Influence of electrolyte concentration on holdup, flow regime transition and local flow properties in a large scale bubble column

We experimentally investigate the influence of the electrolyte concentration on holdup, flow regime transition and local flow properties in a large scale bubble column, with air and water as working fluids. The column is 0.24 m inner diameter, 5.3 m height and the air is introduced by a spider sparger up to a superficial gas velocity of 0.2 m/s. The influence of five NaCl concentrations are investigated by using gas holdup and optical probe measurements. The gas holdup measurements are used for analysing the flow regime transition between the homogeneous and the transition regime and the optical probe is used for studying the local flow characteristics at different radial positions. The presence of NaCl - up to a critical concentration - increases the gas holdup. The increase in the gas holdup is due to the inhibition of the coalescence between the bubbles and, thus, the extension of the homogeneous regime. The results are in agreement with the previous literature on smaller bubble columns

Influence of internals on counter-current bubble column hydrodynamics: Holdup, flow regime transition and local flow properties

Bubble columns are frequently studied without considering internals (open tube bubble columns). However, in most industrial applications, internal devices are often added to control heat transfer, to foster bubble break-up or to limit liquid phase back mixing. These elements can have significant effects on the multiphase flow inside the bubble column reactor and the prediction of these effects is still hardly possible without experimentation. In this paper, we study experimentally a counter-current gas-liquid bubble column in the open tube and annular gap configurations. In the annular gap bubble column, two vertical internal tubes are considered. The column has an inner diameter of 0.24 m, and the global and local hydrodynamic properties are studied using gas holdup measurements and a double-fiber optical probe. The gas holdup measurements are compared with the literature and used to investigate the flow regime transition. A double-fiber optical probe is used to acquire midpoint data and radial profiles of the local properties to study the flow properties and to further investigate the flow regime transition. The counter-current mode is found to increase the holdup, decrease the bubble velocity and cause regime transition at lower superficial gas velocity. The holdup curves in the annular gap and open tube configurations are similar in shape and values, suggesting that the presence of internals has a limited influence on the global hydrodynamic. In addition, it is found that the presence of the internals stabilizes the homogeneous regime in terms of transition gas velocity and holdup. © 2016 Elsevier Ltd

Comprehensive experimental investigation of counter-current bubble column hydrodynamics: Holdup, flow regime transition, bubble size distributions and local flow properties

In this paper, we apply a variety of experimental techniques to investigate the influence of the counter-current mode on bubble column hydrodynamics. We study an air-water bubble column, which is 5.3 m in height and has an inner diameter of 0.24 m, and we consider gas superficial velocities in the range of 0.004-0.20 m/s and liquid superficial velocities up to -0.09 m/s. The experimental investigation consists of holdup, gas disengagement, image analysis and optical probe measurements. The holdup measurements are compared with the literature and are used to investigate the flow regime transition. The gas disengagement measurements are used to further investigate the flow regime transition and study the structure of the holdup curve. The image analysis is used to study the bubble shapes and size distributions near the sparger and in the developed region of the column; in particular, the image analysis is applied to different gas velocities in the homogeneous regime in both the batch and counter-current modes. The optical probe is used to acquire radial profiles of the local properties (i.e., local void fraction and bubble rise velocity) to study the flow properties and further investigate the flow regime transition. Comparing the results from the different techniques, the influence of the gas superficial velocity and the liquid superficial velocity is discussed considering all main aspects of the two-phase flow, from the local flow properties to the global flow features. The counter-current mode is found to increase the holdup, reduce the bubble rise velocity, destabilize the homogeneous regime and change the local flow properties. © 2016 Elsevier Ltd

Bubble size distributions and shapes in annular gap bubble column

An understanding of the bubble properties, size distributions and shapes is of fundamental importance for comprehending flow dynamics and mass transfer phenomena in bubble column reactors. A large number of studies have focused on open tube bubble columns, and the knowledge concerning bubble columns with internals is still limited. This paper contributes to the existing discussion experimentally investigating a counter-current annular bubble column with 0.24. m inner diameter and two internal pipes. The experimental investigation consists in holdup measurements and image analysis. The former is used for identifying the flow regime transition and studying the bubble column hydrodynamics, whereas the latter is used for investigating the bubble shapes and size distributions. The definition of the transition point is important because the size distribution and bubble shapes depend on the operating conditions and a change of the bubble properties is expected near the transition. The image analysis is applied at different superficial gas and liquid velocities, corresponding to a gas holdup between 2.9% and 9.6%. It is difficult to measure bubble size distribution accurately in large-diameter bubble columns owing to the overlapping of bubbles, even at low void fractions, and-in an annular gap bubble column-the fact that cap bubbles have also been reported in the homogeneous flow regime. The use of a bubble image analysis method to study the bubbly flows in a large-diameter annular gap bubble column is described. In the proposed method, each bubble is approximated and reconstructed using an ellipse. The proposed approach is used to quantify the bubble size distribution, as well as to study the bubble shape and orientation as function of the superficial gas and liquid velocities. The experimental data obtained are used to develop a correlation between non-dimensional parameters and aspect ratios. Also, the experimental data are compared with non-dimensional diagrams from the literature, revealing good agreement. Finally, the image analysis is used for supporting the flow regime transition prediction in the stability analysis method: the virtual mass formulation is obtained by using the aspect ratio correlation provided by the image analysis. The stability analysis-supported by the image analysis-was able to predict the transition point in very good agreement with experimental data and performed better than literature correlations. © 2015 Elsevier Inc

