Low-Energy Scale Excitations in the Spectral Function of Organic Monolayer Systems

Using high-resolution photoemission spectroscopy we demonstrate that the electronic structure of several organic monolayer systems, in particular 1,4,5,8-naphthalene tetracarboxylic dianhydride and Copper-phtalocyanine on Ag(111), is characterized by a peculiar excitation feature right at the Fermi level. This feature displays a strong temperature dependence and is immediatly connected to the binding energy of the molecular states, determined by the coupling between the molecule and the substrate. At low temperatures, the line-width of this feature, appearing on top of the partly occupied lowest unoccupied molecular orbital of the free molecule, amounts to only $\approx 25$ meV, representing an unusually small energy scale for electronic excitations in these systems. We discuss possible origins, related e.g. to many-body excitations in the organic-metal adsorbate system, in particular a generalized Kondo scenario based on the single impurity Anderson model.Comment: 6 pages, 3 figures, accepted as PRB Rapid Communication

Detection of Overhead Contact Lines with a 2D-Digital-Beamforming Radar System for Automatic Guidance of Trolley Trucks

The benefit of trolley truck systems is the substitution of the diesel fuel by the cheaper and more ecological electrical energy. Trolley trucks are powered by electricity fromtwo overhead contact lines, where one is the supply and the other the return conductor. Such trolley trucks are used for haulage at open pit mining sites but could also be used for freight traffic at roadways in the future. Automatic guidance prevents the trolley-powered trucks fromleaving the track and thus allows higher operating speeds, higher loading capacity, and greater efficiency. Radar is the ideal sensing technique for automatic guidance in such environments.The presented radar systemwith two-dimensional digital beamforming capability offers a compact measurement solution as it can be installed on top of the truck. Besides the distance measurement, this radar system allows to detect the location and inclination of the overhead contact lines by digital beamforming in two dimensions. Besides automatic guidance, the knowledge of the inclination of the overhead contact lines could allow automatic speed adaption, which would help to achieve maximum speed especially in hilly terrain

Improved Performance of Flip Chip assembled MMIC Amplifiers on LTCC using a Photonic Bandgap Structure

Further cost reduction in today’s microwave frontends is strongly related to assembly technology as well as module technology. Depending on the particular mix of technologies, specific problems and chances can be addressed. In case of flip-chip on LTCC, various effects of performance degradation of the MMICs can be observed, some of which can be related to unwanted internal coupling of the microstrip IC due to the floating groundplane. For some MMICs a periodic structure below the chip can help to improve the characteristics of the assembled chip due to its ability to suppress a particular class of unwanted modes between the chip groundplane and the module ground. The periodic structure is proposed and measured results are given and discussed

Disordering of an Organic Overlayer on a Metal Surface Upon Cooling

Coolly Disordered Generally speaking, at higher temperature phases materials are more disordered—for example, when solids melt to form liquids. In some cases, however—for example, under high pressure—a more disordered phase can emerge upon cooling. Schöll et al. (p. 303 ) now show that an organic molecule, a naphthalene derivative, adsorbed on a silver surface disorders upon cooling below room temperature. This process is driven by the surface bond becoming stronger upon cooling and preventing weaker interactions that allow ordering between molecules in the plane. </jats:p

Orbital Density Reconstruction for Molecules

The experimental imaging of electronic orbitals has allowed one to gain a fascinating picture of quantum effects. We here show that the energetically high-lying orbitals that are accessible to experimental visualization in general differ, depending on which approach is used to calculate the orbitals. Therefore, orbital imaging faces the fundamental question of which orbitals are the ones that are visualized. Combining angular-resolved photoemission experiments with first-principles calculations, we show that the orbitals from self-interaction-free Kohn-Sham density functional theory are the ones best suited for the orbital-based interpretation of photoemission

Different views on the electronic structure of nanoscale graphene: aromatic molecule versus quantum dot

Graphene's peculiar electronic band structure makes it of interest for new electronic and spintronic approaches. However, potential applications suffer from quantization effects when the spatial extension reaches the nanoscale. We show by photoelectron spectroscopy on nanoscaled model systems (disc-shaped, planar polyacenes) that the two-dimensional band structure is transformed into discrete states which follow the momentum dependence of the graphene Bloch states. Based on a simple model of quantum wells, we show how the band structure of graphene emerges from localized states, and we compare this result with ab initio calculations which describe the orbital structure