6 research outputs found
Research data supporting Melt-Quenched Glasses from Hybrid Organic-Inorganic Perovskites
This data set contains all of the data presented in the paper ", B. K. Shaw et. al, Nature Chem, Acceptedâ. Several hybrid materials from the metal-organic framework (MOF) family have been demonstrated to form stable high temperature liquids. Quenching then results in the formation of melt-quenched MOF-glasses, which retain the inorganic-organic bonding of the three-dimensional crystalline phase. The properties of this new class of âhybridâ glass are of intense interest in both coordination polymer and glass domains. The phenomenon is however still limited to several structures. Hybrid perovskites occupy a prominent position within solid-state materials chemistry due to their functional properties such as ionic transport, photoconductivity, ferroelectricity and multiferroicity. Here we show that a series of dicyanamide-based hybrid organic-inorganic perovskites melt. Our combined experimental-computational approach demonstrates that they form glasses upon quenching, which largely retain inorganic-organic connectivity. Their very low thermal conductivities (~ 0.2 W m-1 K-1), combined with moderate electrical conductivities (10-3 â 10-5 S m-1) and polymer-like thermo-mechanical properties identify them as a new family of functional glass-formers. The README file in the main directory contains a list of each sub-folder, and the data it contains. These are correlated to the figure numbers in both main manuscript and SI, which present this data
Percolative Channels for Superionic Conduction in an Amorphous Conductor
NMR, XRD, and Ion Conductivity Data of Amorphous Conductor Material
CCDC 1047056: Experimental Crystal Structure Determination
An entry from the Cambridge Structural Database, the worldâs repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures
CCDC 1047055: Experimental Crystal Structure Determination
An entry from the Cambridge Structural Database, the worldâs repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures
Testing isomorph theory with high pressure diffraction on glass-forming liquid
Testing isomorph theory with high pressure diffraction on glass-forming liqui