Ejector refrigeration: A comprehensive review

The increasing need for thermal comfort has led to a rapid increase in the use of cooling systems and, consequently, electricity demand for air-conditioning systems in buildings. Heat-driven ejector refrigeration systems appear to be a promising alternative to the traditional compressor-based refrigeration technologies for energy consumption reduction. This paper presents a comprehensive literature review on ejector refrigeration systems and working fluids. It deeply analyzes ejector technology and behavior, refrigerant properties and their influence over ejector performance and all of the ejector refrigeration technologies, with a focus on past, present and future trends. The review is structured in four parts. In the first part, ejector technology is described. In the second part, a detailed description of the refrigerant properties and their influence over ejector performance is presented. In the third part, a review focused on the main jet refrigeration cycles is proposed, and the ejector refrigeration systems are reported and categorized. Finally, an overview over all ejector technologies, the relationship among the working fluids and the ejector performance, with a focus on past, present and future trends, is presented. (C) 2015 Elsevier Ltd. All rights reserved

Prediction of gas–liquid flow in an annular gap bubble column using a bi-dispersed Eulerian model

We present and discuss numerical results from simulations of the air–water flow in an annular gap bubble column of 0.24 m internal diameter, at air superficial velocities ranging from 0.004 m/s to 0.225 m/s, covering the homogeneous and heterogeneous flow regimes. A bi-dispersed Eulerian model is implemented to account for both the stabilizing and destabilizing effects of small and large bubbles. Sensitivity studies on the mesh element size, time step size and number of outer iterations per time step are performed and most appropriate simulation parameters and mesh are used to predict the gas holdup curve. Comparison with two mono-dispersed models is provided to emphasize the necessity of a bi-dispersed approach for the accurate prediction of the homogeneous flow regime, given the poly-dispersed nature of the flow investigated. Two different approaches for the characterization of the small and large bubbles groups are also discussed. We found that the relative amount of small bubbles is an important input parameter for the present model and can be provided using available empirical correlations or experimental data. The results obtained from the simulations also demonstrated the necessity of a population balance model able to capture the bubbles coalescence and breakup phenomena for the correct prediction of the heterogeneous flow regime

Annular gap bubble column: Experimental investigation and computational fluid dynamics modeling

This paper investigates the countercurrent gas-liquid flow in an annular gap bubble column with a 0.24 m inner diameter by using experimental and numerical investigations. The two-phase flow is studied experimentally using flow visualizations, gas holdup measurements, and double fiber optical probes in the following range of operating conditions: superficial air velocities up to 0.23 m/s and superficial water velocities up to -0.11 m/s, corresponding to gas holdups up to 29%. The flow visualizations were used to observe the flow patterns and to obtain the bubble size distribution (BSD). The gas holdup measurements were used for investigating the flow regime transitions, and the double fiber optical probes were used to study the local flow phenomena. A computational fluid dynamics (CFD) Eulerian two-fluid modeling of the column operating in the bubbly flow regime is proposed using the commercial software ansys fluent. The three-dimensional (3D) transient simulations have been performed considering a set of nondrag forces and polydispersity. It is shown that the errors in the global holdup and in the local properties are below 7% and 16%, respectively, in the range considered. Copyright © 2016 by ASME

Interpretation of two-phase relative permeability curves through multiple formulations and Model Quality criteria

We illustrate the way formal model identification criteria can be employed to rank and evaluate a set of alternative models in the context of the interpretation of laboratory scale experiments yielding two-phase relative permeability curves. We consider a set of empirical two-phase relative permeability models (i.e., Corey, Chierici and LET) which are typically employed in industrial applications requiring water/oil relative permeability quantifications. Model uncertainty is quantified through the use of a set of model weights which are rendered by model posterior probabilities conditional on observations. These weights are then employed to (a) rank the models according to their relative skill to interpret the observations and (b) obtain model averaged results which allow accommodating within a unified theoretical framework uncertainties arising from differences amongst model structures. As a test bed for our study, we employ high quality two-phase relative permeability estimates resulting from steady-state imbibition experiments on two diverse porous media, a quartz Sand-pack and a Berea sandstone core, together with additional published datasets. The parameters of each model are estimated within a Maximum Likelihood framework. Our results highlight that in most cases the complexity of the problem appears to justify favoring a model with a high number of uncertain parameters over a simpler model structure. Posterior probabilities reveal that in several cases, most notably for the assessment of oil relative permeabilities, the weights associated with the simplest models is not negligible. This suggests that in these cases uncertainty quantification might benefit from a multi-model analysis, including both low- and high-complexity models. In most of the cases analyzed we find that model averaging leads to interpretations of the available data which are characterized by a higher degree of fidelity than that provided by the most skillful model

A study of working fluids for heat driven ejector refrigeration using lumped parameter models

This paper studies the influence of working fluids over the performance of heat driven ejector refrigeration systems performance by using a lumped parameter model. The model used has been selected after a comparison of different models with a set of experimental data available in the literature. The effect of generator, evaporator and condenser temperature over the entrainment ratio and the COP has been investigated for different working fluids in the typical operating conditions of low grade energy sources. The results show a growth in performance (the entrainment ratio and the COP) with a rise in the generator and evaporator temperature and a decrease in the condenser temperature. The working fluids have a great impact on the ejector performance and each refrigerant has its own range of operating conditions. R134a is found to be suitable for low generator temperature (70-100 degrees C), whereas the hydrocarbons R600 is suitable for medium generator temperatures (100-130 degrees C) and R601 for high generator temperatures (130-180 degrees C). (C) 2015 Elsevier Ltd and IIR. All rights reserved