent fractionation. The optimized analytical procedure yielded isotopic ratio data relative to the lead NIST 981 standard, 208Pb/206Pb = 2.16664 and 207Pb/206Pb = 0.914645, in good agreement both with the tabulated values and with the most recent literature data. Measured isotope ratio data highlight the contribute of multiple lead sources in bottled wine but different from the one present in soils

Comparative study of technological behavior of German ball clay and Italian kaolinitic clay in unconventional porcelain stoneware body

This work focused on obtaining a porcelain stoneware body containing only Italian raw materials. The starting mixtures differed in the feldspathic fraction, one pumice-based and one lapillus-based. German ball clay was gradually replaced by Italian kaolinitic clay. The influence of Italian kaolinitic clay on the technical and aesthetic properties of the final product was analyzed by comparing it with the references. The work was carried out in collaboration with a ceramic company which allowed the tile production process to be simulated in the laboratory and fired in an industrial kiln using the production cycle (48 min, 1210 °C). Ceramic bodies were characterized in order to evaluate technological performance by measuring efflux time and density of slip, flexural strength on green, linear shrinkage and water absorption in vacuum on fired samples. Mineralogical, microstructural (ESEM) and colorimetric analyses were also performed on the fired samples. Efflux time and density are processing parameters; these were in line with the reference in the lapillus-based bodies with kaolinitic clay replacement rates of 100%; in the case of the pumice-based bodies, they were considered acceptable only for replacements of 25%. The lapillus-based body showed a microstructure similar to that of porcelain stoneware. Vacuum water absorption values were better in lapillus-based formulations than in pumice-based formulations but showed higher linear shrinkage values for 100% replacements. According to UNI EN 14411 ISO 13006, some of the products obtained can be classified as porcelain stoneware (group BIa)

Chemical Characterization Of Commercial Balsamic Vinegar Glaze

The present study reports the chemical characterization of commercial balsamic vinegar glaze (BVG), a side product of the world-famous Aceto Balsamico di Modena (ABM). BVG, originally a homemade sweet and sour sauce, is now produced on an industrial scale and is gaining a growing success. The determination of total titratable acidity, dry matter, ash, metals, sugars, phenolic acids and furfurals is reported for BVG samples of different batches and years of production. Principal component analysis (PCA) and ANOVA test were applied to evaluate the experimental data. The results showed that the chemical characteristics of the product are almost unchanged in the investigated years and well reflect the characteristics of the ABM. Moreover, it was found that potentially harmful species, namely furfural compounds and heavy metals, were at a lower concentration than that of homologous products. In particular, the concentration of heavy metals, such as Cu, Zn and Pb, suggests that a preventive demetallization of the BVG starting raw materials occurs

Intrapancreatic accessory spleen false positive to 68Ga-Dotatoc: case report and literature review

Background: Intrapancreatic accessory spleen (IPAS) is an uncommon finding of pancreatic mass. Differential diagnosis with pancreatic tumor, especially with non-functional neuroendocrine tumor (NF-NET), may be very hard and sometimes it entails unnecessary surgery. A combination of CT scan, MRI, and nuclear medicine can confirm the diagnosis of IPAS. 68-Ga-Dotatoc PET/CT is the gold standard in NET diagnosis and it can allow to distinguish between IPAS and NET. Case presentation: A 69-year-old man was admitted to our hospital for an incidental nodule in the tail of the pancreas with focal uptake of 68-Ga-dotatate at PET/CT. NET was suspected and open distal splenopancreatectomy was performed. Pathologic examination revealed an IPAS. Conclusion: This is the second IPAS case in which a positive 68Ga-Dotatoc uptake led to a false diagnosis of pancreatic NET. Here is a proposal of a literature review

Characterization of Volcano-Sedimentary Rocks and Related Scraps for Design of Sustainable Materials

This work started as a joint academia and company research project with the aim of finding new applications for domestically sourced volcanic products and related waste (pumice, lapillus, zeolitic tuff and volcanic debris from Tessennano and Arlena quarry) by creating a database of secondary volcanic raw materials and their intrinsic characteristics to help industry replace virgin materials and enhance circularity. In this context, accurate chemical, mineralogical, morphological, granulometric and thermal characterizations were performed. Based on the results presented, it can be concluded that due to their lightness, these materials can be used in the design and preparation of lightweight aggregates for agronomic purposes or in the construction field. Furthermore, due to their aluminosilicate nature and amorphous fraction, pumice and lapillus can play the role of precursor or activator for geopolymer preparation. With its porous nature, zeolitic tuff can be exploited for flue gas treatment. Due to the presence of feldspathic phase (sanidine), these materials can be used in tile production as a fluxing component, and with their pozzolanic activity and calcium content, they have application in the binder field as supplementary cementitious material or as aggregates

