Beryllium-7 and Lead-210 in the atmosphere and surface snow over the Greenland ice sheet in the summer of 1989

The concentrations of 7Be and 210Pb were measured in surface air and fresh and aging snow samples from Summit (72°20′N, 38°45′W) and Dye 3 (65°10′N, 44°45′W) Greenland, during June and July 1989. The aerosol concentrations of these radionuclides showed rapid variations at both sites, but were nearly twice as high, on average, at Summit. Concentrations in the 16 fresh snowfall events that were sampled also showed wide variability, but the averages were the same at the two sites. The apparent difference in air-snow fractionation and the lack of coherence in the concentration in air time series between the two sites indicate previously unsuspected complexity in atmospheric dynamics over the ice sheet. Improved understanding of atmospheric processes, and how the results of those processes are recorded in snow and ice, is crucial for full interpretation of the information about past atmospheric chemistry and climate contained in the snow and ice of glaciers around the world

Recent deposition of 210Pb on the Greenland ice sheet: variations in space and time

Detailed 210Pb profiles were determined for four Chernobyl dated\u27 snowpits sampled during a wide-ranging survey of the Greenland ice sheet during the 1988 season. The profiles from widely separated pits show little or no coherence; even for two pits only 40 km apart the profiles differ in detail. There does not appear to have been any seasonality in the deposition of 210Pb onto the ice sheet in the two years since the Chernobyl accident. The total deposition of 210Pb during this period (10-20 bq m-2) was about 20 times less than has been observed at mid-latitude sites in the eastern United States. The three pits west of the ice-sheet divide recorded very similar depositional fluxes, while the one eastern pit had only two-thirds the average of the others, suggesting a west-to-east gradient in the deposition of 210Pb, and perhaps other continentally-derived submicron aerosols, onto the Greenland ice sheet. -Autho

The Chernobyl Reference Horizon (?) in the Greenland Ice Sheet

Published reports of the presence of radioactive debris from the Chernobyl reactor accident in snow on the Greenland ice sheet raised the strong prospect that such debris might constitute a valuable time stratigraphic marker all over the ice sheet. Large volume snow samples to test this possibility were collected from 7 snowpits as part of a wide ranging regional snow chemistry survey conducted during 1987 and 1988. Snow “labeled” with Chernobyl derived radioactivity was detected in all of the pits. However, the total amount of radioactive debris found at the different locations varied over a 20 fold range. The variability in total fallout showed no clear large scale spatial pattern that could be related to the presumed progress of the radioactive plume over Greenland, suggesting that small scale differences in precipitation pattern and reworking of the snow by wind were predominantly responsible for the patchy preservation of the Chernobyl “layer” on the Greenland ice sheet

Atmospheric deposition of beryllium 7 in the Chesapeake Bay region

Bulk (combined wet and dry) atmospheric deposition of the cosmogenic isotope 7Be was monitored at Solomons, Maryland, from March 1986 to November 1987. The observed deposition of 7Be supported an inventory ranging from 2 to 4 dpm (disintegrations per minute)/cm2. The supported inventory and monthly fluxes of 7Be showed maxima in late spring (March-May). The peak in 7Be deposition was very similar in 1986 and 1987 despite 1986 having a very dry spring. It thus appears that given even modest amounts of precipitation, there is strong seasonality in the atmospheric deposition of 7Be near 40°N. The timing and magnitude of the spring peak in 7Be deposition are in close agreement with estimates of the seasonal variation in the injection of stratospheric air into the troposphere, suggesting that on a monthly time scale the bulk deposition of 7Be closely reflects the tropospheric inventory of 7Be. -Autho

Shouldn’t snowpacks be sources of monocarboxylic acids?

We report the first measurements of the mixing ratios of acetic (CH3COOH) and formic (HCOOH) acids in the air filling the pore spaces of the snowpacks (firn air) at Summit, Greenland and South Pole. Both monocarboxylic acids were present at levels well above 1 ppbv throughout the upper 35 cm of the snowpack at Summit. Maximum mixing ratios in Summit firn air reached nearly 8 ppbv CH3COOH and 6 ppbv HCOOH. At South Pole the mixing ratios of these acids in the top 35 cm of firn air were also generally \u3e1 ppbv, though their maximums barely exceeded 2.5 ppbv of CH3COOH and 2.0 ppbv of HCOOH. Mixing ratios of the monocarboxylic acids in firn air did not consistently respond to diel and experimental (fast) variations in light intensity, unlike the case for N oxides in the same experiments. Air-to-snow fluxes of CH3COOH and HCOOH apparently support high mixing ratios (means of (CH3COOH/HCOOH) 445/460 and 310/159 pptv at Summit and South Pole, respectively) in air just above the snow during the summer sampling seasons at these sites. We hypothesize that oxidation of carbonyls and alkenes (that are produced by photo- and OH-oxidation of ubiquitous organic compounds) within the snowpack is the source of the monocarboxylic acids

Snow accumulation, surface height change, and firn densification at Summit, Greenland: Insights from 2 years of in situ observation

