Photoactivated Processes on the Surface of Metal Oxides and Gas Sensitivity to Oxygen

Photoactivation by UV and visible radiation is a promising approach for the development of semiconductor gas sensors with reduced power consumption, high sensitivity, and stability. Although many hopeful results were achieved in this direction, the theoretical basis for the processes responsible for the photoactivated gas sensitivity still needs to be clarified. In this work, we investigated the mechanisms of UV-activated processes on the surface of nanocrystalline ZnO, In2O3, and SnO2 by in situ mass spectrometry and compared the obtained results with the gas sensitivity to oxygen in the dark and at UV irradiation. The results revealed a correlation between the photoactivated oxygen isotopic exchange activity and UV-activated oxygen gas sensitivity of the studied metal oxides. To interpret the data obtained, a model was proposed based on the idea of the generation of additional oxygen vacancies under UV irradiation due to the interaction with photoexcited holes

Photoactivated Processes on the Surface of Metal Oxides and Gas Sensitivity to Oxygen

Photoactivation by UV and visible radiation is a promising approach for the development of semiconductor gas sensors with reduced power consumption, high sensitivity, and stability. Although many hopeful results were achieved in this direction, the theoretical basis for the processes responsible for the photoactivated gas sensitivity still needs to be clarified. In this work, we investigated the mechanisms of UV-activated processes on the surface of nanocrystalline ZnO, In2O3, and SnO2 by in situ mass spectrometry and compared the obtained results with the gas sensitivity to oxygen in the dark and at UV irradiation. The results revealed a correlation between the photoactivated oxygen isotopic exchange activity and UV-activated oxygen gas sensitivity of the studied metal oxides. To interpret the data obtained, a model was proposed based on the idea of the generation of additional oxygen vacancies under UV irradiation due to the interaction with photoexcited holes

UV-Activated NO₂ Gas Sensing by Nanocrystalline ZnO: Mechanistic Insights from Mass Spectrometry Investigations

In this work, the photostimulated processes of O2 and NO2 molecules with the surface of ZnO under UV radiation were studied by in situ mass spectrometry in the temperature range of 30–100 ∘C. Nanocrystalline needle-like ZnO was synthesized by decomposition of basic zinc carbonate at 300 ∘C, and the surface concentration of oxygen vacancies in it were controlled by reductive post-annealing in an inert gas at 170 ∘C. The synthesized materials were characterized by XRD, SEM, low-temperature nitrogen adsorption (BET), XPS, Raman spectroscopy, and PL spectroscopy. Irradiation of samples with UV light causes the photoabsorption of both O2 and NO2. The photoadsorption properties of ZnO are compared with its defective structure and gas-sensitive properties to NO2. A model of the sensor response of ZnO to NO2 under UV photoactivation is proposed

UV-Activated NO2 Gas Sensing by Nanocrystalline ZnO: Mechanistic Insights from Mass Spectrometry Investigations

In this work, the photostimulated processes of O2 and NO2 molecules with the surface of ZnO under UV radiation were studied by in situ mass spectrometry in the temperature range of 30–100 ∘C. Nanocrystalline needle-like ZnO was synthesized by decomposition of basic zinc carbonate at 300 ∘C, and the surface concentration of oxygen vacancies in it were controlled by reductive post-annealing in an inert gas at 170 ∘C. The synthesized materials were characterized by XRD, SEM, low-temperature nitrogen adsorption (BET), XPS, Raman spectroscopy, and PL spectroscopy. Irradiation of samples with UV light causes the photoabsorption of both O2 and NO2. The photoadsorption properties of ZnO are compared with its defective structure and gas-sensitive properties to NO2. A model of the sensor response of ZnO to NO2 under UV photoactivation is proposed

Influence of Mono- and Bimetallic PtO_x, PdO_x, PtPdO_x Clusters on CO Sensing by SnO₂ Based Gas Sensors

To obtain a nanocrystalline SnO2 matrix and mono- and bimetallic nanocomposites SnO2/Pd, SnO2/Pt, and SnO2/PtPd, a flame spray pyrolysis with subsequent impregnation was used. The materials were characterized using X-ray diffraction (XRD), a single-point BET method, transmission electron microscopy (TEM), and high angle annular dark field scanning transmission electron microscopy (HAADF-STEM) with energy dispersive X-ray (EDX) mapping. The electronic state of the metals in mono- and bimetallic clusters was determined using X-ray photoelectron spectroscopy (XPS). The active surface sites were investigated using the Fourier Transform infrared spectroscopy (FTIR) and thermo-programmed reduction with hydrogen (TPR-H2) methods. The sensor response of blank SnO2 and nanocomposites had a carbon monoxide (CO) level of 6.7 ppm and was determined in the temperature range 60⁻300 °C in dry (Relative Humidity (RH) = 0%) and humid (RH = 20%) air. The sensor properties of the mono- and bimetallic nanocomposites were analyzed on the basis of information on the electronic state, the distribution of modifiers in SnO2 matrix, and active surface centers. For SnO2/PtPd, the combined effect of the modifiers on the electrophysical properties of SnO2 explained the inversion of sensor response from n- to p-types observed in dry conditions