Critical point shift in a fluid confined between opposing walls

The properties of a fluid, or Ising magnet, confined in a $L \times \infty$ geometry with opposing surface fields at the walls are studied by density matrix renormalization techniques. In particular we focus on the effect of gravity on the system, which is modeled by a bulk field whose strength varies linearly with the distance from the walls. It is well known that in the absence of gravity phase coexistence is restricted to temperatures below the wetting temperature. We find that gravity restores phase coexistence up to the bulk critical temperature, in agreement with previous mean field results. A detailed study of the scaling to the critical point, as $L \to \infty$, is performed. The temperature shift scales as $1/L^{y_T}$, while the gravitational constant scales as $1/L^{1+y_H}$, with $y_T$ and $y_H$ the bulk thermal and magnetic exponents respectively. For weak surface fields and $L$ not too large, we also observe a regime where the gravitational constant scales as $1/L^{1+y_H - \Delta_1 y_T}$ ($\Delta_1$ is the surface gap exponent) with a crossover, for sufficiently large $L$, to a scaling of type $1/L^{1+y_H}$.Comment: 9 pages, RevTeX, 11 PostScript figures included. Minor corrections. Final version as publishe

Models of DNA denaturation dynamics: universal properties

We briefly review some of the models used to describe DNA denaturation dynamics, focusing on the value of the dynamical exponent $z$, which governs the scaling of the characteristic time $\tau\sim L^z$ as a function of the sequence length $L$. The models contain different degrees of simplifications, in particular sometimes they do not include a description for helical entanglement: we discuss how this aspect influences the value of $z$, which ranges from $z=0$ to $z \approx 3.3$. Connections with experiments are also mentioned

Density Matrix Renormalization Group and Reaction-Diffusion Processes

The density matrix renormalization group (DMRG) is applied to some one-dimensional reaction-diffusion models in the vicinity of and at their critical point. The stochastic time evolution for these models is given in terms of a non-symmetric ``quantum Hamiltonian'', which is diagonalized using the DMRG method for open chains of moderate lengths (up to about 60 sites). The numerical diagonalization methods for non-symmetric matrices are reviewed. Different choices for an appropriate density matrix in the non-symmetric DMRG are discussed. Accurate estimates of the steady-state critical points and exponents can then be found from finite-size scaling through standard finite-lattice extrapolation methods. This is exemplified by studying the leading relaxation time and the density profiles of diffusion-annihilation and of a branching-fusing model in the directed percolation universality class.Comment: 16 pages, latex, 5 PostScript figures include

A lattice polymer study of DNA renaturation dynamics

DNA renaturation is the recombination of two complementary single strands to form a double helix. It is experimentally known that renaturation proceeds through the formation of a double stranded nucleus of several base pairs (the rate limiting step) followed by a much faster zippering. We consider a lattice polymer model undergoing Rouse dynamics and focus on the nucleation of two diffusing strands. We study numerically the dependence of various nucleation rates on the strand lengths and on an additional local nucleation barrier. When the local barrier is sufficiently high, all renaturation rates considered scale with the length as predicted by Kramers' rate theory and are also in agreement with experiments: their scaling behavior is governed by exponents describing equilibrium properties of polymers. When the local barrier is lowered renaturation occurs in a regime of genuine non-equilibrium behavior and the scaling deviates from the rate theory prediction.Comment: 13 pages, 6 figures. To appear in Journal of Statistical Mechanic

A Transfer Matrix study of the staggered BCSOS model

The phase diagram of the staggered six vertex, or body centered solid on solid model, is investigated by transfer matrix and finite size scaling techniques. The phase diagram contains a critical region, bounded by a Kosterlitz-Thouless line, and a second order line describing a deconstruction transition. In part of the phase diagram the deconstruction line and the Kosterlitz-Thouless line approach each other without merging, while the deconstruction changes its critical behaviour from Ising-like to a different universality class. Our model has the same type of symmetries as some other two-dimensional models, such as the fully frustrated XY model, and may be important for understanding their phase behaviour. The thermal behaviour for weak staggering is intricate. It may be relevant for the description of surfaces of ionic crystals of CsCl structure.Comment: 13 pages, RevTex, 1 Postscript file with all figures, to be published in Phys. Rev.

Equilibrium shapes and faceting for ionic crystals of body-centered-cubic type

A mean field theory is developed for the calculation of the surface free energy of the staggered BCSOS, (or six vertex) model as function of the surface orientation and of temperature. The model approximately describes surfaces of crystals with nearest neighbor attractions and next nearest neighbor repulsions. The mean field free energy is calculated by expressing the model in terms of interacting directed walks on a lattice. The resulting equilibrium shape is very rich with facet boundaries and boundaries between reconstructed and unreconstructed regions which can be either sharp (first order) or smooth (continuous). In addition there are tricritical points where a smooth boundary changes into a sharp one and triple points where three sharp boundaries meet. Finally our numerical results strongly suggest the existence of conical points, at which tangent planes of a finite range of orientations all intersect each other. The thermal evolution of the equilibrium shape in this model shows strong similarity to that seen experimentally for ionic crystals.Comment: 14 Pages, Revtex and 10 PostScript figures include