Tracing geographical origin of Lambrusco PDO wines using isotope ratios of oxygen, boron, strontium, lead and their elemental concentration

Wine identification is one of the most important aspects in the classification of wines and consumer protection. In particular, assuring wine authenticity is a crucial issue on which researchers are focusing on. This study aims to evaluate the feasibility of using chemical (B, Pb and Sr concentration) and isotopic compositions (δ11B, 20yPb/20xPb, 87Sr/86Sr and δ18O) of wine samples to trace their geographic origins. Different PDO Lambrusco wines coming from a confined area of northern Italy were analyzed and all the isotopic systematics were monitored by using a multi collector inductively coupled plasma mass spectrometer (MC-ICP/MS). The obtained results showed that boron isotope ratio measurements led to a satisfactory degree of accuracy and precision (measured value, n = 28, 11B/10B of NIST SRM 951a equal to 4.04343 ± 0.00178, (u = 2s) with a certified value of 4.04362 ± 0.00136 (u = 2s). Furthermore, in the present study, it has been possible to highlight significant differences among samples by means of one-way analysis of variance (ANOVA) and post hoc Tukey-Kramer test. Finally, Principal Component Analysis (PCA) was also carried out in order to evaluate to which extent the different PDOs can be distinguished from each other, taking into account the whole set of geographical origin descriptors. Although δ11B provided more sensitive information, the obtained results highlighted the important to consider the synergistic combination of all the investigated parameters to trace the different samples and the need to combine the obtained values with the same parameters evaluated in the soil, water and fertilizer as well

On the master equation approach to kinetic theory: linear and nonlinear Fokker--Planck equations

We discuss the relationship between kinetic equations of the Fokker-Planck type (two linear and one non-linear) and the Kolmogorov (a.k.a. master) equations of certain N-body diffusion processes, in the context of Kac's "propagation of chaos" limit. The linear Fokker-Planck equations are well-known, but here they are derived as a limit N->infty of a simple linear diffusion equation on (3N-C)-dimensional N-velocity spheres of radius sqrt(N) (with C=1 or 4 depending on whether the system conserves energy only or energy and momentum). In this case, a spectral gap separating the zero eigenvalue from the positive spectrum of the Laplacian remains as N->infty,so that the exponential approach to equilibrium of the master evolution is passed on to the limiting Fokker-Planck evolution in R^3. The non-linear Fokker-Planck equation is known as Landau's equation in the plasma physics literature. Its N-particle master equation, originally introduced (in the 1950s) by Balescu and Prigogine (BP), is studied here on the (3N-4)-dimensional N-velocity sphere. It is shown that the BP master equation represents a superposition of diffusion processes on certain two-dimensional sub-manifolds of R^{3N} determined by the conservation laws for two-particle collisions. The initial value problem for the BP master equation is proved to be well-posed and its solutions are shown to decay exponentially fast to equilibrium. However, the first non-zero eigenvalue of the BP operator is shown to vanish in the limit N->infty. This indicates that the exponentially fast approach to equilibrium may not be passed from the finite-N master equation on to Landau's nonlinear kinetic equation.Comment: 20 pages; based on talk at the 18th ICTT Conference. Some typos and a few minor technical fixes. Modified title slightl

Pumice and lapillus scraps: New national environmental-friendly chance for the production of ceramic tiles

Italian pumice and volcanic lapillus scraps have been used in different percentages as alternative raw materials to foreign feldspars in porcelain stoneware mixtures. The aim of this work was to create naturally colored support to limit the use of artificial dyes while maintaining the technical properties of the reference product. For this purpose, the significant presence of chromophores (Fe and Ti in particular) in by-products from extraction of Italian volcanic pumice and lapillus was exploited. The work was carried out in collaboration with a company: the products were made on a laboratory scale and then they were glazed and fired within the industrial production cycle (48 min, 1210 ◦C). The resulting slip and the fired samples were characterized by measuring the efflux time, density, linear shrinkage, water absorption and tensile strength to evaluate the technological performance. In addition, thermogravimetric analysis (TG), differential thermal analysis (DTA), and optical and mechanical dilatometry were performed to study the thermal behavior of the formulations. The obtained products could be classified as porcelain stoneware and belong to the BIa group (WA 0.5%, B. S.>35 MPa) in accordance with UNI EN 14411 ISO 13006

