Finite temperature behavior of impurity doped Lithium cluster {\em viz} Li6_6Sn

We have carried out extensive isokinetic {\it ab initio} molecular dynamic simulations to investigate the finite temperature properties of the impurity doped cluster Li$_6$Sn along with the host cluster Li$_7$. The data obtained from about 20 temperatures and total simulation time of at least 3 ns is used to extract thermodynamical quantities like canonical specific heat. We observe a substantial charge transfer from all Li atoms to Sn which inturn weakens the Li-Li bonds in Li$_6$Sn compared to the bonds in Li$_7$. This weakening of bonds changes the finite temperature behavior of Li$_6$Sn significantly. Firstly, Li$_6$Sn becomes liquid-like around 250 K, a much lower temperature than that of Li$_7$ ($\approx$~425 K). Secondly, an additional quasirotational motion of lithium atoms appears at lower temperatures giving rise to a shoulder around 50 K in the specific heat curve of Li$_6$Sn. The peak in the specific heat of Li$_7$ is very broad and the specific heat does not show any premelting features.Comment: 16 pages, 10 figures Submitted to J. Chem. Phy

Quantum Hertz entropy increase in a quenched spin chain

The classical Hertz entropy is the logarithm of the volume of phase space bounded by the constant energy surface; its quantum counterpart, the quantum Hertz entropy, is $\hat S = k_B \ln \hat N$, where the quantum operator $\hat N$ specifies the number of states with energy below a given energy eigenstate. It has been recently proved that, when an isolated quantum mechanical system is driven out of equilibrium by an external driving, the change in the expectation of its quantum Hertz entropy cannot be negative, and is null for adiabatic driving. This is in full agreement with the Clausius principle. Here we test the behavior of the expectation of the quantum Hertz entropy in the case when two identical XY spin chains initially at different temperatures are quenched into a single XY chain. We observed no quantum Hertz entropy decrease. This finding further supports the statement that the quantum Hertz entropy is a proper entropy for isolated quantum systems. We further quantify how far the quenched chain is from thermal equilibrium and the temperature of the closest equilibrium.Comment: 9 pages, 5 figure

The Charged Neutrino: A New Approach to the Solar Neutrino Problem

We have considered the effect of the reduction of the solar neutrino flux on earth due to the deflection of the charged neutrino by the magnetic field of the solar convective zone. The antisymmetry of this magnetic field about the plane of the solar equator induces the anisotropy of the solar neutrino flux thus creating the deficit of the neutrino flux on the earth. The deficit has been estimated in terms of solar and neutrino parameters and the condition of a 50 \% deficit has been obtained: Q_{\nu} gradH \agt 10^{-18} eG/cm where $Q_{\nu}$ is the neutrino electric charge, $gradH$ is the gradient of the solar toroidal magnetic field, e is the electron charge. Some attractive experimental consequences of this scenario are qualitatively discussed.Comment: 15 pages, UM-P/94-26, in REVTE

Maverick Examples Of Coset Conformal Field Theories

We present coset conformal field theories whose spectrum is not determined by the identification current method. In these ``maverick'' cosets there is a larger symmetry identifying primary fields than under the identification current. We find an A-D-E classification of these mavericks. }Comment: 16pages , reportSWAT-93-0