Oxidative Study of Benzaldehyde by Isoqauinolinium Bromo Chromate

The kinetics analysis of the oxidative reaction between benzaldehyde and oxidant is quinolinium Bromo chromate was reported in aqueous 40% acetic acid medium at 313 K. The rate of reaction varies first-power of [IQBC] and [H2SO4], whereas fractional-order kinetics was observed for benzaldehyde. The rate constant gradually increases with decrease in dielectric constant of the medium. The neutral salt does not alter the rate. The metal cations (Cu++) slightly accelerate the rate of oxidation when added to reaction mixture. The study rules out the participation of keto form of substrate in complex formation. Benzoic acid was identified as the end-product in stoichiometrically 1:1 based mechanism. The rate law was derived in accordance with the kinetic results

Oxidative Cleavage of Alpha Amino Acids ℓ–Glycine and ℓ–Valine By1,3-Dichloro-5,5-Dimethylhydantoin in Medium of Aqueous Acetic Acid Medium

Abstract: 1,3-dichloro-5,5-dimethylhydantoin (DCDMH) hydrolysed of this compounds leads to the formation of active positive halogen species like HOCl and H2O+Cl. The H2O+Cl in non-polar or less polar media, extensively used as a chlorinating and oxidizing agents in organic substrate. The rate of reaction is enhanced by the increasing [H+] and percentage of acetic acid. The main product of the oxidation is corresponding aldehydes. The thermodynamic parameters for the oxidation have been computed in the show step mechanism. The observed rate law was in good conformity with the mechanism

Effect of Oxidant 1, 3-Dichloro-5-5-Dimethylhydantoin and 5, 5-Dimethylhydantoin with Different Substrates: The Kinetic Measurements

The kinetic measurement with different concentration of oxidant 1,3-dichloro-5,5-dimethylhydantoin and 5,5-dimethylhydantoin with ℓ–alanine,  ℓ-glycine and ℓ–valine. The catalytic effect of acid in the reaction rate reveal an interaction between oxidants species H2O+Cl and substrates. The observed order of reactivity of ℓ-amino acids (ℓ-glycine > ℓ–alanine > ℓ-valine) was explained on the basis of hydrolysis of reacting species

Synthesis and Characterization of Novel Quadri-dentate Demi-macrocyclic Ligand Having N2O2 as its Donors

Abstract: A novel quadric-dentate demi-macrocycle of the type [C14H30N2O2] (ClO4)2¯ was synthesized by 1:2 condensation reaction at high dilution process. The desired demi-macrocycle was characterized by spectral methods such as UV-visible, IR, 1HNMR and elemental analysis. The results obtained were in close conformity with properties and proposed structure

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Not AvailableEmerging micronutrient deficiencies in different soils of the world is a threat for sustainability of agriculture. As distribution of micronutrients in soil varies spatially, site‐specific management of micronutrients by delineating regional zones (RZs) is an effective strategy for precision agriculture. The current investigation was performed to delineate RZs in a Deccan Plateau Region (DPR) of India by considering spatial variability of some soil properties and available micronutrients for efficient management of micronutrients. Altogether, 4,939 representative soil samples (with geographical coordinates) from surface (0–0.15 m depth) layers were obtained from Telangana state lying in DPR of India. After processing, soil samples were analysed for pH, electrical conductivity, soil organic carbon and available zinc, copper, iron, and manganese. Soil pH, electrical conductivity, and soil organic carbon content had mean values of 7.48 ± 0.95, 0.42 ± 0.22 dS/m and 0.48 ± 0.17%, respectively. Whereas, the mean values of available zinc, iron, copper, and manganese concentrations were 0.83 ± 0.36, 8.79 ± 4.15, 0.99 ± 0.43, and 8.79 ± 4.06 mg/kg, respectively. Geostatistical analysis divulged different distribution pattern of soil properties and available micronutrients with strong to moderate spatial dependency. The four principal components (with >1 eigenvalue) responsible for 73% of total variance were considered for analysis. Six RZs from the study area were created through geostatistical, principal component, and clustering analysis. The measured soil properties and available micronutrients in the RZs varied significantly highlighting the usefulness of RZ delineation technique for precise micronutrients management in DPR of India.Not Availabl

Genetic, Physiological, and Gene Expression Analyses Reveal That Multiple QTL Enhance Yield of Rice Mega-Variety IR64 under Drought

<div><p>Background</p><p>Rice (<i>Oryza sativa</i> L.) is a highly drought sensitive crop, and most semi dwarf rice varieties suffer severe yield losses from reproductive stage drought stress. The genetic complexity of drought tolerance has deterred the identification of agronomically relevant quantitative trait loci (QTL) that can be deployed to improve rice yield under drought in rice. Convergent evidence from physiological characterization, genetic mapping, and multi-location field evaluation was used to address this challenge.</p><p>Methodology/Principal Findings</p><p>Two pairs of backcross inbred lines (BILs) from a cross between drought-tolerant donor Aday Sel and high-yielding but drought-susceptible rice variety IR64 were produced. From six BC₄F₃ mapping populations produced by crossing the +QTL BILs with the −QTL BILs and IR64, four major-effect QTL - one each on chromosomes 2, 4, 9, and 10 - were identified. Meta-analysis of transcriptome data from the +QTL/−QTL BILs identified differentially expressed genes (DEGs) significantly associated with QTL on chromosomes 2, 4, 9, and 10. Physiological characterization of BILs showed increased water uptake ability under drought. The enrichment of DEGs associated with root traits points to differential regulation of root development and function as contributing to drought tolerance in these BILs. BC₄F₃-derived lines with the QTL conferred yield advantages of 528 to 1875 kg ha⁻¹ over IR64 under reproductive-stage drought stress in the targeted ecosystems of South Asia.</p><p>Conclusions/Significance</p><p>Given the importance of rice in daily food consumption and the popularity of IR64, the BC₄F₃ lines with multiple QTL could provide higher livelihood security to farmers in drought-prone environments. Candidate genes were shortlisted for further characterization to confirm their role in drought tolerance. Differential yield advantages of different combinations of the four QTL reported here indicate that future research should include optimizing QTL combinations in different genetic backgrounds to maximize yield advantage under drought.</p></div

Number of differentially expressed genes in +QTL and –QTL lines under two drought stress conditions.

<p>DEG, differentially expressed genes; *DTY 10.1 resolves to two adjacent regions when physically mapped to the Nipponbare reference genome.</p

Yield of QTL-introgressed IR64 lines in the target ecosystem in Bangladesh, Nepal, and India.

<p>Yield of QTL-introgressed IR64 lines in the target ecosystem in Bangladesh, Nepal, and India.</p