105 research outputs found
N-(2,5-Dichlorophenyl)maleamic acid
The asymmetric unit of the title compound, C10H7Cl2NO3, contains two independent molecules. The molecular conformation of each maleamic unit is stabilized by an intramolecular O—H⋯Ocarbonyl hydrogen bond owing to the anti disposition of the participating entities. The mean planes through the benzene ring and the amido group are inclined at angles of 45.7 (1) and 40.8 (1)° in the two molecules. In the crystal, the independent molecules self-associate via N—H⋯O hydrogen bonds into zigzag ribbons propagating along the a axis. The ribbons are weakly coupled by C—H⋯π and C—H⋯O interactions
3-Chloro-N-(2-methylphenyl)benzamide
In the molecular structure of the title compound, C14H12ClNO, the meta-Cl atom in the benzoyl ring is positioned anti to the C=O bond, while the ortho-methyl group in the aniline ring is positioned syn to the N—H bond. The two benzene rings are nearly coplanar [dihedral angle = 3.48 (5)°]. The crystal structure is stabilized by N—H⋯O hydrogen bonds, which link the molecules into chains along the b axis
4-Chloro-N-(3,5-dimethylphenyl)benzamide
In the molecular structure of the title compound, C15H14ClNO, the amide group forms dihedral angles of 15.8 (2) and 27.2 (2)°, respectively, with the benzoyl and aniline rings, while the angle between the benzoyl and aniline rings is 11.5 (1)°. The crystal structure is stabilized by N—H⋯O hydrogen bonds, which give rise to infinite chains running along the c axis
(7R,8S,8aS)-8-Hydroxy-7-phenylperhydroindolizin-3-one
In the title compound, C14H17NO2, the six-membered ring of the indolizine system adopts a chair conformation. In the crystal, molecules form chains parallel to the b axis via intermolecular O—H⋯O hydrogen bonds. The absolute molecular configuration was assigned from the synthesis
2-Chloro-N-phenylacetamide
In the title compound, C8H8ClNO, the conformations of the N—H and C=O bonds are anti to each other, but the C—Cl and C=O bonds in the side chain are syn. The molecules are linked by N—H⋯O hydrogen bonds into infinite chains running in the [101] direction
Phenyl 4-methylbenzoate
The structure of the title compound, C14H12O2, resembles those of phenyl benzoate and 4-methylphenyl benzoate, with similar bond parameters. The two aromatic rings make a dihedral angle of 76.0 (1)°. The plane of the central —C(=O)—O— group is twisted by 9.4 (2)° out of the plane of the benzoyl ring, and by 83.3 (1)° out of the plane of the phenyl ring. The crystal structure exhibits weak parallel stacking of the benzoyl rings, with an interplanar distance of 3.65 Å and an offset of 1.84 Å. The methyl group shows orientational disorder
N-(3-Chlorophenyl)maleamic acid
In the title compound, C10H8ClNO3, the molecular conformation is stabilized by two intramolecular hydrogen bonds. The first is a short O—H⋯O hydrogen bond within the maleamic acid unit and the second is a C—H⋯O hydrogen bond which connects the amide group with the phenyl ring. The maleamic acid unit is essentially planar, with an r.m.s. deviation of 0.044 Å, and makes a dihedral angle of 15.2 (1)° with the phenyl ring. In the crystal, intermolecular N—H⋯O hydrogen bonds link the molecules into C(7) chains running [010]
N-(2,4,6-Trimethylphenyl)maleamic acid
The molecular structure of the title compound, C13H15NO3, is stabilized by a short intramolecular O—H⋯O hydrogen bond within the maleamic unit. In the crystal, intermolecular N—H⋯O hydrogen bonds link molecules into zigzag chains propagating in [010]
N-(3,4-Dimethylphenyl)maleamic acid
The title compound, C12H13NO3, crystallizes with four independent molecules in the asymmetric unit. The N—H bond and the C=O bond in the amide segment are anti to each other. The C=C double bond is cis configured and an intramolecular O—H⋯O hydrogen bond is formed in each molecule. The mean planes through the aromatic ring and the amide group –NHCO– are inclined at angles of 17.4 (3), 20.8 (2), 16.2 (2) and 11.2 (3)° in the four molecules. In the crystal, intermolecular N—H⋯O hydrogen bonds link the molecules into ribbons along the b axis
N-(2,6-Dichlorophenyl)-3-methylbenzamide
In the molecular structure of the title compound, C14H11Cl2NO, the two aromatic rings form a dihedral angle of 70.9 (1)°. The central amido group –NH—C(=O)– makes a dihedral angle of 26.6 (2)° with the methylphenyl ring and 82.5 (1)° with the dichlorophenyl ring. Intermolecular N—H⋯O hydrogen bonds link the molecules into chains running along the c axis of the crystal
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