Directed current in the Holstein system

We propose a mechanism to rectify charge transport in the semiclassical Holstein model. It is shown that localised initial conditions, associated with a polaron solution, in conjunction with a nonreversion symmetric static electron on-site potential constitute minimal prerequisites for the emergence of a directed current in the underlying periodic lattice system. In particular, we demonstrate that for unbiased spatially localised initial conditions, violation of parity prevents the existence of pairs of counter-propagating trajectories, thus allowing for a directed current despite the time-reversibility of the equations of motion. Occurrence of long-range coherent charge transport is demonstrated

Theory of a Narrow roton Absorption Line in the Spectrum of a Disk-Shaped SHF Resonator

We calculate the probability of the birth of a circular phonon (c-phonon) in He II by a c-photon of the resonator. It is shown that this probability has sharp maxima at frequencies, where the effective group velocity of the c-phonon is equal to zero; the density of states of c-phonons strongly grows at such frequencies. For He II, these frequencies correspond to a roton and a maxon. From the probability of the c-roton birth, we calculate the roto line width which is found to approximately agree with the experimental one. We conclude that the roton line observed in the super-high-frequency (SHF) absorption spectrum of helium is related to the birth of c-rotons. A possible interpretation of the Stark effect observed for the roton line is also proposed.Comment: 13 pages, 1 figure, v2: journal variant, several minor correction

Microscopic derivation of Frenkel excitons in second quantization

Starting from the microscopic hamiltonian describing free electrons in a periodic lattice, we derive the hamiltonian appropriate to Frenkel excitons. This is done through a grouping of terms different from the one leading to Wannier excitons. This grouping makes appearing the atomic states as a relevant basis to describe Frenkel excitons in the second quantization. Using them, we derive the Frenkel exciton creation operators as well as the commutators which rule these operators and which make the Frenkel excitons differing from elementary bosons. The main goal of the present paper is to provide the necessary grounds for future works on Frenkel exciton many-body effects, with the composite nature of these particles treated exactly through a procedure similar to the one we have recently developed for Wannier excitons.Comment: 16 pages, 4 figure

A Variational Approach to Nonlocal Exciton-Phonon Coupling

In this paper we apply variational energy band theory to a form of the Holstein Hamiltonian in which the influence of lattice vibrations (optical phonons) on both local site energies (local coupling) and transfers of electronic excitations between neighboring sites (nonlocal coupling) is taken into account. A flexible spanning set of orthonormal eigenfunctions of the joint exciton-phonon crystal momentum is used to arrive at a variational estimate (bound) of the ground state energy for every value of the joint crystal momentum, yielding a variational estimate of the lowest polaron energy band across the entire Brillouin zone, as well as the complete set of polaron Bloch functions associated with this band. The variation is implemented numerically, avoiding restrictive assumptions that have limited the scope of previous assaults on the same and similar problems. Polaron energy bands and the structure of the associated Bloch states are studied at general points in the three-dimensional parameter space of the model Hamiltonian (electronic tunneling, local coupling, nonlocal coupling), though our principal emphasis lay in under-studied area of nonlocal coupling and its interplay with electronic tunneling; a phase diagram summarizing the latter is presented. The common notion of a "self-trapping transition" is addressed and generalized.Comment: 33 pages, 11 figure

Cylindrically symmetric solitons in Einstein-Yang-Mills theory

Recently new Einstein-Yang-Mills (EYM) soliton solutions were presented which describe superconducting strings with Kasner asymptotic (hep-th/0610183). Here we study the static cylindrically symmetric SU(2) EYM system in more detail. The ansatz for the gauge field corresponds to superposition of the azimuthal $B_\phi$ and the longitudinal $B_z$ components of the color magnetic field. We derive sum rules relating data on the symmetry axis to asymptotic data and show that generic asymptotic structure of regular solutions is Kasner. Solutions starting with vacuum data on the axis generically are divergent. Regular solutions correspond to some bifurcation manifold in the space of parameters which has the low-energy limiting point corresponding to string solutions in flat space (with the divergent total energy) and the high-curvature point where gravity is crucial. Some analytical results are presented for the low energy limit, and numerical bifurcation curves are constructed in the gravitating case. Depending on the parameters, the solution looks like a straight string or a pair of straight and circular strings. The existence of such non-linear superposition of two strings becomes possible due to self-interaction terms in the Yang-Mills action which suppress contribution of the circular string near the polar axis.Comment: 21 pages, 11 figure

