Dilution effects in Ho2−x_{2-x}Yx_xSn2_2O7_7: from the Spin Ice to the single-ion magnet

A study of the modifications of the magnetic properties of Ho$_{2-x}$Y$_x$Sn$_2$O$_7$ upon varying the concentration of diamagnetic Y$^{3+}$ ions is presented. Magnetization and specific heat measurements show that the Spin Ice ground-state is only weakly affected by doping for $x\leq 0.3$, even if non-negligible changes in the crystal field at Ho$^{3+}$ occur. In this low doping range $\mu$SR relaxation measurements evidence a modification in the low-temperature dynamics with respect to the one observed in the pure Spin Ice. For $x\to 2$, or at high temperature, the dynamics involve fluctuations among Ho$^{3+}$ crystal field levels which give rise to a characteristic peak in $^{119}$Sn nuclear spin-lattice relaxation rate. In this doping limit also the changes in Ho$^{3+}$ magnetic moment suggest a variation of the crystal field parameters.Comment: 4 pages, 5 figures, proceedings of HFM2008 Conferenc

Intracluster stellar population properties from N-body cosmological simulations -- I. Constraints at z=0z=0

We use a high resolution collisionless simulation of a Virgo--like cluster in a $\Lambda$CDM cosmology to determine the velocity and clustering properties of the diffuse stellar component in the intracluster region at the present epoch. The simulated cluster builds up hierarchically and tidal interactions between member galaxies and the cluster potential produce a diffuse stellar component free-flying in the intracluster medium. Here we adopt an empirical scheme to identify tracers of the stellar component in the simulation and hence study its properties. We find that at $z=0$ the intracluster stellar light is mostly unrelaxed in velocity space and clustered in structures whose typical clustering radii are about 50 kpc at R=400--500 kpc from the cluster center, and predict the radial velocity distribution expected in spectroscopic follow-up surveys. Finally, we compare the spatial clustering in the simulation with the properties of the Virgo intracluster stellar population, as traced by ongoing intracluster planetary nebulae surveys in Virgo. The preliminary results indicate a substantial agreement with the observed clustering properties of the diffuse stellar population in Virgo.Comment: 39 pages, 10 figures, 8 tables, in press on ApJ. Bad image quality for some figures because resizing is neede

Density profiles and substructure of dark matter halos: converging results at ultra-high numerical resolution

Can N-body simulations reliably determine the structural properties of dark matter halos? Focussing on a Virgo-sized galaxy cluster, we increase the resolution of current ``high resolution simulations'' by almost an order of magnitude to examine the convergence of the important physical quantities. We have 4 million particles within the cluster and force resolution 0.5 kpc/h (0.05% of the virial radius). The central density profile has a logarithmic slope of -1.5, as found in lower resolution studies of the same halo, indicating that the profile has converged to the ``physical'' limit down to scales of a few kpc. Also the abundance of substructure is consistent with that derived from lower resolution runs; on the scales explored, the mass and circular velocity functions are close to power laws of exponents ~ -1.9 and -4. Overmerging appears to be globally unimportant for suhalos with circular velocities > 100 km/s. We can trace most of the cluster progenitors from z=3 to the present; the central object (the dark matter analog of a cD galaxy)is assembled between z=3 and 1 from the merging of a dozen halos with v_circ \sim 300 km/s. The mean circular velocity of the subhalos decreases by ~ 20% over 5 billion years, due to tidal mass loss. The velocity dispersions of halos and dark matter globally agree within 10%, but the halos are spatially anti-biased, and, in the very central region of the cluster, they show positive velocity bias; however, this effect appears to depend on numerical resolution.Comment: 19 pages, 13 figures, ApJ, in press. Text significantly clarifie

Electrodeposited cu thin layers as low cost and effective underlayers for Cu2O photocathodes in photoelectrochemical water electrolysis

Cu2O is one of the most studied semiconductors for photocathodes in photoelectrochemical water splitting (PEC-WS). Its low stability is counterbalanced by good activity, provided that a suitable underlayer/support is used. While Cu2O is mostly studied on Au underlayers, this paper proposes Cu(0) as a low-cost, easy to prepare and highly efficient alternative. Cu and Cu2O can be electrodeposited from the same bath, thus allowing in principle to tune the final material\u2019s physico-chemical properties with high precision with a scalable method. Electrodes and photoelectrodes are studied by means of electrochemical methods (cyclic voltammetry, Pb underpotential deposition) and by ex-situ X-ray absorption spectroscopy (XAS). While the potential applied for the deposition of Cu has no influence on the bulk structure and on the photocurrent displayed by the semiconductor, it plays a role on the dark currents, making this strategy promising for improving the material\u2019s stability. Au/Cu2O and Cu/Cu2O show similar performances, the latter having clear advantages in view of future use in practical applications. The influence of Cu underlayer thickness was also evaluated in terms of obtained photocurrent

The descendents of Lyman Break Galaxies in galaxy clusters: spatial distribution and orbital properties

We combine semi-analytical methods with a ultra-high resolution simulation of a galaxy cluster (of mass 2.3 10^14h-1Msolar, and 4 10^6 particles within its virial radius) formed in a standard CDM universe to study the spatial distribution and orbital properties of the present-day descendents of Lyman Break Galaxies (LBGs). At the present time only five (out of 12) of halos containing LBGs survive as separate entities inside the cluster virial radius. Their circular velocities are in the range 200 - 550 km/sec. Seven halos merged together to form the central object at the very center of the cluster. Using semi-analytical modeling of galaxy evolution we show that descendents of halos containing LBGs now host giant elliptical galaxies. Galaxy orbits are radial, with a pericenter to apocenter ratio of about 1:5. The orbital eccentricities of LBGs descendents are statistically indistinguishable from those of the average galaxy population inside the cluster, suggesting that the orbits of these galaxies are not significantly affected by dynamical friction decay after the formation of the cluster's main body. In this cluster, possibly due to its early formation time, the descendents of LBGs are contained within the central 60% of the cluster virial radius and have an orbital velocity dispersion lower than the global galaxy population, originating a mild luminosity segregation for the brightest cluster members. Mass estimates based only on LBGs descendents (especially including the central cD) reflect this bias in space and velocity and underestimate the total mass of this well virialized cluster by up to a factor of two compared to estimates using at least 20 cluster members.Comment: 6 Pages, 2 Postscript figures. Submitted to Ap

