Enhancement of Low-field Magnetoresistance in Self-Assembled Epitaxial La0.67Ca0.33MnO3:NiO and La0.67Ca0.33MnO3:Co3O4 Composite Films via Polymer-Assisted Deposition

Polymer-assisted deposition method has been used to fabricate self-assembled epitaxial La(0.67)Ca(0.33)MnO(3):NiO and La(0.67)Ca(0.33)MnO(3):Co(3)O(4) films on LaAlO(3) substrates. Compared to pulsed-laser deposition method, polymer-assisted deposition provides a simpler and lower-cost approach to self-assembled composite films with enhanced low-field magnetoresistance effect. After the addition of NiO or Co(3)O(4), triangular NiO and tetrahedral Co(3)O(4) nanoparticles remain on the surface of La(0.67)Ca(0.33)MnO(3) films. This results in a dramatic increase in resistivity of the films from 0.0061 Ω•cm to 0.59 Ω•cm and 1.07 Ω•cm, and a decrease in metal-insulator transition temperature from 270 K to 180 K and 172 K by the addition of 10%-NiO and 10%-Co(3)O(4), respectively. Accordingly, the maximum absolute magnetoresistance value is improved from −44.6% to −59.1% and −52.7% by the addition of 10%-NiO and 10%-Co(3)O(4), respectively. The enhanced low-field magnetoresistance property is ascribed to the introduced insulating phase at the grain boundaries. The magnetism is found to be more suppressed for the La(0.67)Ca(0.33)MnO(3):Co(3)O(4) composite films than the La(0.67)Ca(0.33)MnO(3):NiO films, which can be attributed to the antiferromagnetic properties of the Co(3)O(4) phase. The solution-processed composite films show enhanced low-field magnetoresistance effect which are crucial in practical applications. We expect our polymer-assisted deposited films paving the pathway in the field of hole-doped perovskites with their intrinsic colossal magnetoresistance

Self-Cleaning Glass of Photocatalytic Anatase TiO2@Carbon Nanotubes Thin Film by Polymer-Assisted Approach

Due to the good photocatalytic activity, the TiO2@CNTs thin film is highly desirable to apply to the self-cleaning glass for green intelligent building. Here, the TiO2@CNTs thin film has been successfully achieved by polymer-assisted approach of an aqueous chemical solution method. The polymer, polyethylenimine, aims to combine the Ti4+ with CNTs for film formation of TiO2@CNTs. The resultant thin film was uniform, highly transparent, and super-hydrophilic. Owing to fast electron transport and effectively hindering electron-hole recombination, the TiO2@CNTs thin film has nearly twofold photocatalytic performance than pure TiO2. The TiO2@CNTs thin films show a good application for self-cleaning glasses

Experimental Study on Hydraulic Fracture Initiation and Propagation in Hydrated Shale

Shale reservoirs contain a certain amount of clay minerals, which can hydrate through imbibition when in contact with various water-based fluids during drilling and completion. Shale hydration can lead to structural changes in the shale such as the expansion of bedding planes and propagation of microfractures, consequently affecting the initiation and propagation of hydraulic fractures. However, the effect of shale hydration under confining pressure on hydraulic fracture propagation and stimulation effect is still unclear. To this end, a novel experimental method integrating shale hydration and hydraulic fracturing was proposed based on the laboratory triaxial hydraulic fracturing simulation system. This method enables a more realistic simulation of shale hydration and hydraulic fracturing process happening in downhole conditions. The experimental results show that under simulated reservoir conditions, water imbibition increases over time with the imbibition rate reaching its peak within 24 h. The breakdown pressure, number of fractures, and complexity of fractures are positively correlated with imbibition time. The increase in fracture complexity could be attributed to the increase in the number of fractures. In contrast, imbibition pressure (injection pressure for imbibition) has little influence on water imbibition. For specimens under different imbibition pressure, the breakdown pressure and the number of fractures are close, and the complexity of fractures does not change prominently; all are T-shaped fractures. It is believed that the closure of microfractures under confining pressure caused by hydration is the main reason for the increase in breakdown pressure. Higher breakdown pressure means higher net pressure in the wellbore, which facilitates fracture initiation where the breakdown pressure is higher. Therefore, shale hydration is conducive to the initiation of multiple fractures, thus increasing the number and complexity of fractures

Optimization of Water Injection Strategy before Re-Stimulation Considering Fractures Propagation

Water injection before re-stimulation has a positive effect to mitigate the “frac hit” and increase oil production in tight reservoirs. However, the study of water injection strategy optimization has not been thoroughly investigated. Some conclusions can be found in the existing literature, but the pressure and stress distribution, fractures morphology and oil production were not considered as a whole workflow during the study. In addition, the different reservoir deficit was not considered. Although technical experience and economic benefit have been obtained in some field tests, failed cases still exist. To fill this gap, a series of numerical models are established based on a tight reservoir located in northwest China. Under the different re-stimulation timing, the pressure distribution, stress distribution, and fractures morphology after water injection of different injection/production ratios are calculated, respectively. The oil and water production are predicted. The results show that, after a short period of production with a small deficit, the degree of “frac hit” is slight. Injecting water has an obvious effect on increasing oil production for both parent and infill well. After a long period of production with a large deficit, the problem of “frac hit” is very severe. Injecting water has an obvious effect on increasing oil production only for the parent well. The production of infill well is influenced by the fractures’ interference and pressure increasing comprehensively. For the well group, measured by the final cumulative oil production, the optimal injection/production ratio is different, but the water injection volume is similar, which is about 15,000 m3

Amorphous RuS₂ electrocatalyst with optimized active sites for hydrogen evolution

Transition metal chalcogenides have attracted much attention as high-performance electrocatalysts for hydrogen evolution reaction (HER). Here, we synthesized an efficient HER electrocatalyst of amorphous ruthenium sulfide (A-RuS2), exhibiting an overpotential of 141 mV at the current density of 10 mA cm-2 and a Tafel slope of 65.6 mV dec-1. Experiments demonstrate amorphous RuS2 has much better catalytic activity than that of its crystalline counterparts. Our study shows that amorphous RuS2 has increased intrinsic activity and active sites. This work provides a feasible strategy for the development of HER electrocatalysts in amorphous state.We gratefully acknowledge the support from the National Natural Science Foundation of China (Grant Nos. 21971172, 21671141), `973 Program-The National Basic Research Program of China' Special Funds for the Chief Young Scientist (Grant No. 2015CB358600), the Priority Academic Program Development (PAPD) of Jiangsu Higher Education Institutions for Optical Engineering, and the Jiangsu Collaborative Innovation Center of Photovoltaic Science and Engineering