62 research outputs found
Theory of photoinduced charge transfer in weakly coupled donor-acceptor conjugated polymers: application to an MEH-PPV:CN-PPV pair
In a pair of coupled donor-acceptor conjugated polymer chains, it is possible
for an exciton photoexcited on either polymer to decay into a hole in the donor
polymer's valence band and an electron in the conduction band of the acceptor
polymer. We calculate the corresponding exciton decay rate and its dependence
on inter-polymer distance. For a pair of derivatives of poly(phenylene
vinylene), PPV, specifically poly[2-methoxy, 5-(2-ethyl-hexyloxy)-1, 4
PPV], MEH-PPV, and poly(2,5-hexyloxy -phenylene cyanovinylene), CN-PPV, at a
separation of 6 \AA the characteristic decay time is 2.2 ps, whereas at 4 \AA
it is fs.Comment: 9 pages, RevTeX, 4 PS files, to be published in a special issue of
Chem. Phy
Transport in -Sexithiophene Films
The field-effect mobility of hole polarons in -sexithiophene,
measured in thin film transistors, was shown to be well fitted by Holstein's
small polaron theory. Unfortunately, Holstein's formulation is based on an
integral that does not converge. We show that the data are well fitted by a
theory of polaron transport that was successful in accounting for mobility in
molecular crystals of naphthalene.Comment: 10 pages, RevTex, one PostScript file aviable upon reques
Polarons with a twist
We consider a polaron model where molecular \emph{rotations} are important.
Here, the usual hopping between neighboring sites is affected directly by the
electron-phonon interaction via a {\em twist-dependent} hopping amplitude. This
model may be of relevance for electronic transport in complex molecules and
polymers with torsional degrees of freedom, such as DNA, as well as in
molecular electronics experiments where molecular twist motion is significant.
We use a tight-binding representation and find that very different polaronic
properties are already exhibited by a two-site model -- these are due to the
nonlinearity of the restoring force of the twist excitations, and of the
electron-phonon interaction in the model. In the adiabatic regime, where
electrons move in a {\em low}-frequency field of twisting-phonons, the
effective splitting of the energy levels increases with coupling strength. The
bandwidth in a long chain shows a power-law suppression with coupling, unlike
the typical exponential dependence due to linear phonons.Comment: revtex4 source and one eps figur
Quadratic solitons as nonlocal solitons
We show that quadratic solitons are equivalent to solitons of a nonlocal Kerr
medium. This provides new physical insight into the properties of quadratic
solitons, often believed to be equivalent to solitons of an effective saturable
Kerr medium. The nonlocal analogy also allows for novel analytical solutions
and the prediction of novel bound states of quadratic solitons.Comment: 4 pages, 3 figure
Phonon-drag effects on thermoelectric power
We carry out a calculation of the phonon-drag contribution to the
thermoelectric power of bulk semiconductors and quantum well structures for the
first time using the balance equation transport theory extended to the weakly
nonuniform systems. Introducing wavevector and phonon-mode dependent relaxation
times due to phonon-phonon interactions, the formula obtained can be used not
only at low temperatures where the phonon mean free path is determined by
boundary scattering, but also at high temperatures. In the linear transport
limit, is equivalent to the result obtained from the Boltzmann equation
with a relaxation time approximation. The theory is applied to experiments and
agreement is found between the theoretical predictions and experimental
results. The role of hot-electron effects in is discussed. The importance
of the contribution of to thermoelectric power in the hot-electron
transport condition is emphasized.Comment: 8 pages, REVTEX 3.0, 7 figures avilable upon reques
Thermoelectric power of nondegenerate Kane semiconductors under the conditions of mutual electron-phonon drag in a high electric field
The thermoelectric power of nondegenerate Kane semiconductors with due regard
for the electron and phonon heating, and their thermal and mutual drags is
investigated. The electron spectrum is taken in the Kane two-band form. It is
shown that the nonparabolicity of electron spectrum significantly influences
the magnitude of the thermoelectric power and leads to a change of its sign and
dependence on the heating electric field. The field dependence of the
thermoelectric power is determined analytically under various drag conditions.Comment: 25 pages, RevTex formatted, 3 table
Large scale numerical investigation of excited states in poly(phenylene)
A density matrix renormalisation group scheme is developed, allowing for the
first time essentially exact numerical solutions for the important excited
states of a realistic semi-empirical model for oligo-phenylenes. By monitoring
the evolution of the energies with chain length and comparing them to the
experimental absorption peaks of oligomers and thin films, we assign the four
characteristic absorption peaks of phenyl-based polymers. We also determine the
position and nature of the nonlinear optical states in this model.Comment: RevTeX, 10 pages, 4 eps figures included using eps
Investigation of conduction band structure, electron scattering mechanisms and phase transitions in indium selenide by means of transport measurements under pressure
In this work we report on Hall effect, resistivity and thermopower
measurements in n-type indium selenide at room temperature under either
hydrostatic and quasi-hydrostatic pressure. Up to 40 kbar (= 4 GPa), the
decrease of carrier concentration as the pressure increases is explained
through the existence of a subsidiary minimum in the conduction band. This
minimum shifts towards lower energies under pressure, with a pressure
coefficient of about -105 meV/GPa, and its related impurity level traps
electrons as it reaches the band gap and approaches the Fermi level. The
pressure value at which the electron trapping starts is shown to depend on the
electron concentration at ambient pressure and the dimensionality of the
electron gas. At low pressures the electron mobility increases under pressure
for both 3D and 2D electrons, the increase rate being higher for 2D electrons,
which is shown to be coherent with previous scattering mechanisms models. The
phase transition from the semiconductor layered phase to the metallic sodium
cloride phase is observed as a drop in resistivity around 105 kbar, but above
40 kbar a sharp nonreversible increase of the carrier concentration is
observed, which is attributed to the formation of donor defects as precursors
of the phase transition.Comment: 18 pages, Latex, 10 postscript figure
Coherent electron-phonon coupling and polaron-like transport in molecular wires
We present a technique to calculate the transport properties through
one-dimensional models of molecular wires. The calculations include inelastic
electron scattering due to electron-lattice interaction. The coupling between
the electron and the lattice is crucial to determine the transport properties
in one-dimensional systems subject to Peierls transition since it drives the
transition itself. The electron-phonon coupling is treated as a quantum
coherent process, in the sense that no random dephasing due to electron-phonon
interactions is introduced in the scattering wave functions. We show that
charge carrier injection, even in the tunneling regime, induces lattice
distortions localized around the tunneling electron. The transport in the
molecular wire is due to polaron-like propagation. We show typical examples of
the lattice distortions induced by charge injection into the wire. In the
tunneling regime, the electron transmission is strongly enhanced in comparison
with the case of elastic scattering through the undistorted molecular wire. We
also show that although lattice fluctuations modify the electron transmission
through the wire, the modifications are qualitatively different from those
obtained by the quantum electron-phonon inelastic scattering technique. Our
results should hold in principle for other one-dimensional atomic-scale wires
subject to Peierls transitions.Comment: 21 pages, 8 figures, accepted for publication in Phys. Rev. B (to
appear march 2001
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