14 research outputs found
Electronic structures of doped anatase : (M=Co, Mn, Fe, Ni)
We have investigated electronic structures of a room temperature diluted
magnetic semiconductor : Co-doped anatase . We have obtained the
half-metallic ground state in the local-spin-density approximation(LSDA) but
the insulating ground state in the LSDA++SO incorporating the spin-orbit
interaction. In the stoichiometric case, the low spin state of Co is realized
with the substantially large orbital moment. However, in the presence of oxygen
vacancies near Co, the spin state of Co becomes intermediate. The
ferromagnetisms in the metallic and insulating phases are accounted for by the
double-exchange-like and the superexchange mechanism, respectively. Further,
the magnetic ground states are obtained for Mn and Fe doped ,
while the paramagnetic ground state for Ni-doped .Comment: 5 pages, 4 figure
Coordination and chemical effects on the structural, electronic and magnetic properties in Mn pnictides
Simple structures of MnX binary compounds, namely hexagonal NiAs and
zincblende, are studied as a function of the anion (X = Sb, As, P) by means of
the all-electron FLAPW method within local spin density and generalized
gradient approximations. An accurate analysis of the structural, electronic and
magnetic properties reveals that the cubic structure greatly favours the
magnetic alignment in these compounds leading to high magnetic moments and
nearly half-metallic behaviour for MnSb and MnAs. The effect of the anion
chemical species is related to both its size and the possible hybridization
with the Mn states; both contributions are seen to hinder the magnitude of
the magnetic moment for small and light anions. Our results are in very good
agreement with experiment - where available - and show that the generalized
gradient approximation is essential to correctly recover both the equilibrium
volume and magnetic moment.Comment: 18 pages and 4 figures, Latex-file, submitted to Phys.Rev.
Electronic structure and magnetism of Mn doped GaN
Mn doped semiconductors are extremely interesting systems due to their novel
magnetic properties suitable for the spintronics applications. It has been
shown recently by both theory and experiment that Mn doped GaN systems have a
very high Curie temperature compared to that of Mn doped GaAs systems. To
understand the electronic and magnetic properties, we have studied Mn doped GaN
system in detail by a first principles plane wave method. We show here the
effect of varying Mn concentration on the electronic and magnetic properties.
For dilute Mn concentration, states of Mn form an impurity band completely
separated from the valence band states of the host GaN. This is in contrast to
the Mn doped GaAs system where Mn states in the gap lie very close to the
valence band edge and hybridizes strongly with the delocalized valence band
states.
To study the effects of electron correlation, LSDA+U calculations have been
performed.
Calculated exchange interaction in (Mn,Ga)N is short ranged in contrary to
that in (Mn,Ga)As where the strength of the ferromagnetic coupling between Mn
spins is not decreased substantially for large Mn-Mn separation. Also, the
exchange interactions are anisotropic in different crystallographic directions
due to the presence or absence of connectivity between Mn atoms through As
bonds.Comment: 6 figures, submitted to Phys. Rev.
Magnetic Interactions and Transport in (Ga,Cr)As
The magnetic, transport, and structural properties of (Ga,Cr)As are reported.
Zincblende GaCrAs was grown by low-temperature molecular beam
epitaxy (MBE). At low concentrations, x0.1, the materials exhibit unusual
magnetic properties associated with the random magnetism of the alloy. At low
temperatures the magnetization M(B) increases rapidly with increasing field due
to the alignment of ferromagnetic units (polarons or clusters) having large
dipole moments of order 10-10. A standard model of
superparamagnetism is inadequate for describing both the field and temperature
dependence of the magnetization M(B,T). In order to explain M(B) at low
temperatures we employ a distributed magnetic moment (DMM) model in which
polarons or clusters of ions have a distribution of moments. It is also found
that the magnetic susceptibility increases for decreasing temperature but
saturates below T=4 K. The inverse susceptibility follows a linear-T
Curie-Weiss law and extrapolates to a magnetic transition temperature
=10 K. In magnetotransport measurements, a room temperature resistivity
of =0.1 cm and a hole concentration of cm
are found, indicating that Cr can also act as a acceptor similar to Mn. The
resistivity increases rapidly for decreasing temperature below room
temperature, and becomes strongly insulating at low temperatures. The
conductivity follows exp[-(T/T)] over a large range of
conductivity, possible evidence of tunneling between polarons or clusters.Comment: To appear in PRB 15 Mar 200
Theory of spin-polarized bipolar transport in magnetic p-n junctions
The interplay between spin and charge transport in electrically and
magnetically inhomogeneous semiconductor systems is investigated theoretically.
In particular, the theory of spin-polarized bipolar transport in magnetic p-n
junctions is formulated, generalizing the classic Shockley model. The theory
assumes that in the depletion layer the nonequilibrium chemical potentials of
spin up and spin down carriers are constant and carrier recombination and spin
relaxation are inhibited. Under the general conditions of an applied bias and
externally injected (source) spin, the model formulates analytically carrier
and spin transport in magnetic p-n junctions at low bias. The evaluation of the
carrier and spin densities at the depletion layer establishes the necessary
boundary conditions for solving the diffusive transport equations in the bulk
regions separately, thus greatly simplifying the problem. The carrier and spin
density and current profiles in the bulk regions are calculated and the I-V
characteristics of the junction are obtained. It is demonstrated that spin
injection through the depletion layer of a magnetic p-n junction is not
possible unless nonequilibrium spin accumulates in the bulk regions--either by
external spin injection or by the application of a large bias. Implications of
the theory for majority spin injection across the depletion layer, minority
spin pumping and spin amplification, giant magnetoresistance, spin-voltaic
effect, biasing electrode spin injection, and magnetic drift in the bulk
regions are discussed in details, and illustrated using the example of a GaAs
based magnetic p-n junction.Comment: 36 pages, 11 figures, 2 table