전기도금으로 제작한 Ni과 Cu 단일막 및 NiCu 다층막의 미소인장거동 평가 및 해석

학위논문(석사)--서울대학교 대학원 :재료공학부,2004.Maste

일방향으로 배열된 단섬유 보강 복합재료의 탄성율 예측

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HTZ/AC8A 금속복합재료의 기계적 성질과 피로 거동

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Reversible Phase Modulation and Hydrogen Storage in Multi-Valent VO2 Epitaxial Thin Films

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Reversible phase transition of hydrogen sponge in multi-valent VO2 epitaxial thin film

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Systematic Tuning of Hydrogen-induced Phase Transition in VO2 Epitaxial Thin Film

Phase transition by band filling control is one of the core concepts in correlated electronic systems. Unlike the substitutional dopants, hydrogen plays a key role in effectively filling significant amount of carriers in the empty narrow d band by reversibly adding it into interstitial sites and supplying carriers. Vanadium dioxide (VO2), typical correlated oxide with 3d 1 electronic configuration, can also reversibly incorporate hydrogen atoms into its interstitial sites and simultaneously occurs phase transition by its 3d band filling. Here, we demonstrate that as many as two hydrogen atoms can be incorporated into each VO2 unit cell, and that hydrogen is reversibly absorbed into, and released from, VO2 without destroying its lattice framework. This hydrogenation process demonstrates two-step insulator (VO2) – metal (HxVO2) – insulator (HVO2) phase modulation during inter-integer d-band filling. Moreover, HVO2 can be thermodynamically stabilized regardless of facet direction of VO2 epilayer, but remarkable discrepancy in kinetics of phase modulation was clearly visualized depending on the crystal facet. The unprecedented insulating HVO2 with 3d 2 configuration is attributed to highly doped electrons via hydrogenation process in conjunction with huge lattice expansion. Our finding suggests the possibility of reversible and dynamic control of topotactic phase modulation in VO2 and opens up the potential application in proton-based Mottronics and novel hydrogen storage.2

Synchrotron x-ray study of hydrogen-induced phase transition in VO2 epitaxial thin films

Phase transition by band filling control is one of the core concepts in correlated electronic systems. Unlike the substitutional dopants, hydrogen, the smallest and the lightest atom, plays a key role in effectively filling significant amount of carriers in the empty narrow d band by reversibly adding it into interstitial sites and supplying carriers. Vanadium dioxide (VO2), typical correlated oxide with 3d1 electronic configuration, can also reversibly incorporate hydrogen atoms into its interstitial sites and simultaneously occurs phase transition by its 3d band filling. Here, we demonstrate that as many as two hydrogen atoms can be incorporated into each VO2 unit cell, and that hydrogen is reversibly absorbed into, and released from, VO2 without destroying its lattice framework due to the low temperature annealing process. This hydrogenation process demonstrates twostep insulator (VO2) – metal (HxVO2) – insulator (HVO2) phase modulation during inter-integer d-band filling. Moreover, HVO2 can be thermodynamically stabilized regardless of facet direction of VO2 epi-layer, but remarkable discrepancy in kinetics of phase modulation was clearly visualized depending on the crystal facet. Based on in situ XRD, XPS and NEXAFS in synchrotron, the unprecedented insulating HVO2 with 3d2 configuration is attributed to highly doped electrons via hydrogenation process in conjunction with huge lattice expansion. Our finding suggests the possibility of reversible and dynamic control of topotactic phase modulation in VO2 and opens up the potential application in proton-based Mottronics and novel hydrogen storage.2

Systematic Tuning of Hydrogen-Induced Phase Transition in VO2 Epitaxial Thin Films.

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