Proton hot spots and exclusive vector meson production

We explore consequences of the existence of gluonic hot spots inside the proton for coherent and incoherent exclusive vector meson production cross sections in deep inelastic scattering. By working in the dilute limit of the Color Glass Condensate framework to compute the cross sections for Gaussian hot spots of fluctuating color charges and employing a nonrelativistic vector meson wave function, we are able to perform large parts of the calculation analytically. We find that the coherent cross section is sensitive to both the size of the target and the structure of the probe. The incoherent cross section is dominated by color fluctuations at small transverse momentum transfer (t), by proton and hot spot sizes as well as the structure of the probe at medium t and again by color fluctuations at large t. While the t-dependence of the cross section is well reproduced in our model, the relative normalization between the coherent and the incoherent cross sections points to the need for additional fluctuations in the proton.Peer reviewe

Cyclodextrin- grafted electrospun cellulose acetate nanofibers via "Click" reaction for removal of phenanthrene

Cataloged from PDF version of article.Beta-cyclodextrin (p-CD) functionalized cellulose acetate (CA) nanofibers have been successfully prepared by combining electrospinning and "click" reaction. Initially, p-CD and electrospun CA nanofibers were modified so as to be azide-p-CD and propargyl-terminated CA nanofibers, respectively. Then, "click" reaction was performed between modified CD molecules and CA nanofibers to obtain permanent grafting of CDs onto nanofibers surface. It was observed from the SEM image that, while CA nanofibers have smooth surface, there were some irregularities and roughness at nanofibers morphology after the modification. Yet, the fibrous structure was still protected. ATR-FTIR and XPS revealed that, CD molecules were successfully grafted onto surface of CA nanofibers. The adsorption capacity of p-CD-functionalized CA (CA-CD) nanofibers was also determined by removing phenanthrene (polycyclic aromatic hydrocarbons, PAH) from its aqueous solution. Our results indicate that CA-CD nanofibers have potential to be used as molecular filters for the purpose of water purification and waste water treatment by integrating the high surface area of nanofibers with inclusion complexation property of CD molecules. (C) 2014 Elsevier B.V. A

Weighted Chebyshev Distance Algorithms for Hyperspectral Target Detection and Classification Applications

In this study, an efficient spectral similarity method referred to as Weighted Chebyshev Distance (WCD) is introduced for supervised classification of hyperspectral imagery (HSI) and target detection applications. The WCD is based on a simple spectral similarity based decision rule using limited amount of reference data. The estimation of upper and lower spectral boundaries of spectral signatures for all classes across spectral bands is referred to as a vector tunnel (VT). To obtain the reference information, the training signatures are provided randomly from existing data for a known class. After determination of the parameters of the WCD algorithm with the training set, classification or detection procedures are accomplished at each pixel. The comparative performances of the algorithms are tested under various cases. The decision criterion for classification of an input vector is based on choosing its class corresponding to the narrowest VT that the input vector fits in to. This is also shown to be approximated by the WCD in which the weights are chosen as an inverse power of the generalized standard deviation per spectral band. In computer experiments, the WCD classifier is compared with the Euclidian Distance (ED) classifier and the Spectral Angle Map (SAM) classifier. The WCD algorithm is also used for HSI target detection purpose. Target detection problem is considered as a two-class classification problem. The WCD is characterized only by the target class spectral information. Then, this method is compared with ED, SAM, Spectral Matched Filter (SMF), Adaptive Cosine Estimator (ACE) and Support Vector Machine (SVM) algorithms. During these studies, threshold levels are evaluated based on the Receiver Operating Characteristic Curves (ROC)

Geometrical Optimization of Resonant Cantilevers Vibrating in In-Plane Bending Modes

The influence of the beam geometry on the quality factor and resonance frequency of resonant silicon cantilever beams vibrating in their fundamental in-plane flexural mode has been investigated in air and water. Compared to cantilevers vibrating in their out-of-plane flexural mode, utilizing the in plane mode results in reduced damping and reduced mass loading by the surrounding fluid. Quality factors as high as 4,300 in air and 67 in water have been measured for cantilevers with a 12 μm thick silicon layer. This is in comparison to Q factors up to 1,500 in air and up to 20 in water for cantilevers vibrating in their fundamental out-of-plane bending mode. Based on the experimental data, design guidelines are established for beam dimensions that ensure maximal Q-factors and minimal mass loading by the surrounding fluid

Liquid-Phase Chemical Sensing Using Lateral Mode Resonant Cantilevers

Liquid-phase operation of resonant cantilevers vibrating in an out-of-plane flexural mode has to date been limited by the considerable fluid damping and the resulting low quality factors (Q factors). To reduce fluid damping in liquids and to improve the detection limit for liquid-phase sensing applications, resonant cantilever transducers vibrating in their in-plane rather than their out-of-plane flexural resonant mode have been fabricated and shown to have Q factors up to 67 in water (up to 4300 in air). In the present work, resonant cantilevers, thermally excited in an in-plane flexural mode, are investigated and applied as sensors for volatile organic compounds in water. The cantilevers are fabricated using a complementary metal oxide semiconductor (CMOS) compatible fabrication process based on bulk micromachining. The devices were coated with chemically sensitive polymers allowing for analyte sorption into the polymer. Poly(isobutylene) (PIB) and poly(ethylene-co-propylene) (EPCO) were investigated as sensitive layers with seven different analytes screened with PIB and 12 analytes tested with EPCO. Analyte concentrations in the range of 1−100 ppm have been measured in the present experiments, and detection limits in the parts per billion concentration range have been estimated for the polymer-coated cantilevers exposed to volatile organics in water. These results demonstrate significantly improved sensing properties in liquids and indicate the potential of cantilever-type mass-sensitive chemical sensors operating in their in-plane rather than out-of-plane flexural modes

