Sterically stabilized lock and key colloids: A self-consistent field theory study

A self-consistent field theory study of lock and key type interactions between sterically stabilized colloids in polymer solution is performed. Both the key particle and the lock cavity are assumed to have cylindrical shape, and their surfaces are uniformly grafted with polymer chains. The lock-key potential of mean force is computed for various model parameters, such as length of free and grafted chains, lock and key size matching, free chain volume fraction, grafting density, and various enthalpic interactions present in the system. The lock-key interaction is found to be highly tunable, which is important in the rapidly developing field of particle self-assembly

The eddy heat-flux in rotating turbulent convection

The three components of the heat-flux vector $F =\rho C_p are numerically computed for a stratified rotating turbulent convection using the NIRVANA code in a flat box. The latitudinal component$F_\theta$proves to be negative (positive) in the northern (southern) hemisphere so that the heat always flows towards the poles. As a surprise, the radial heat-flux$F_r$peaks at the equator rather than at the poles (Taylor numbers O(10^6)). The same behavior is observed for the radial turbulence intensity$ which for \emph{free} turbulence is also believed to peak at the poles (see Eq. (19) below). As we can show, however, the consequences of this unexpected result (also obtained by Kaepylae, Korpi and Tuominen 2004) for the theory of differential rotation are small as mainly the F_\theta$is responsible to solve the `Taylor number puzzle'. In all our simulations the azimuthal component$F_\phi$proves to be negative so that the rotating turbulence produces an westwards directed azimuthal heat-flux which should be observable. Fluctuations with higher temperature are expected to be anticorrelated with their own angular velocity fluctuations. We find this rotation-induced result as understandable as the$F_\phi$ is closely related to the radial \Lambda-effect which is known to be also negative in stratified and rapidly rotating convection zones.Comment: 8 pages, 9 figures, Astron. Astrophys. (subm.

Hysteresis in the de Haas-van Alphen Effect

A hysteresis loop is observed for the first time in the de Haas-van Alphen (dHvA) effect of beryllium at low temperatures and quantizing magnetic field applied parallel to the hexagonal axis of the single crystal. The irreversible behavior of the magnetization occurs at the paramagnetic part of the dHvA period in conditions of Condon domain formation arising by strong enough dHvA amplitude. The resulting extremely nonlinear response to a very small modulation field offers the possibility to find in a simple way the Condon domain phase diagram. From a harmonic analysis, the shape and size of the hysteresis loop is constructed.Comment: 4 pages, 5 figures, submitted to PR

59Co NMR study of the Co states in superconducting and anhydrous cobaltates

$^{59}$Co NMR spectra in oriented powders of Na$_{0.35}$CoO$_{2}$ and in its hydrated superconducting phase (HSC) Na$_{0.35}$CoO$_{2}$,1.3H$_{2}$O reveal a single electronic Co state with identical $T$ independent NMR shift tensor. These phases differ markedly from Na$_{0.7}$CoO$_{2}$, in which we resolve 3 types of Co sites. The large T variation of their spin susceptibilities $\chi ^{s}$ and the anisotropy of the orbital susceptibility $\chi ^{orb}$ allow us to conclude that charge disproportionation occurs, in a non magnetic Co$^{3+}$ and two magnetic sites with about 0.3 and 0.7 holes in the $t_{2g}$ multiplet. The data are consistent with those for the single Co site in the anhydrous and HSC phase assuming the expected Co$^{3.65+}$ charge.Comment: 5 pages, 3 figures, accepted for publication in Phys. Rev. Let