Cold collapse and the core catastrophe

We show that a universe dominated by cold dark matter fails to reproduce the rotation curves of dark matter dominated galaxies, one of the key problems that it was designed to resolve. We perform numerical simulations of the formation of dark matter halos, each containing \gsim 10^6 particles and resolved to 0.003 times the virial radius, allowing an accurate comparison with rotation curve data. A good fit to both galactic and cluster sized halos can be achieved using the density profile rho(r) \propto [(r/r_s)^1.5(1+(r/r_s)^1.5)]^-1, where r_s is a scale radius. This profile has a steeper asymptotic slope, rho(r) \propto r^-1.5, and a sharper turnover than found by lower resolution studies. The central structure of relaxed halos that form within a hierarchical universe has a remarkably small scatter (unrelaxed halos would not host disks). We compare the results with a sample of dark matter dominated, low surface brightness (LSB) galaxies with circular velocities in the range 100-300 km/s. The rotation curves of disks within cold dark matter halos rise too steeply to match these data which require a constant mass density in the central regions. The same conclusion is reached if we compare the scale free shape of observed rotation curves with the simulation data. It is important to confirm these results using stellar rather than HI rotation curves for LSB galaxies. We test the effects of introducing a cut-off in the power spectrum that may occur in a universe dominated by warm dark matter. In this case halos form by a monolithic collapse but the final density profile hardly changes, demonstrating that the merger history does not play a role in determining the halo structure.Comment: Latex 13 pages, 4 figures. Submitted to MNRAS. High resolution colour version of figure 4 and other N-body images here: http://star-www.dur.ac.uk:80/~moore/images

Dark Matter Substructure in Galactic Halos

We use numerical simulations to examine the substructure within galactic and cluster mass halos that form within a hierarchical universe. Clusters are easily reproduced with a steep mass spectrum of thousands of substructure clumps that closely matches observations. However, the survival of dark matter substructure also occurs on galactic scales, leading to the remarkable result that galaxy halos appear as scaled versions of galaxy clusters. The model predicts that the virialised extent of the Milky Way's halo should contain about 500 satellites with circular velocities larger than Draco and Ursa-Minor i.e. bound masses > 10^8Mo and tidally limited sizes > kpc. The substructure clumps are on orbits that take a large fraction of them through the stellar disk leading to significant resonant and impulsive heating. Their abundance and singular density profiles has important implications for the existence of old thin disks, cold stellar streams, gravitational lensing and indirect/direct detection experiments.Comment: Astrophysical Journal Letters. 4 pages, latex. Simulation images and movies at http://star-www.dur.ac.uk:80/~moore

In Situ X-ray Absorption Spectroscopy Study of the Deactivation Mechanism of a Ni-SrTiO3 Photocatalyst Slurry Active in Water Splitting

We used in situ X-ray absorption spectroscopy (XAS) to investigate the composition-performance correlation of Ni-SrTiO3 photocatalysts active for water splitting. After preparation and exposure to ambient conditions, the Ni particles on SrTiO3 consist of Ni(0) and Ni(II) phases, with a 4:1 at % ratio, in a metal/oxide core/shell configuration, as confirmed by XPS and TEM-EDX. In situ XAS experiments using an aqueous slurry of the Ni-SrTiO3 photocatalyst and simultaneous continuous exposure to 365 nm light with a power density of 100 mW cm(-2) and the X-rays do not reveal significant changes in oxidation state of the Ni particles. Contrarily, when the X-rays are discontinuously applied, UV excitation leads to oxidation of a significant fraction of Ni(0) to Ni(II), specifically to NiO and Ni(OH)(2) phases, along with cocatalyst restructuring. Ni dissolution or oxidation to higher valence states (e.g., Ni(III)) was not observed. The UV light-induced oxidation of Ni(0) causes the hydrogen evolution rate to drop to similar rates as observed for pristine SrTiO3, suggesting that Ni(0) is the active phase for H-2 generation. Our results underscore the importance of assessing the effects of (continuous) X-ray exposure to (photo)catalyst-containing aqueous slurries during in situ XAS experiments, which can significantly influence the observation of compositional and structural changes in the (photo)catalysts. We ascribe this to X-ray induced water photolysis and formation of free electrons, which in this study quench SrTiO3 photoholes and prevent Ni oxidation

On the Detectability of Galactic Dark Matter Annihilation into Monochromatic Gamma-rays

Monochromatic gamma-rays are thought to be the smoking gun signal for identifying the dark matter annihilation. However, the flux of monochromatic gamma-rays is usually suppressed by the virtual quantum effects since dark matter should be neutral and does not couple with gamma-rays directly. In the work we study the detection strategy of the monochromatic gamma-rays in a future space-based detector. The monochromatic gamma-ray flux is calculated by assuming supersymmetric neutralino as a typical dark matter candidate. We discuss both the detection focusing on the Galactic center and in a scan mode which detects gamma-rays from the whole Galactic halo are compared. The detector performance for the purpose of monochromatic gamma-rays detection, with different energy and angular resolution, field of view, background rejection efficiencies, is carefully studied with both analytical and fast Monte-Carlo method