Boosting the Performance of WO3/n‐Si Heterostructures for Photoelectrochemical Water Splitting: from the Role of Si to Interface Engineering

Metal oxide/Si heterostructures make up an exciting design route to high‐performance electrodes for photoelectrochemical (PEC) water splitting. By monochromatic light sources, contributions of the individual layers in WO3/n‐Si heterostructures are untangled. It shows that band bending near the WO3/n‐Si interface is instrumental in charge separation and transport, and in generating a photovoltage that drives the PEC process. A thin metal layer inserted at the WO3/n‐Si interface helps in establishing the relation among the band bending depth, the photovoltage, and the PEC activity. This discovery breaks with the dominant Z‐scheme design idea, which focuses on increasing the conductivity of an interface layer to facilitate charge transport, but ignores the potential profile around the interface. Based on the analysis, a high‐work‐function metal is predicted to provide the best interface layer in WO3/n‐Si heterojunctions. Indeed, the fabricated WO3/Pt/n‐Si photoelectrodes exhibit a 2 times higher photocurrent density at 1.23 V versus reversible hydrogen electrode (RHE) and a 10 times enhancement at 1.6 V versus RHE compared to WO3/n‐Si. Here, it is essential that the native SiO2 layer at the interface between Si and the metal is kept in order to prevent Fermi level pinning in the Schottky contact between the Si and the metal.</p

Software architecture for control and data acquisition of linear plasma generator Magnum-PSI

The FOM Institute DIFFER – Dutch Institute for Fundamental Energy Research has completed the construction phase of Magnum-PSI, a magnetized, steady-state, large area, high-flux linear plasma beam generator to study plasma surface interactions under ITER divertor conditions. Magnum-PSI consists of several hardware subsystems, and a variety of diagnostic systems. The COntrol, Data Acquisition and Communication (CODAC) system integrates these subsystems and provides a complete interface for the Magnum-PSI users. Integrating it all, from the lowest hardware level of sensors and actuators, via the level of networked PLCs and computer systems, up to functions and classes in programming languages, demands a sound and modular software architecture, which is extendable and scalable for future changes. This paper describes this architecture, and the modular design of the software subsystems. The design is implemented in the CODAC system at the level of services and subsystems (the overall software architecture), as well as internally in the software subsystems.</p

Power handling of a liquid-metal based CPS structure under high steady-state heat and particle fluxes

Liquid metal infused capillary porous structures (CPSs) are considered as a potential divertor solution for DEMO due to their potential power handling capability and resilience to long term damage. In this work the power handling and performance of such Sn-based CPS systems is assessed both experimentally and via modelling. A Sn-CPS target was exposed to heat fluxes of up to 18.1 MW m−2 in He plasma in the Pilot-PSI linear device. Post-mortem the target showed no damage to nor any surface exposure of the underlying W-CPS felt. The small pore size (∼40 µm) employed resulted in no droplet formation from the target in agreement with calculated Rayleigh-Taylor and Kelvin-Helmoholtz instability thresholds. The temperature response of the Sn-target was used to determine the thermal conductivity of the mixed Sn-CPS material using COMSOL modelling. These values were then used via further finite element analysis to extrapolate to DEMO relevant monoblock designs and estimate the maximum power handling achievable based on estimated temperature windows for all component elements of the design. For an optimized design a heat-load of up to 20 MW m−2 may be received while the use of CPS also offers other potential design advantages such as the removal of interlayer requirements

Thermographic investigation of the effect of plasma exposure on the surface of a MAST upgrade divertor tile in Magnum-PSI

One of the issues faced by future fusion devices will be high divertor target heat loads. Alternative divertors can promote detachment, flux expansion and dissipation mechanisms to mitigate these heat loads. They have been investigated in several devices including TCV and DIII-D, and will be investigated on MAST-U. To evaluate their effectiveness, accurate target heat flux and power balance measurements are required in these machines. Infrared (IR) thermography is a widely used technique to determine the target heat flux, but is susceptible to surface effects and emissivity in carbon-walled machines. In this work, the effect of plasma exposure on graphite is assessed to understand what may happen in MAST-U. A sample of fine grain graphite, as used on MAST-U, is exposed to 30min plasma exposures, with density ne=6 × 1018m−3 and temperature Te=0.08eV as measured by Thomson scattering. During these pulses, the temperature is measured by a medium wave IR camera and is seen to decrease by ≈70 °C over the course of 3h of plasma exposure. Pyrometer measurements suggest that the IR camera data is affected by a change in the surface emissivity. Profilometry confirms erosion of graphite at the tile centre to a depth of ≈100µm, and a larger region of deposition further out, amounting to ≈40µm of material

Thermographic investigation of the effect of plasma exposure on the surface of a MAST upgrade divertor tile in Magnum-PSI