Weekly measurements of surface height change were made at an accumulation forest of 100 stakes at Summit, Greenland, over a 2-year period (17 August 2000 to 8 August 2002). On average, the surface height relative to the stakes increased 64 (±4.8) cm in the first year and 65 (±5.3) cm in the second, identical to the average (65 ± 4.5 cm yr−1) previously reported for the period 1991–1995 in a similar forest 28 km to the southwest. The continuous 2-year data set indicates that the rate of surface rise was not constant, with the summers of 2001 and 2002 both showing markedly slower increases. On-site weather observations suggest that more new snow fell during the summer months than in any other season, consistent with results from previous snow pit and modeling studies yet apparently at odds with the slow rate of height increase. Density profiles from a series of 1-m-deep snow pits sampled monthly reveal that the thickness of the most recent year of accumulated snow (25 cm water equivalent) decreased rapidly between late May and early July, and the layers remained thin through early September. The thinning of the top year is clearly due to compaction in the snowpack. Combining the observed variations in annual layer thickness with a linear height increase based on assumed constant accumulation at 0.18 cm d−1 explains much of the variation in surface height found in the stake measurements. Estimated surface height changes can be forced to exactly match the stake measurements by combining changes in annual layer thickness with a variable accumulation rate over the intervals between pits. This exercise suggests that during the 2 years of this study a consistent seasonal pattern in accumulation was not apparent, rather the intervals indicated to have had enhanced accumulation in the first year (August–October and March–April) apparently had reduced accumulation in the second year

Evidence of road salt in New Hampshire’s snowpack hundreds of meters from roadways

Salinization of surface and groundwater has been directly linked to the area of road surfaces in a watershed and the subsequent wintertime maintenance used to keep roads free of snow and ice. Most studies that explore road salt in snow along roadways limit the study to within 100 m from a roadway and conclude that there is negligible deposition of de-icing salt at distances greater than 100 m. In this study, we analyze the ion content of the southern New Hampshire snowpack and use Mg2+ as a conservative sea-salt tracer to calculate sea salt and non-sea salt fractions of Cl−. There is a minimum of 60% non-sea salt Cl−, which we attribute to road salt, in the snowpack at our study sites 115 to 350 m from the nearest maintained roadways. This suggests that larger areas need to be considered when investigating the negative impact of Cl− loading due to winter-time maintenance

Relationships between surface and column aerosol radiative properties and air mass transport at a rural New England site

Chemical, physical, and radiative properties of surface and vertical column aerosols were measured at a rural site in southern New Hampshire from July 2000 to September 2001. The primary objective was to determine how intensive and extensive aerosol properties vary in air masses originating in different upwind regions. The data set also allows for an investigation of some of the relationships between surface and column aerosol properties at the site, and provides an estimate of direct radiative forcing by aerosols during the study period. Extensive properties (e.g., optical depth and chemical concentration) were at maximum values during times of south-southwest (S-SW) transport, while minimum values were seen during north-northeast (N-NE) transport. Certain intensive properties such as fine particle mass scattering efficiency did not vary significantly between times of transport from different source regions. Mean optical depth (wavelength = 500 nm) was 0.24 during S-SW transport, compared to 0.10 during N-NE transport. The study period average scattering efficiency for (NH4)2SO4 was 6.54 ± 0.26 m2 g−1 (± standard error) and 3.36 ± 0.49 m2 g−1 for organic carbon, while the absorption efficiency of elemental carbon was 12.85 ± 0.80 m2 g−1. Top of the atmosphere aerosol direct radiative forcing was −0.35 ± 0.83 Wm−2 (±1 standard deviation) in winter 2000–2001 and −9.06 ± 3.77 Wm−2 in summer 2001, differences that can be primarily attributed to seasonal changes in surface reflectance (high in winter, low in summer) and the relatively low values of single scatter albedo observed in winter. The annual average direct radiative forcing was −5.14 ± 4.32 Wm−2. We generally observed a moderate correlation between surface and column aerosol light extinction, suggesting that vertical column aerosol radiative properties measured by surface-based radiometers should be supplemented by boundary layer measurements of aerosol chemical, physical, and radiative properties to help understand the mechanisms contributing to global aerosol variability

137CS gamma-ray detection at Summit, Greenland

Global fall-out from atmospheric testing of thermonuclear weapons produced horizon markers corresponding to the initiation of testing in 1953 and the maximum fall-out in 1963. The radioactive isotope 137Cs associated with these events has a half-life of 30.2 years. Therefore, with the appropriate radiation detectors, this fall-out can be used as a long-term temporal indicator in glaciers and snowpack. A prototype γ-ray detector system was successfully tested and was used to make in-situ measurements of the 137Cs marker in a borehole at Summit, Greenland. The system consisted of a 7.6 cm by 7.6 cm NaI (Tl) scintillation crystal/photomultiplier detector, commercial pre-amplifier, amplifier and power supplies, and a microcomputer-based pulse-height analyzer. The measurements were made in boreholes of 25.4 cm and 12.7 cm diameter to depths of 22 m. Based on the results reported here, the γ-ray detection technique promises to be a powerful way to locate quickly horizon markers in the field. -Author

Air-snow exchange investigations at Summit, Greenland: An overview

The Greenland Ice Sheet Project 2 (GISP2) and Greenland Ice Core Project (GRIP) deep drilling programs at Summit, Greenland included support (both logistical and scientific) of extensive investigation of atmospheric transport and air-snow exchange processes of gases and particles relevant to the interpretation of the ice-core records. Much of the sampling for the air-snow exchange investigations was conducted at a unique solar-powered camp 30 km southwest of the GISP2 drill camp (even further from the GRIP camp) and was characterized by a high degree of international collaboration and cooperation. The wide range of expertise and analytical capabilities of the 20-plus investigators participating in these studies has provided important insight into the meteorological, physical, and chemical processes which interact to determine the composition of snow and firn at Summit. Evolving understanding of this system will allow improved reconstruction of the composition of the atmosphere over Greenland in the past from the detailed Summit ice-core records. This paper provides an overview of air-snow exchange investigations at Summit, including their development through the course of the drilling programs (1989–1993), significant findings related to both air-snow exchange issues and the present state of the Arctic free troposphere, as well as the major outstanding questions which are being addressed in ongoing experiments at Summit