10 research outputs found
Microstructural Evolution and Refinement Mechanism of a Beta–Gamma TiAl-Based Alloy during Multidirectional Isothermal Forging
Multidirectional isothermal forging (MDIF) was used on a Ti-44Al-4Nb-1.5Cr-0.5Mo-0.2B (at. %) alloy to obtain a crack-free pancake. The microstructural evolution, such as dynamic recovery and recrystallization behavior, were investigated using electron backscattered diffraction and transmission electron microscopy methods. The MDIF broke down the initial near-lamellar microstructure and produced a refined and homogeneous duplex microstructure. γ grains were effectively refined from 3.6 μm to 1.6 μm after the second step of isothermal forging. The ultimate tensile strength at ambient temperature and the elongation at 800 °C increased significantly after isothermal forging. β/B2→α2 transition occurred during intermediate annealing, and α2 + γ→β/B2 transition occurred during the second step of isothermal forging. The refinement mechanism of the first-step isothermal forging process involved the conversion of the lamellar structure and discontinuous dynamic recrystallization (DDRX) of γ grains in the original mixture-phase region. The lamellar conversion included continuous dynamic recrystallization and DDRX of the γ laths and bugling of the γ phase. DDRX behavior of γ grains dominated the refinement mechanism of the second step of isothermal forging
Exploration of the atomic-level structures of the icosahedral clusters in Cu–Zr–Al ternary metallic glasses via first-principles theory
The atomic-level structures of the icosahedral clusters in Cu–Zr–Al ternary metallic glasses were studied via the first-principles theory. The rules of icosahedra stability were determined. Icosahedra with a better chemical order or with a better symmetry exhibited a better stability. The strong connectivity between Al atom and Cu and Zr atoms was observed as demonstrated by the obvious degree of ‘bond shortening’. The Al atom contributed more to the structural stability when used as the central atom than the other atoms. Therefore, the addition of even a small amount of Al atom to the Cu–Zr binary system remarkably improved the stability of the icosahedron structures. The continued addition of Al atoms had a lower contribution to the improvement to the glass-forming ability of the Cu–Zr–Al alloys
Evolution of the Microstructure and Lamellar Orientation of a β-Solidifying γ-TiAl-Based Alloy during Hot Compression
A type of advanced γ-TiAl-based alloy called β-solidifying γ-TiAl has elicited remarkable research interest in the last few decadesbecause of its excellent workability and homogeneous microstructures. Thermomechanical treatments are widely applied to this alloy to obtain fine duplex microstructures. To investigate the deformation behavior and microstructure evolution of Ti-44Al-4Nb-1.5Cr-0.5Mo-0.2B alloy, we conducted a series of hot compression tests at a temperature of 1473 K and a strain rate of 0.01 s−1. Scanning electron microscopy, electron backscattered diffraction, and transmission electron microscopy were performed to analyze the crystal orientation and microstructures of the alloy. During compression at 1473 K, β/B2→γ transition and α2/γ lamellae→γ+β/B2 transition occurred simultaneously, which increased the content of the γ phase and decreased the content of the α2 phase. The lamellar colonies exhibited distinct anisotropy, which could affect their hot deformation behavior. The colonies that remained after compression had strong texture components
The Low Strain Rate Response of As-Cast Ti-6Al-4V Alloy with an Initial Coarse Lamellar Structure
The microstructure and microtexture evolution of the as-cast Ti-6Al-4V alloy with an initial lamellar microstructure was investigated in the temperature range of 900–1050 °C and the low strain rate range of 10−3–10−1 s−1. In the ranges 900–950 °C and 10−3–10−2 s−1, globularization of the α lamellar structure took place; the initial α {0001} texture softened, and the {0001} texture rotated to the transverse direction. Additionally, the increasing strain rate led to more randomization. The globularization process was considered to be continuous dynamic recrystallization (CDRX). At strain rates higher than 10−2 s−1 and temperatures between 900 and 950 °C, flow instabilities occurred. In the β range, dynamic recrystallization (DRX) occurred at a temperature of 1050 °C and a strain rate of 10−3 s−1
A New Mechanism of Dynamic Phase Transformations in An Isothermal Forged Beta–Gamma Intermetallic Alloy
A new mechanism of dynamic phase transformations of α2 ↔ γ in an isothermally forged γ-TiAl-based alloy that occur simultaneously during a short-term exposure at 1000 °C is identified in this study. In the heating process, γ phase significantly decreases through a phase transformation of γ → α2, while new γ lamellae are precipitated in the interior of equiaxed grains of α2 phase through a phase transformation of α2 → γ. The reasons for the presence of these two inverse phase transformations α2 ↔ γ occurring simultaneously are discussed
Microstructure and Electrochemical Behavior of a 3D-Printed Ti-6Al-4V Alloy
