Variational characterization of the critical curve for pinning of random polymers

In this paper we look at the pinning of a directed polymer by a one-dimensional linear interface carrying random charges. There are two phases, localized and delocalized, depending on the inverse temperature and on the disorder bias. Using quenched and annealed large deviation principles for the empirical process of words drawn from a random letter sequence according to a random renewal process (Birkner, Greven and den Hollander [6]), we derive variational formulas for the quenched, respectively, annealed critical curve separating the two phases. These variational formulas are used to obtain a necessary and sufficient criterion, stated in terms of relative entropies, for the two critical curves to be different at a given inverse temperature, a property referred to as relevance of the disorder. This criterion in turn is used to show that the regimes of relevant and irrelevant disorder are separated by a unique inverse critical temperature. Subsequently, upper and lower bounds are derived for the inverse critical temperature, from which sufficient conditions under which it is strictly positive, respectively, finite are obtained. The former condition is believed to be necessary as well, a problem that we will address in a forthcoming paper. Random pinning has been studied extensively in the literature. The present paper opens up a window with a variational view. Our variational formulas for the quenched and the annealed critical curve are new and provide valuable insight into the nature of the phase transition. Our results on the inverse critical temperature drawn from these variational formulas are not new, but they offer an alternative approach that is exible enough to be extended to other models of random polymers with disorder. Key words and phrases. Random polymer, random charges, localization vs. delocalization, quenched vs. annealed large deviation principle, quenched vs. annealed critical curve, relevant vs. irrelevant disorder, critical temperature

Free energy of a copolymer in a micro-emulsion

In this paper we consider a two-dimensional model of a copolymer consisting of a random concatenation of hydrophilic and hydrophobic monomers, immersed in a micro-emulsion of random droplets of oil and water. The copolymer interacts with the micro-emulsion through an interaction Hamiltonian that favors matches and disfavors mismatches between the monomers and the solvents, in such a way that the interaction with the oil is stronger than with the water. The configurations of the copolymers are directed self-avoiding paths in which only steps up, down and right are allowed. The configurations of the micro-emulsion are square blocks with oil and water arranged in percolation-type fashion. The only restriction imposed on the path is that in every column of blocks its vertical displacement on the block scale is bounded. The way in which the copolymer enters and exits successive columns of blocks is a directed self-avoiding path as well, but on the block scale. We refer to this path as the coarse-grained self-avoiding path. We are interested in the limit as the copolymer and the blocks become large, in such a way that the copolymer spends a long time in each block yet visits many blocks. This is a coarse-graining limit in which the space-time scales of the copolymer and of the micro-emulsion become separated. We derive a variational formula for the quenched free energy per monomer, where quenched means that the disorder in the copolymer and the disorder in the micro-emulsion are both frozen. In a sequel paper we will analyze this variational formula and identify the phase diagram. It turns out that there are two regimes, supercritical and subcritical, depending on whether the oil blocks percolate or not along the coarse-grained self-avoiding path. The phase diagrams in the two regimes turn out to be completely different. In earlier work we considered the same model, but with an unphysical restriction: paths could enter and exit blocks only at diagonally opposite corners. Without this restriction, the variational formula for the quenched free energy is more complicated, but in the sequel paper we will see that it is still tractable enough to allow for a qualitative analysis of the phase diagram. Part of our motivation is that our model can be viewed as a coarse-grained version of the well-known directed polymer with bulk disorder. The latter has been studied intensively in the literature, but no variational formula is as yet available