Analytical Concentrations of Some Elements in Seeds and Crude Extracts from Aesculus hippocastanum, by ICP-OES Technique

The metal content in some samples of horse chestnut seeds (Aesculus hippocastanum) was monitored over time (years 2016, 2017, 2018, 2019) considering the two most common and representative Mediterranean varieties: the pure species (AHP, which gives white flowers) and a hybrid one (AHH, which gives pink flowers). The selected elemental composition of the samples was determined by applying the ICP-OES technique. Several samples obtained from different preliminary treatments of the peeled seeds were examined, such as: i) floury samples (wild type) mineralized with the wet method; ii) the ashes of both AHP and AHH varieties; iii) the fraction of total inorganic soluble salts (TISS). Furthermore, the hydroalcoholic crude extracts (as a tincture) were obtained according to the official Pharmacopoeia methods, and the relevant results were compared with those of a commercial sample, an herbal product - food supplement of similar characteristics. The main characteristics of this research work underline that the two botanical varieties give different distinctive characters, due to the Fe content (80.05 vs 1.42 mg / 100 g d.s., for AHP and AHH - wild type flour samples, respectively), along with K, Ca, Mn, Ni and Cu, which are more abundant in the AHP samples. Furthermore, the PCA analysis was applied to the experimental dataset in order to classify and discriminate the samples, in relation to their similar botanical origin, but different for the color of the bloom. These results can be useful for the traceability of raw materials potentially intended for the production of auxiliary systems of pharmacological interest.The metal content in some samples of horse chestnut seeds (Aesculus hippocastanum) was monitored over time (years 2016–2019) considering the two most common and representative Mediterranean varieties: the pure species (AHP, which gives white flowers) and a hybrid one (AHH, which gives pink flowers). The selected elemental composition of the samples was determined by applying the Inductively Coupled Plasma-Optical Emission Spectroscopy (ICP-OES) technique. Several samples obtained from different preliminary treatments of the peeled seeds were examined, such as: (i) floury samples (wild-type) mineralized with the wet method; (ii) the ashes of both AHP and AHH varieties; (iii) the fraction of total inorganic soluble salts (TISS). Furthermore, the hydroalcoholic crude extracts (as a tincture) were obtained according to the official Pharmacopoeia methods, and the relevant results were compared with those of a commercial sample, an herbal product-food supplement of similar characteristics. The main characteristics of this research work underline that the two botanical varieties give different distinctive characters, due to the Fe content (80.05 vs. 1.42 mg/100 g d.s., for AHP and AHH wild-type flour samples, respectively), along with K, Ca, Mn, Ni and Cu, which are more abundant in the AHP samples. Furthermore, the Principal Component Analysis (PCA) was applied to the experimental dataset in order to classify and discriminate the samples, in relation to their similar botanical origin, but different for the color of the bloom. These results can be useful for the traceability of raw materials potentially intended for the production of auxiliary systems of pharmacological interest

Physical-chemical characterization of a galvanic sludge and its inertization by vitrification using container glass

Several industrial processes produce large amounts of heavy metals-rich wastes, which could be considered as "trash-can raw materials". The incorporation in ceramic systems can be regarded as a key process to permanently incorporate hazardous heavy metals in stable matrixes. In particular the aim of this work is to prepare and evaluate environmental risk assessment of coloured glass and glass-ceramic with the addition of chromium(III) galvanic sludge having a high content of Cr2O3 (15.91 wt%). Trivalent chromium compounds generally have low toxicity while hexavalent chromium is recognized by the International Agency for Research on Cancer and by the US Toxicology Program as a pulmonary carcinogen. The sludge has been characterized by ICP -AES chemical analysis, powder XRD diffraction, DTA, SEM, leaching test after different thermal treatments ranging from 400°C to 1200°C. Batch compositions were prepared by mixing this sludge with glass containers. The glass container composition is rich in SiO2 (69.89 wt%), Na 2O (12.32 wt%) and CaO (11.03 wt%), while the sludge has a high amount of CaO (42.90 wt%) and Cr2O3 (15.91 wt%). The vitrification was carried out at 1450°C in an electrical melting furnace for 2 h followed by quenching in water or on graphite mould. Chromium incorporation mechanisms, vitrification processability, effect of initial Cr oxidation state, and product performance were investigated. In particular toxic characterization by leaching procedure and chemical durability studies of the glasses and glass-ceramics were used to evaluate the leaching of heavy metals (in particular of Cr). The results indicate that all the glasses obtained were inert and the heavy metals were immobilized