13 research outputs found
Second Harmonic Detection of Atmospheric Trace Gases with a Train-Pulse Driven Lead-Salt Tunable Diode Laser for an Operation at Peltier Cooling Temperature
Is proposed a tunable diode laser absorption spectrometer system which employs a pulsed current to drive the diode laser still implementing a second-harmonic detection methods enhancing a signal to noise up to 104 times that the case without it. This system affords the lead-salt diode laser a higher operating temperature which allows a more compact deep cooling system. A principle is based on employing a gated integrator between the preamplifier and the lock-in amplifier. Investigations are made on the optimum selection of the gating aperture time interval as determined by response time of the infrared detector and the pulse width of the laser driving current
Application of the Adjoint Spectrum to the Frequency Tracking in Spectrometry with Tunable Diode Lasers Suffering from Temperature Drift
A numerical technique called as "adjoint spectrum" has been proposed by the authors in a previous work. Two applications of it are presented here. It is demonstrated that by generalizing the aspect of adjoint spectrum it becomes possible to measure densities of mixed gases simultaneously. An experimental proof of this has been carried on and simultaneous measurement of densities of both methane and dinitrogen oxide was realized. On the other hand, it is also reported that frequency shifting of spectra, which is a cause of error in spectrometric measurements, can be corrected by exploiting the adjoint spectrum technique in connection with the Taylor expansion. Numerical examples showing the success of this method are reported as well
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Electronic band structures and optical properties of 2D XOF (X = Ga or In) oxyfluoride monolayers using density functional theory and GW approximation
The class of two-dimensional oxyfluoride monolayers is currently considered one of the most attractive nanomaterials for enhancing design and pushing the limits of different cutting-edge technologies. Two-dimensional semiconductor materials are the most promising systems for various applications in optoelectronic devices because they have a unique optical properties. We continue in this way by investigating the GW band structures and optical properties of unique 2D XOF (X = Ga or In) oxyfluoride monolayers, involving absorption, conductivity, refractive index, and dielectric function. We find no imaginary frequencies in the computed phonon spectra, indicating that these systems are dynamically stable. Furthermore, GaOF and InOF stay stable for temperatures T ≤ 840 K. The band gap of GaOF obtained with the single shot (G0W0) is larger than the band gap energy Eg of InOF. Where the direct band gap energies of GaOF and InOF are 6.1 eV and 4.8 eV, respectively. Our GW(PBE) numerical simulations demonstrate that the GaOF monolayer moves transparent once the frequency of the incoming light exceeds the plasma frequency (35.00 eV). Furthermore, InOF switches transparently once the incident light frequency exceeds the plasma frequency ∼ 35.00 eV. Interestingly, we obtain that these 2D sheets have a strong absorption coefficient in the range of ∼ 3.00–60.00 eV. They are emerging as a potential for the building blocks of the nano-size and ultra-thin optoelectronics of the future since they productively emit and absorb light
Second Harmonic Detection of Atmospheric Trace Gases with a Train-Pulse Driven Lead-Salt Tunable Diode Laser for an Operation at Peltier Cooling Temperature
SYNOPSIS Is proposed a tunable diode laser absorption spectrometer system which employs a pulsed current to drive the diode laser still implementing a second-harmonic detection methods enhancing a signal to noise up to 104 times that the case without it. This system affords the lead-salt diode laser a higher operating temperature which allows a more compact deep cooling system. A principle is based on employing a gated integrator between the preamplifier and the lock-in amplifier. Investigations are made on the optimum selection of the gating aperture time interval as determined by response time of the infrared detector and the pulse width of the laser driving current