3D printing (or more formally called additive manufacturing) has the potential to revolutionize the way objects are manufactured, ranging from critical applications such as aerospace components to medical devices, making the materials stronger, lighter and more durable than those manufactured via conventional methods. While the mechanical properties of Ti-6Al-4V parts manufactured with two major 3D printing techniques: selective laser melting (SLM) and electron beam melting (EBM), have been reported, it is unknown if the corrosion resistance of the 3D-printed parts is comparable to that of the alloy made with isothermal forging (ISF). The aim of this study was to identify the corrosion resistance and mechanisms of Ti-6Al-4V alloy manufactured by SLM, EBM and ISF via electrochemical corrosion tests in 3.5% NaCl solution, focusing on the effect of microstructures. It was observed that the equiaxed α + β microstructure in the ISF-manufactured Ti-6Al-4V alloy had a superior corrosion resistance to the acicular martensitic α′ + β and lamellar α + β microstructures of the 3D-printed samples via SLM and EBM, respectively. This was mainly due to the fact that (1) a higher amount of β phase was present in the ISF-manufactured sample, and (2) the fraction of phase interfaces was lower in the equiaxed α + β microstructure than in the acicular α′ + β and lamellar α + β microstructures, leading to fewer microgalvanic cells. The lower corrosion resistance of SLM-manufactured sample was also related to the higher strain energy and lower electrochemical potential induced by the presence of martensitic twins, resulting in faster anodic dissolution and higher corrosion rate
Influence of Nonmetallic Interstitials on the Phase Transformation between FCC and HCP Titanium: A Density Functional Theory Study
In addition to the common stable and metastable phases in titanium alloys, the face-centered cubic phase was recently observed under various conditions; however, its formation remains largely unclarified. In this work, the effect of nonmetallic interstitial atoms O, N, C and B on the formation of the face-centered cubic phase of titanium was investigated with the density functional theory. The results indicate that the occupancy of O, N, C and B on the octahedral interstitial sites reduces the energy gap between the hexagonal-close-packed (HCP) and face-centered cubic (FCC) phases, thus assisting the formation of FCC-Ti under elevated temperature or plastic deformation. Such a gap further decreases with the increase in the interstitial content, which is consistent with the experimental observation of FCC-Ti under high interstitial content. The relative stability of the interstitial-containing HCP-Ti and FCC-Ti was studied against the physical and chemical origins, e.g., the lattice distortion and the electronic bonding. Interstitial O, N, C and B also reduce the stacking fault energy, thus further benefiting the formation of FCC-Ti
Influence of Nonmetallic Interstitials on the Phase Transformation between FCC and HCP Titanium: A Density Functional Theory Study
In addition to the common stable and metastable phases in titanium alloys, the face-centered cubic phase was recently observed under various conditions; however, its formation remains largely unclarified. In this work, the effect of nonmetallic interstitial atoms O, N, C and B on the formation of the face-centered cubic phase of titanium was investigated with the density functional theory. The results indicate that the occupancy of O, N, C and B on the octahedral interstitial sites reduces the energy gap between the hexagonal-close-packed (HCP) and face-centered cubic (FCC) phases, thus assisting the formation of FCC-Ti under elevated temperature or plastic deformation. Such a gap further decreases with the increase in the interstitial content, which is consistent with the experimental observation of FCC-Ti under high interstitial content. The relative stability of the interstitial-containing HCP-Ti and FCC-Ti was studied against the physical and chemical origins, e.g., the lattice distortion and the electronic bonding. Interstitial O, N, C and B also reduce the stacking fault energy, thus further benefiting the formation of FCC-Ti
Active Slip Mode Analysis of an Additively Manufactured Ti-6Al-4V Alloy via In-Grain Misorientation Axis Distribution
Selective laser-melted (SLM) Ti-6Al-4V alloy was quasi-statically compressed in the transverse and longitudinal directions at a strain rate of 1 × 10−3 s−1 at room temperature. The twinning, in-grain misorientation axis (IGMA) distribution and active slip modes of individual grains in the deformed SLM Ti-6Al-4V alloy were studied in detail via transmission Kikuchi diffraction (TKD) and transmission electron microscopy (TEM). The α’/α phase was textured with the c-axis oriented either at ~45° or perpendicular to the building direction (BD). A combined analysis of the IGMA distribution and Schmid factor revealed that the prismatic <a> slip or pyramidal slip was easily activated in the soft grains with their c-axes perpendicular to the BD (or the loading direction) in the longitudinal compressed sample, while slip was hardly activated in the transverse compressed sample due to the lack of soft grains. Prismatic <a> slip with IGMA around <0001> Taylor axis also occurred in {10–11} twins. The observations revealed that the prismatic <a> slip played a key role in accommodating the external strain and, thus, well explained the anisotropy of mechanical properties in the SLM Ti-6Al-4V alloy