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Phase Transitions in "Small" Systems - A Challenge for Thermodynamics
Traditionally, phase transitions are defined in the thermodynamic limit only.
We propose a new formulation of equilibrium thermo-dynamics that is based
entirely on mechanics and reflects just the {\em geometry and topology} of the
N-body phase-space as function of the conserved quantities, energy, particle
number and others. This allows to define thermo-statistics {\em without the use
of the thermodynamic limit}, to apply it to ``Small'' systems as well and to
define phase transitions unambiguously also there. ``Small'' systems are
systems where the linear dimension is of the characteristic range of the
interaction between the particles. Also astrophysical systems are ``Small'' in
this sense. Boltzmann defines the entropy as the logarithm of the area
of the surface in the mechanical N-body phase space at
total energy E. The topology of S(E,N) or more precisely, of the curvature
determinant allows the classification of phase
transitions {\em without taking the thermodynamic limit}. The topology gives
further a simple and transparent definition of the {\em order parameter.}
Attention: Boltzmann's entropy S(E) as defined here is different from the
information entropy and can even be non-extensive and convex.Comment: 8 pages, 4 figures, Invited paper for CRIS200
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