Interaction of Colloidal Particles with Surfaces of Biological Significance

The adhesion of colloidal gold on membranes was examined with an electron microscope with protein on the membrane, on the colloidal particles and present on both membrane and particles. The conditions for best adhesion were determined. Quantitative measurements were caNied out using adhesion to the membrane to monitor diffusion, centrifugation and electrophoresis of colloidal particles. Electrophoresis in a centrifugal field was used as a nul method to determine the charge on the colloidal particle

Bioactive surface design based on functional composite electrospun nanofibers for biomolecule immobilization and biosensor applications

Cataloged from PDF version of article.The combination of nanomaterials and conducting polymers attracted remarkable attention for development of new immobilization matrices for enzymes. Hereby, an efficient surface design was investigated by modifying the graphite rod electrode surfaces with one-step electrospun nylon 6,6 nanofibers or 4% (w/w) multiwalled carbon nanotubes (MWCNTs) incorporating nylon 6,6 nanofibers (nylon 6,6/4MWCNT). High-resolution transmission electron microscopy study confirmed the successful incorporation of the MWCNTs into the nanofiber matrix for nylon 6,6/4MWCNT sample. Then, these nanofibrous surfaces were coated with a conducting polymer, (poly-4-(4,7-di(thiophen-2-yl)-1H-benzo[d]imidazol-2-yl) benzaldehyde) (PBIBA) to obtain a high electroactive surface area as new functional immobilization matrices. Due to the free aldehyde groups of the polymeric structures, a model enzyme, glucose oxidase was efficiently immobilized to the modified surfaces via covalent binding. Scanning electron microscope images confirmed that the nanofibrous structures were protected after the electrodeposition step of PBIBA and a high amount of protein attachment was successfully achieved by the help of high surface to volume ratio of electroactive nanofiber matrices. The biosensors were characterized in terms of their operational and storage stabilities and kinetic parameters (K mapp and Imax). The resulting novel glucose biosensors revealed good stability and promising Imax values (10.03 and 16.67 μA for nylon 6,6/PBIBA and nylon 6,6/4MWCNT/PBIBA modified biosensors, respectively) and long shelf life (32 and 44 days for nylon 6,6/PBIBA and nylon 6,6/4MWCNT/PBIBA modified biosensors, respectively). Finally, the biosensor was tested on beverages for glucose detection. © 2014 American Chemical Society

pH-responsive nanofibers with controlled drug release properties

Cataloged from PDF version of article.Smart polymers and nanofibers are potentially intriguing materials for controlled release of bioactive agents. This work describes a new class of pH responsive nanofibers for drug delivery systems with controlled release properties. Initially, poly(4-vinylbenzoic acid-co-(ar-vinylbenzyl) trimethylammonium chloride) [poly(VBA-co-VBTAC)] was synthesized via reversible addition-fragmentation chain transfer (RAFT) polymerization. Then, ciprofloxacin was chosen as the model drug for the release study and encapsulated into pH-responsive polymeric carriers of poly(VBA-co-VBTAC) nanofibers via electrospinning. The morphology of the electrospun nanofibers was examined by scanning electron microscopy (SEM). The structural characteristics of the pH responsive nanofibers were investigated by Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD). The release measurements of ciprofloxacin from pH responsive nanofibers were also performed by high-performance liquid chromatography (HPLC) analysis. To show the pH sensitivity of these nanofibers, the release profile of ciprofloxacin was examined under acidic, neutral and basic conditions. The results indicate that pH responsive nanofibers can serve as effective drug carriers since the release of ciprofloxacin could be controlled by changing the pH of the environment, and therefore these drug loaded pH-responsive nanofibers might have potential applications in the biomedical field. This journal is © The Royal Society of Chemistry

Untethered micro-robotic coding of three-dimensional material composition

Complex functional materials with three-dimensional micro- or nano-scale dynamic compositional features are prevalent in nature. However, the generation of three-dimensional functional materials composed of both soft and rigid microstructures, each programmed by shape and composition, is still an unsolved challenge. Herein, we describe a method to code complex materials in three-dimensions with tunable structural, morphological, and chemical features using an untethered magnetic micro-robot remotely controlled by magnetic fields. This strategy allows the micro-robot to be introduced to arbitrary microfluidic environments for remote two- and three-dimensional manipulation. We demonstrate the coding of soft hydrogels, rigid copper bars, polystyrene beads, and silicon chiplets into three-dimensional heterogeneous structures. We also use coded microstructures for bottom-up tissue engineering by generating cell-encapsulating constructs