Coulombic Quantum Liquids in Spin-1/2 Pyrochlores

We develop a non-perturbative "gauge Mean Field Theory" (gMFT) method to study a general effective spin-1/2 model for magnetism in rare earth pyrochlores. gMFT is based on a novel exact slave-particle formulation, and matches both the perturbative regime near the classical spin ice limit and the semiclassical approximation far from it. We show that the full phase diagram contains two exotic phases: a quantum spin liquid and a coulombic ferromagnet, both of which support deconfined spinon excitations and emergent quantum electrodynamics. Phenomenological properties of these phases are discussed.Comment: 4+ pages, 6+ pages of Supplementary Material, 4 figures, 1 tabl

Spin Liquid Regimes at Nonzero Temperature in Quantum Spin Ice

Quantum spin liquids are highly entangled ground states of quantum systems with emergent gauge structure, fractionalized spinon excitations, and other unusual properties. While these features clearly distinguish quantum spin liquids from conventional, mean-field-like states at zero temperature (T), their status at T>0 is less clear. Strictly speaking, it is known that most quantum spin liquids lose their identity at non-zero temperature, being in that case adiabatically transformable into a trivial paramagnet. This is the case for the U(1) quantum spin liquid states recently proposed to occur in the quantum spin ice pyrochlores. Here we propose, however, that in practical terms, the latter quantum spin liquids can be regarded as distinct phases from the high temperature paramagnet. Through a combination of gauge mean field theory calculations and physical reasoning, we argue that these systems sustain both quantum spin liquid and thermal spin liquid phases, dominated by quantum fluctuations and entropy, respectively. These phases are separated by a first order "thermal confinement" transition, such that for temperatures below the transition, spinons and emergent photons are coherently propagating excitations, and above it the dynamics is classical. Even for parameters for which the ground state is magnetically ordered and not a quantum spin liquid, this strong first order transition occurs, pre-empting conventional Landau-type criticality. We argue that this picture explains the anomalously low temperature phase transition observed in the quantum spin ice material Yb2Ti2O7.Comment: 15 pages (including 7 pages of appendices), 3 figures, 1 tabl

Disorder-Induced Entanglement in Spin Ice Pyrochlores

We propose that in a certain class of magnetic materials, known as non-Kramers 'spin ice,' disorder induces quantum entanglement. Instead of driving glassy behavior, disorder provokes quantum superpositions of spins throughout the system, and engenders an associated emergent gauge structure and set of fractional excitations. More precisely, disorder transforms a classical phase governed by a large entropy, classical spin ice, into a quantum spin liquid governed by entanglement. As the degree of disorder is increased, the system transitions between (i) a "regular" Coulombic spin liquid, (ii) a phase known as "Mott glass," which contains rare gapless regions in real space, but whose behavior on long length scales is only modified quantitatively, and (iii) a true glassy phase for random distributions with large width or large mean amplitude.Comment: 6+2 pages, 2+1 figure

Quantum Spin Liquids

Quantum spin liquids may be considered "quantum disordered" ground states of spin systems, in which zero point fluctuations are so strong that they prevent conventional magnetic long range order. More interestingly, quantum spin liquids are prototypical examples of ground states with massive many-body entanglement, of a degree sufficient to render these states distinct phases of matter. Their highly entangled nature imbues quantum spin liquids with unique physical aspects, such as non-local excitations, topological properties, and more. In this review, we discuss the nature of such phases and their properties based on paradigmatic models and general arguments, and introduce theoretical technology such as gauge theory and partons that are conveniently used in the study of quantum spin liquids. An overview is given of the different types of quantum spin liquids and the models and theories used to describe them. We also provide a guide to the current status of experiments to study quantum spin liquids, and to the diverse probes used therein.Comment: 60 pages, 8 figures, 1 tabl

Signatures of the Helical Phase in the Critical Fields at Twin Boundaries of Non-Centrosymmetric Superconductors

Domains in non-centrosymmetric materials represent regions of different crystal structure and spin-orbit coupling. Twin boundaries separating such domains display unusual properties in non-centrosymmetric superconductors (NCS), where magneto-electric effects influence the local lower and upper critical magnetic fields. As a model system, we investigate NCS with tetragonal crystal structure and Rashba spin-orbit coupling (RSOC), and with twin boundaries parallel to their basal planes. There, we report that there are two types of such twin boundaries which separate domains of opposite RSOC. In a magnetic field parallel to the basal plane, magneto-electric coupling between the spin polarization and supercurrents induces an effective magnetic field at these twin boundaries. We show this leads to unusual effects in such superconductors, and in particular to the modification of the upper and lower critical fields, in ways that depend on the type of twin boundary, as analyzed in detail, both analytically and numerically. Experimental implications of these effects are discussed.Comment: 10 pages, 6 figure

A New Type of Quantum Criticality in the Pyrochlore Iridates

Magnetic fluctuations and electrons couple in intriguing ways in the vicinity of zero temperature phase transitions - quantum critical points - in conducting materials. Quantum criticality is implicated in non-Fermi liquid behavior of diverse materials, and in the formation of unconventional superconductors. Here we uncover an entirely new type of quantum critical point describing the onset of antiferromagnetism in a nodal semimetal engendered by the combination of strong spin-orbit coupling and electron correlations, and which is predicted to occur in the iridium oxide pyrochlores. We formulate and solve a field theory for this quantum critical point by renormalization group techniques, show that electrons and antiferromagnetic fluctuations are strongly coupled, and that both these excitations are modified in an essential way. This quantum critical point has many novel features, including strong emergent spatial anisotropy, a vital role for Coulomb interactions, and highly unconventional critical exponents. Our theory motivates and informs experiments on pyrochlore iridates, and constitutes a singular realistic example of a non-trivial quantum critical point with gapless fermions in three dimensions.Comment: 5 pages + 8 pages of Supplementary Material, 3 figures + 1 supplementary figur