Anomalous tunneling of bound pairs in crystal lattices

A novel method of solving scattering problems for bound pairs on a lattice is developed. Two different break ups of the hamiltonian are employed to calculate the full Green operator and the wave function of the scattered pair. The calculation converges exponentially in the number of basis states used to represent the non-translation invariant part of the Green operator. The method is general and applicable to a variety of scattering and tunneling problems. As the first application, the problem of pair tunneling through a weak link on a one-dimensional lattice is solved. It is found that at momenta close to \pi the pair tunnels much easier than one particle, with the transmission coefficient approaching unity. This anomalously high transmission is a consequence of the existence of a two-body resonant state localized at the weak link.Comment: REVTeX, 5 pages, 4 eps figure

Second quantization method in the presence of bound states of particles

We develop an approximate second quantization method for describing the many-particle systems in the presence of bound states of particles at low energies (the kinetic energy of particles is small in comparison to the binding energy of compound particles). In this approximation the compound and elementary particles are considered on an equal basis. This means that creation and annihilation operators of compound particles can be introduced. The Hamiltonians, which specify the interactions between compound and elementary particles and between compound particles themselves are found in terms of the interaction amplitudes for elementary particles. The nonrelativistic quantum electrodynamics is developed for systems containing both elementary and compound particles. Some applications of this theory are considered.Comment: 35 page

Phonon Coherence and New Set of Sidebands in Phonon-Assisted Photoluminescence

We investigate excitonic polaron states comprising a local exciton and phonons in the longitudinal optical (LO) mode by solving the Schr\"{o}dinger equation. We derive an exact expression for the ground state (GS), which includes multi-phonon components with coefficients satisfying the Huang-Rhys factors. The recombination of GS and excited polaron states gives one set of sidebands in photoluminescence (PL): the multi-phonon components in the GS produce the Stokes lines and the zero-phonon components in the excited states produce the anti-Stokes lines. By introducing the mixing of the LO mode and environal phonon modes, the exciton will also couple with the latter, and the resultant polaron states result in another set of phonon sidebands. This set has a zero-phonon line higher and wider than that of the first set due to the tremendous number of the environal modes. The energy spacing between the zero-phonon lines of the first and second sets is proved to be the binding energy of the GS state. The common exciton origin of these two sets can be further verified by a characteristic Fano lineshape induced by the coherence in the mixing of the LO and the environal modes.Comment: 5 pages, 3 figures 1 figure (fig. 1) replaced 1 figure (fig. 2) remove

Coherent charge transport through molecular wires: "Exciton blocking" and current from electronic excitations in the wire

We consider exciton effects on current in molecular nanojunctions, using a model comprising a two two-level sites bridge connecting free electron reservoirs. Expanding the density operator in the many-electron eigenstates of the uncoupled sites, we obtain a 16X16 density matrix in the bridge subspace whose dynamics is governed by Liuoville equation that takes into account interactions on the bridge as well as electron injection and damping to and from the leads. Our consideration can be considerably simplified by using the pseudospin description based on the symmetry properties of Lie group SU(2). We study the influence of the bias voltage, the Coulomb repulsion and the energy-transfer interactions on the steady-state current and in particular focus on the effect of the excitonic interaction between bridge sites. Our calculations show that in case of non-interacting electrons this interaction leads to reduction in the current at high voltage for a homodimer bridge. In other words, we predict the effect of \textquotedblleft exciton\textquotedblright blocking. The effect of \textquotedblleft exciton\textquotedblright blocking is modified for a heterodimer bridge, and disappears for strong Coulomb repulsion at sites. In the latter case the exciton type interactions can open new channels for electronic conduction. In particular, in the case of strong Coulomb repulsion, conduction exists even when the electronic connectivity does not exist.Comment: 14 pages, 15 figure