Electro-optic measurement of carrier mobility in an organic thin-film transistor

We have used an electro-optic technique to measure the position-dependent infrared absorption of holes injected into a thin crystal of the organic semiconductor, 6,13-bis(triisopropylsilylethynyl)-pentacene incorporated in a field-effect transistor. By applying square-wave voltages of variable frequency to the gate or drain, one can measure the time it takes for charges to accumulate on the surface, and therefore determine their mobility.Comment: 11 pages, 4 figures, to be published in Applied Physics Letter

Dynamics of Charge Flow in the Channel of a Thin-Film Field-Effect Transistor

The local conductivity in the channel of a thin-film field-effect transistor is proportional to the charge density induced by the local gate voltage. We show how this determines the frequency- and position-dependence of the charge induced in the channel for the case of "zero applied current": zero drain-source voltage with charge induced by a square-wave voltage applied to the gate, assuming constant mobility and negligible contact impedances. An approximate expression for the frequency dependence of the induced charge in the center of the channel can be conveniently used to determine the charge mobility. Fits of electro-optic measurements of the induced charge in organic transistors are used as examples.Comment: 9 pages including table + 3 figures; submitted to Jnl. Appl. Phy

Thermal Diffusivities of Functionalized Pentacene Semiconductors

We have measured the interlayer and in-plane (needle axis) thermal diffusivities of 6,13-bis(triisopropylsilylethynyl) pentacene (TIPS-Pn). The needle axis value is comparable to the phonon thermal conductivities of quasi-one dimensional organic metals with excellent pi-orbital overlap, and its value suggests that a significant fraction of heat is carried by optical phonons. Furthermore, the interlayer (c-axis) thermal diffusivity is at least an order of magnitude larger, and this unusual anisotropy implies very strong dispersion of optical modes in the interlayer direction, presumably due to interactions between the silyl-containing side groups. Similar values for both in-plane and interlayer diffusivities have been observed for several other functionalized pentacene semiconductors with related structures.Comment: 9 pages, including 4 figures; submitted to Applied Physics Letter

Predicting Morphologically-Complex Unknown Words in Igbo

The effective handling of previously unseen words is an important factor in the performance of part-of-speech taggers. Some trainable POS taggers use suffix (sometimes prefix) strings as cues in handling unknown words (in effect serving as a proxy for actual linguistic affixes). In the context of creating a tagger for the African language Igbo, we compare the performance of some existing taggers, implementing such an approach, to a novel method for handling morphologically complex unknown words, based on morphological reconstruction (i.e. a linguistically-informed segmentation into root and affixes). The novel method outperforms these other systems by several percentage points, achieving accuracies of around 92 % on morphologically-complex unknown words

The isolation of gravitational instantons: Flat tori V flat R^4

The role of topology in the perturbative solution of the Euclidean Einstein equations about flat instantons is examined.Comment: 15 pages, ICN-UNAM 94-1

\u3cem\u3eRhizobium japonicum\u3c/em\u3e Mutants Defective in Symbiotic Nitrogen Fixation

Rhizobium japonicum strains 3I1b110 and 61A76 were mutagenized to obtain 25 independently derived mutants that produced soybean nodules defective in nitrogen fixation, as assayed by acetylene reduction. The proteins of both the bacterial and the plant portions of the nodules were analyzed by two-dimensional polyacrylamide gel electrophoresis. All of the mutants had lower-than-normal levels of the nitrogenase components, and all but four contained a prominent bacteroid protein not observed in wild-type bacteroids. Experiments with bacteria grown ex planta suggested that this protein was derepressed by the absence of ammonia. Nitrogenase component II of one mutant was altered in isoelectric point. The soluble plant fraction of the nodules of seven mutants had very low levels of heme, yet the nodules of five of these seven mutants contained the polypeptide of leghemoglobin. Thus, the synthesis of the globin may not be coupled to the content of available heme in soybean nodules. The nodules of the other two of these seven mutants lacked not only leghemoglobin but most of the other normal plant and bacteroid proteins. Ultrastructural examination of nodules formed by these two mutants indicated normal ramification of infection threads but suggested a problem in subsequent survival of the bacteria and their release from the infection threads

Tuning electronic structures via epitaxial strain in Sr2IrO4 thin films

We have synthesized epitaxial Sr2IrO4 thin-films on various substrates and studied their electronic structures as a function of lattice-strains. Under tensile (compressive) strains, increased (decreased) Ir-O-Ir bond-angles are expected to result in increased (decreased) electronic bandwidths. However, we have observed that the two optical absorption peaks near 0.5 eV and 1.0 eV are shifted to higher (lower) energies under tensile (compressive) strains, indicating that the electronic-correlation energy is also affected by in-plane lattice-strains. The effective tuning of electronic structures under lattice-modification provides an important insight into the physics driven by the coexisting strong spin-orbit coupling and electronic correlation.Comment: 9 pages, 5 figures, 1 tabl

Asymptotic Behaviour of the Proper Length and Volume of the Schwarzschild Singularity

Though popular presentations give the Schwarzschild singularity as a point it is known that it is spacelike and not timelike. Thus it has a "length" and is not a "point". In fact, its length must necessarily be infinite. It has been proved that the proper length of the Qadir-Wheeler suture model goes to infinity [1], while its proper volume shrinks to zero, and the asymptotic behaviour of the length and volume have been calculated. That model consists of two Friedmann sections connected by a Schwarzschild "suture". The question arises whether a similar analysis could provide the asymptotic behaviour of the Schwarzschild black hole near the singularity. It is proved here that, unlike the behaviour for the suture model, for the Schwarzschild essential singularity $\Delta s$ $\thicksim$ $K^{1/3}\ln K$ and $V\thicksim$ $K^{-1}\ln K$, where $K$ is the mean extrinsic curvature, or the York time.Comment: 13 pages, 1 figur