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2-Amino-3-ammoniopyridinium dichloride
The asymmetric unit of the title compound, C5H9N3
2+·2Cl−, contains two diprotonated 2,3-diaminopyridine cations and four chloride anions. In the crystal structure, the anions and cations are connected by intermolecular N—H⋯Cl and C—H⋯Cl hydrogen bonds, forming a three-dimensional network. The crystal structure is further stabilized by π–π interactions between pyridinium rings [centroid–centroid distance = 3.695 (1) Å]
3,4-Diaminopyridinium 2-carboxy-4,6-dinitrophenolate
In the title salt, C5H8N3
+·C7H3N2O7
−, the pyridine N atom of the 3,4-diaminopyridine molecule is protonated. The 3,5-dinitrosalicylate anion shows whole-molecule disorder over two orientations with a refined occupancy ratio of 0.875 (4): 0.125 (4). In the crystal, the cations and anions are connected by intermolecular N—H⋯O and C—H⋯O hydrogen bonds, forming a three-dimensional network
2-Amino-5-methylpyridinium nicotinate
In the title compound, C6H9N2
+·C6H4NO2
−, the 2-amino-5-methylpyridinium cation is essentially planar, with a maximum deviation of 0.023 (2) Å. In the crystal, the cations and anions are linked via strong N—H⋯O hydrogen bonds, forming a two dimensional network parallel to (100). In addition, π⋯π interactions involving the pyridinium and pyridine rings, with centroid–centroid distances of 3.6383 (8) Å, are observed
2-Amino-5-chloropyridinium (Z)-3-carboxyprop-2-enoate 0.25-hydrate
In the title hydrated salt, C5H6ClN2
+·C4H3O4
−·0.25H2O, the water O atom lies on a twofold axis with 0.25 occupancy. The 2-amino-5-chloropyridinium cation is almost planar, with a maximum deviation of 0.015 (3) Å. In the hydrogen malate anion, an intramolecular O—H⋯O hydrogen bond generates an S(7) ring and results in a folded conformation. In the crystal, the protonated N atom and the 2-amino group of the cation are hydrogen bonded to the carboxylate O atoms of the anion via a pair of N—H⋯O hydrogen bonds, forming an R
2
2(8) ring motif. The ion pairs are further connected via O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds, forming layers parallel to the ab plane which stack down the c axis
2-Isopropyl-6-methyl-4-oxo-3,4-dihydropyrimidin-1-ium 2-carboxy-4,6-dinitrophenolate monohydrate
In the title molecular salt, C8H13N2O+·C7H3N2O7
−·H2O, the pyrimidinium cation is essentially planar, with a maximum deviation of 0.009 (1) Å. The cation undergoes an enol–keto tautomerism during the crystallization. In the crystal, the ion pairs and water molecules are connected via O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds, forming two-dimensional networks parallel to the bc plane. There is an intramolecular O—H⋯O hydrogen bond in the 3,5-dinitrosalicylate anion, which generates an S(6) ring motif
2-Amino-5-chloropyridine–fumaric acid (1/2)
The asymmetric unit of the title compound, C5H5ClN2·0.5C4H4O4, comprises a neutral 2-amino-5-chloropyridine molecule and one half of a fumaric acid molecule which lies on an inversion center. The dihedral angle between the pyridine ring and the plane formed by the fumaric acid molecule is 3.22 (8)°. The 2-amino-5-chloropyridine molecule is planar, with a maximum deviation of 0.004 (1) Å for the pyridine N atom. In the crystal, the 2-amino-5-chloropyridine molecules interact with the carboxyl groups of fumaric acid molecules through N—H⋯O and O—H⋯N hydrogen bonds, forming centrosymmetric R
2
2(8) ring motifs and another N—H⋯O hydrogen bond links these motifs into a two-dimensional network parallel to (100)
2-Amino-5-chloropyridinium 6-oxo-1,6-dihydropyridine-2-carboxylate 0.85-hydrate
In the title salt, C5H6ClN2
+·C6H4NO3
−·0.85H2O, the pyridinium ring is planar, with a maximum deviation of 0.010 (2) Å. In the crystal structure, the cations, anions and water molecules are linked via N—H⋯O, O—H⋯O and C—H⋯O hydrogen bonds, forming a three-dimensional network
4-Methoxyquinolinium-2-carboxylate dihydrate
The title hydrated quinoline derivative, C11H9NO3·2H2O, crystallizes as a zwitterion in which the quinoline N atom is protonated. The quinoline ring is essentially planar, with a maximum deviation of 0.017 (2) Å. An intramolecular N—H⋯O hydrogen bond between the protonated N atom and the O atom of the carboxylate group in the zwitterion forms an S(5) ring motif. In the crystal, the zwitterions are connected into inversion dimers via pairs of N—H⋯O and C—H⋯O hydrogen bonds with R
2
2(4) and R
1
2(6) motifs. The water molecules are connected via O—H⋯O hydrogen bonds, forming supramolecular chains along the c axis. Furthermore, the chains and the dimers are connected via O—H⋯O hydrogen bonds, forming ladder-like supramolecular ribbons along the c axis
N,N′-Bis(3-chloro-2-fluorobenzylidene)ethane-1,2-diamine
The molecule of the title centrosymmetric Schiff base compound, C16H12Cl2F2N2, adopts an E configuration with respect to the azomethine C=N bond. The imino groups are coplanar with the aromatic rings. Within the molecule, the planar units are parallel, but extend in opposite directions from the dimethylene bridge. An interesting feature of the crystal structure is the short intermolecular Cl⋯F [3.1747 (5) Å] interactions, which are shorter than the sum of the van der Waals radii of these atoms. These interactions link neighbouring molecules along the b axis. The crystal structure is further stabilized by π–π interactions, with a centroid–centroid distance of 3.5244 (4) Å
(E)-1,2-Bis(4-fluorophenyl)ethane-1,2-dione
The title compound, C14H8F2O2, is a substituted benzil with an s-trans conformation of the dicarbonyl unit. This conformation is also shown by the O—C—C—O torsion angle of −110.65 (12)°. An unusual feature of the structure is the length, 1.536 (2) Å, of the central C—C bond connecting the carbonyl units, which is significantly longer than a normal Csp
2—Csp
2 single bond. This is probably the result of decreasing the unfavourable vicinal dipole–dipole interactions by increasing the distance between the two electronegative O atoms [O⋯O = 3.1867 (12) Å] and allowing orbital overlap of the dione with the π system of the benzene rings. The dihedral angle between the aromatic rings is 64.74 (5)°. In the crystal structure, neighbouring molecules are linked together by weak intermolecular C—H⋯O (× 2) hydrogen bonds. In addition, the crystal structure is further stabilized by intermolecular π–π interactions with centroid–centroid distances in the range 3.6416 (6)–3.7150 (7) Å
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