46 research outputs found
Lewis Acid Promoted Titanium Alkylidene Formation: Off-Cycle Intermediates Relevant to Olefin Trimerization Catalysis
Full text linkHighly Selective Olefin Trimerization Catalysis by a Borane-Activated Titanium Trimethyl Complex
Full text linkDiastereoselective Synthesis of Polysubstituted Piperidines through Visible‐Light‐Driven Silylative Cyclization of Aza‐1,6‐Dienes: Experimental and DFT Studies
No full text
Diboron(4) Compounds: From Structural Curiosity to Synthetic Workhorse
No full textThis article is also available through American Chemical Society Authorchoice Open Access at http://dx.doi.org/10.1021/acs.chemrev.6b00193Although known for over 90 years, only in the past two decades has the chemistry of diboron(4) compounds been extensively explored. Many interesting structural features and reaction patterns have emerged, and more importantly, these compounds now feature prominently in both metal-catalyzed and metal-free methodologies for the formation of B-C bonds and other processes.T.B.M. thanks the DFG and the University of Würzburg for
support. S.A.W. thanks Chris Vogels for helpful discussions and
NSERC of Canada for support