One of the issues faced by future fusion devices will be high divertor target heat loads. Alternative divertors can promote detachment, flux expansion and dissipation mechanisms to mitigate these heat loads. They have been investigated in several devices including TCV and DIII-D, and will be investigated on MAST-U. To evaluate their effectiveness, accurate target heat flux and power balance measurements are required in these machines. Infrared (IR) thermography is a widely used technique to determine the target heat flux, but is susceptible to surface effects and emissivity in carbon-walled machines. In this work, the effect of plasma exposure on graphite is assessed to understand what may happen in MAST-U. A sample of fine grain graphite, as used on MAST-U, is exposed to 30min plasma exposures, with density ne=6 × 1018m−3 and temperature Te=0.08eV as measured by Thomson scattering. During these pulses, the temperature is measured by a medium wave IR camera and is seen to decrease by ≈70 °C over the course of 3h of plasma exposure. Pyrometer measurements suggest that the IR camera data is affected by a change in the surface emissivity. Profilometry confirms erosion of graphite at the tile centre to a depth of ≈100µm, and a larger region of deposition further out, amounting to ≈40µm of materia

Electrochemistry of Sputtered Hematite Photoanodes: A Comparison of Metallic DC versus Reactive RF Sputtering

The water splitting activity of hematite is sensitive to the film processing parameters due to limiting factors such as a short hole diffusion length, slow oxygen evolution kinetics, and poor light absorptivity. In this work, we use direct current (DC) magnetron sputtering as a fast and cost-effective route to deposit metallic iron thin films, which are annealed in air to obtain well-adhering hematite thin films on F: SnO2-coated glass substrates. These films are compared to annealed hematite films, which are deposited by reactive radio frequency (RF) magnetron sputtering, which is usually used for depositing metal oxide thin films, but displays an order of magnitude lower deposition rate. We find that DC sputtered films have much higher photoelectrochemical activity than reactive RF sputtered films. We show that this is related to differences in the morphology and surface composition of the films as a result of the different processing parameters. This in turn results in faster oxygen evolution kinetics and lower surface and bulk recombination effects. Thus, fabricating hematite thin films by fast and cost-efficient metallic iron deposition using DC magnetron sputtering is shown to be a valid and industrially relevant route for hematite photoanode fabrication.</p

Power deposition behavior of high-density transient hydrogen plasma on tungsten in Magnum-PSI

The lifetime of plasma-facing components (PFCs) will have a strong influence on the efficiency and viability of future fusion power plants. However, the PFCs suffer from thermal stresses and physical sputtering induced by edge-localized modes (ELMs). ELMs in future fusion devices are expected to occur with a high plasma density compared to current day devices such that coupling of recycling neutrals and plasma ions will be strong. Because of the scale hierarchy of future fusion devices compared to the present ones, the influence of this coupling is difficult to predict. Here, we investigate the ELM-like hydrogen plasma induced heat loads on tungsten in the linear device Magnum-PSI, producing similar to 1 ms plasma pulses with electron densities up to 3.5 x 10(21) m(-3). A combination of time-resolved Thomson scattering and coherent Thomson scattering was used to acquire plasma parameters in front of the target. Moreover, a fast infrared camera coupled to finite element thermal analyses allowed to determine the deposited heat loads on the target. We found a significant inconsistency between the plasma power calculated with a conventional collisionless sheath model and the absorbed power by the target. Moreover, plasma stagnation upstream and plasma cooling downstream were observed during the pulses. The observations are explained based on ionization and elastic collisions between the recycling neutrals and plasma ions. The results highlight the impact of plasma-neutral interaction on the power deposition behavior of ELM-like hydrogen plasma on tungsten.</p

Operational characteristics of the superconducting high flux plasma generator Magnum-PSI

The interaction of intense plasma impacting on the wall of a fusion reactor is an area of high and increasing importance in the development of electricity production from nuclear fusion. In the Magnum-PSI linear device, an axial magnetic field confines a high density, low temperature plasma produced by a wall stabilized DC cascaded arc into an intense magnetized plasma beam directed onto a target. The experiment has shown its capability to reach conditions that enable fundamental studies of plasma-surface interactions in the regime relevant for fusion reactors such as ITER: 1023–1025 m−2s−1 hydrogen plasma flux densities at 1–5 eV for tens of seconds by using conventional electromagnets. Recently the machine was upgraded with a superconducting magnet, enabling steady-state magnetic fields up to 2.5 T, expanding the operational space to high fluence capabilities for the first time. Also the diagnostic suite has been expanded by a new 4-channel resistive bolometer array and ion beam analysis techniques for surface analysis after plasma exposure of the target. A novel collective Thomson scattering system has been developed and will be implemented on Magnum-PSI. In this contribution, the current status, capabilities and performance of Magnum-PSI are presented