Red-Emitting Manganese-doped Aluminum Nitride Phosphor

We report high efficiency luminescence with a manganese-doped aluminum nitride red-emitting phosphor under 254 nm excitation, as well as its excellent lumen maintenance in fluorescent lamp conditions, making it a candidate replacement for the widely deployed europium-doped yttria red phosphor. Solid-state reaction of aluminum nitride powders with manganese metal at 1900 °C, 10 atm N2 in a reducing environment results in nitrogen deficiency, as revealed diffuse reflectance spectra. When these powders are subsequently annealed in flowing nitrogen at 1650 °C, higher nitrogen content is recovered, resulting in white powders. Silicon was added to samples as an oxygen getter to improve emission efficiency. NEXAFS spectra and DFT calculations indicate that the Mn dopant is divalent. From DFT calculations, the UV absorption band is proposed to be due to an aluminum vacancy coupled with oxygen impurity dopants, and Mn2+ is assumed to be closely associated with this site. In contrast with some previous reports, we find that the highest quantum efficiency with 254 nm excitation (Q.E. = 0.86 ± 0.14) is obtained in aluminum nitride with a low manganese doping level of 0.06 mol.%. The principal Mn2+ decay of 1.25 ms is assigned to non-interacting Mn sites, while additional components in the microsecond range appear with higher Mn doping, consistent with Mn clustering and resultant exchange coupling. Slower components are present in samples with low Mn doping, as well as strong afterglow, assigned to trapping on shallow traps followed by detrapping and subsequent trapping on Mn

Strontium and barium iodide high light yield scintillators

Europium-doped strontium and barium iodide are found to be readily growable by the Bridgman method and to produce high scintillation light yields

745 fs resolution single-shot recording at 2.1 Tsample/s and 104 Mframes/s using temporal imaging

We demonstrate temporal imaging with -42.6x time magnification of 200 ps frames with subpicosecond resolution for waveforms containing 2.5 Gb/s modulated picosecond pulses. 852 GHz signal bandwidth is captured single-shot at 104 MHz frame rates

104 MHz rate single-shot recording with subpicosecond resolution using temporal imaging

We demonstrate temporal imaging for the measurement and characterization of optical arbitrary waveforms and events. The system measures single-shot 200 ps frames at a rate of 104 MHz, where each frame is time magnified by a factor of -42.4x. Impulse response tests show that the system enables 783 fs resolution when placed at the front end of a 20 GHz oscilloscope. Modulated pulse trains characterize the system’s impulse response, jitter, and frame-to-frame variation

Red-Emitting Manganese-doped Aluminum Nitride Phosphor

We report high efficiency luminescence with a manganese-doped aluminum nitride red-emitting phosphor under 254 nm excitation, as well as its excellent lumen maintenance in fluorescent lamp conditions, making it a candidate replacement for the widely deployed europium-doped yttria red phosphor. Solid-state reaction of aluminum nitride powders with manganese metal at 1900 °C, 10 atm N2 in a reducing environment results in nitrogen deficiency, as revealed diffuse reflectance spectra. When these powders are subsequently annealed in flowing nitrogen at 1650 °C, higher nitrogen content is recovered, resulting in white powders. Silicon was added to samples as an oxygen getter to improve emission efficiency. NEXAFS spectra and DFT calculations indicate that the Mn dopant is divalent. From DFT calculations, the UV absorption band is proposed to be due to an aluminum vacancy coupled with oxygen impurity dopants, and Mn2+ is assumed to be closely associated with this site. In contrast with some previous reports, we find that the highest quantum efficiency with 254 nm excitation (Q.E. = 0.86 ± 0.14) is obtained in aluminum nitride with a low manganese doping level of 0.06 mol.%. The principal Mn2+ decay of 1.25 ms is assigned to non-interacting Mn sites, while additional components in the microsecond range appear with higher Mn doping, consistent with Mn clustering and resultant exchange coupling. Slower components are present in samples with low Mn doping, as well as strong afterglow, assigned to trapping on shallow traps followed by detrapping and subsequent trapping on Mn.This is a manuscript of an article published as Cherepy, Nerine J., Stephen A. Payne, Nicholas M. Harvey, Daniel Åberg, Zachary M. Seeley, Kiel S. Holliday, Ich C. Tran, Fei Zhou, H. Paul Martinez, Jessica M. Demeyer, Alexander D. Drobshoff, Alok M. Srivastava, Samuel J. Camardello, Holly A. Comanzo, Deborah L. Schlagel, and Thomas A. Lograsso. "Red-emitting manganese-doped aluminum nitride phosphor." Optical Materials 54 (2016): 14-21. doi: 10.1016/j.optmat.2016.02.008. Posted with permission.</p