Process modelling for the production of hydrogen-rich gas from gasification of coal using oxygen, CO2 and steam reactants

This process modelling studied the effect of different reactants on syngas composition and gasifier heat duty (heat energy required to carry out the operation) and the downstream treatment of CO rich syngas to maximise hydrogen yield. The process modelling was validated against experimental data obtained from a large bench-scale entrained flow gasifier. Results show that considering the H2/CO ratio, the steam-O2 reactant favours the most compared to those of the pure oxygen and oxygen-CO2 reactants. Under comparable operating conditions, the highest H2/CO ratio of 0.74 was determined using steam-O2 reactant compared to that of 0.31 and 0.33 using steam-CO2 and pure oxygen reactant. The catalytic water-gas shift reaction (WGSR) favours the yield of H2 with complete CO conversion at a temperature of 400 °C using the steam/coal ratio of 1.2. Supplying steam in the gasifier requires more heat energy to be supplied to drive endothermic gasification reaction and maintain the gasifier temperature. Under complete carbon conversion, steam-CO2 and steam-oxygen reactants require 5–65 kW more energy than pure oxygen. © 2021 Hydrogen Energy Publications LL

Mitigating Direct Detection Bounds in Non-minimal Higgs Portal Scalar Dark Matter Models

Minimal scalar Higgs portal dark matter model is increasingly in tension with recent results form direct detection experiments like LUX and XENON. In this paper we make a systematic study of minimal extension of the $\mathbb{Z}_2$ stabilised singlet scalar Higgs portal scenario in terms of their prospects at direct detection experiments. We consider both enlarging the stabilising symmetry to $\mathbb{Z}_3$ and incorporating multipartite features in the dark sector. We demonstrate that in these non-minimal models the interplay of annihilation, co-annihilation and semi-annihilation processes considerably relax constraints from present and proposed direct detection experiments while simultaneously saturating observed dark matter relic density. We explore in particular the resonant semi-annihilation channel within the multipartite $\mathbb{Z}_3$ framework which results in new unexplored regions of parameter space that would be difficult to constrain by direct detection experiments in the near future. The role of dark matter exchange processes within multi-component $\mathbb{Z}_3 \times \mathbb{Z}_3'$ framework is illustrated. We make quantitative estimates to elucidate the role of the various annihilation processes in the different allowed regions of parameter space of these models.Comment: 31 pages, 15 figures, added brief discussion on vaccum stability and unitarity; minor changes in the text; updated references; typos fixed; matches published versio