CO preferential oxidation in a novel Au@ZrO₂ flow-through catalytic membrane reactor with high stability and efficiency

CO preferential oxidation (CO-PROX) achieves much interest as a strategy to remove trace CO in reformed gases for hydrogen utilization. Herein, we reported a novel Au@ZrO₂ catalytic membrane reactor by embedding gold nano-particles in ZrO₂ hollow fiber membrane for CO-PROX. The flow-through catalytic membrane exhibited high catalytic activity and oxygen selectivity, which gave a turnover frequency of 4.73 s⁻¹ at 60 °C, 2–3 times higher than conventional catalyst pellets. CO conversion of >95% was achieved over the catalytic membrane, which maintained great operational stability during 500-h operation even CO₂ and H₂O were added in the feed stream. The excellent catalytic performance of the flow-through catalytic membrane makes gold catalyst possible for practical application in the removal of CO from hydrogen

DC-Net: Divide-and-Conquer for Salient Object Detection

In this paper, we introduce Divide-and-Conquer into the salient object detection (SOD) task to enable the model to learn prior knowledge that is for predicting the saliency map. We design a novel network, Divide-and-Conquer Network (DC-Net) which uses two encoders to solve different subtasks that are conducive to predicting the final saliency map, here is to predict the edge maps with width 4 and location maps of salient objects and then aggregate the feature maps with different semantic information into the decoder to predict the final saliency map. The decoder of DC-Net consists of our newly designed two-level Residual nested-ASPP (ResASPP$^{2}$) modules, which have the ability to capture a large number of different scale features with a small number of convolution operations and have the advantages of maintaining high resolution all the time and being able to obtain a large and compact effective receptive field (ERF). Based on the advantage of Divide-and-Conquer's parallel computing, we use Parallel Acceleration to speed up DC-Net, allowing it to achieve competitive performance on six LR-SOD and five HR-SOD datasets under high efficiency (60 FPS and 55 FPS). Codes and results are available: https://github.com/PiggyJerry/DC-Net

Comparing the contribution of visible-light irradiation, gold nanoparticles, and titania supports in photocatalytic nitroaromatic coupling and aromatic alcohol oxidation

Under visible-light irradiation, gold nanoparticles (Au NPs) supported by titania (TiO₂) nanofibers show excellent activity and high selectivity for both reductive coupling of nitroaromatics to corresponding azobenzene or azoxylbenzene and selective oxidation of aromatic alcohols to corresponding aldehydes. The Au NPs act as active centers mainly due to their localized surface plasmon resonance (LSPR) effect. They can effectively couple the photonic energy and thermal energy to enhance reaction efficiency. Visible-light irradiation has more influence on the reduction than on the oxidation, lowering the activation energy by 24.7 kJ mol⁻¹ and increasing the conversion rate by 88% for the reductive coupling, compared to merely 8.7 kJ mol⁻¹ and 46% for the oxidation. Furthermore, it is found that the conversion of nitroaromatics significantly depends on the particle size and specific surface area of supported Au NPs; and the catalyst on TiO₂(B) support outperforms that on anatase phase with preferable ability to activate oxygen. In contrast, for the selective oxidation, the effect of surface area is less prominent and Au NPs on anatase exhibit higher photo-catalytic activity than other TiO₂ phases. The catalysts can be recovered efficiently because the Au NPs stably attach to TiO₂ supports by forming a well-matched coherent interface observed via high-resolution TEM

Co2N nanoparticles embedded N-doped mesoporous carbon as efficient electrocatalysts for oxygen reduction reaction

Co-N-C electrocatalysts have attracted great attention in electrocatalytic ORR (oxygen reduction reaction) field. In this work, we propose to prepare Co 2 N nanoparticles embedded N-doped mesoporous carbon by a facile method including in situ copolymerization and pyrolysis under NH 3 atmosphere. The results show that more N atoms can be doped in carbon framework by NH 3 pyrolysis, it is also found that pyrolysis temperature and Co content can influence the ORR performance of samples. The sample prepared by adding Co precursor and pyrolysis at 700 °C has high N content (11.86 at.%) and relative large specific surface area (362 m 2 g −1 ), and it also exhibited superior electrocatalytic ORR performance in terms of E onset (−0.038 V vs. SCE), E 1/2 (−0.126 V vs. SCE) and large current density (5.22 mA cm −2 ). Additionally, the sample also shows better stability and resistance to methanol poisoning than Pt/C catalyst. The synergistic effect of Co-N active centers and hierarchical porous structures contribute the excellent electrocatalytic activity, which are considering as alternative catalysts for ORR in full cells

3,5-Di-O-benzoyl-1,2-O-isopropyl­idene-α-d-ribo-hexos-3-ulo-1,4:3,6-difuran­ose

The title compound, C23H22O8, is a binary benzoyl ester whose nucleus consists of a fused system made up of a methyl­enedi­oxy ring and two tetra­hydro­furan rings. One of the benzoyl ester groups is attached at the junction of the two tetra­hydro­furan rings. The other is attached to the outer tetra­furan ring. Both the benzoyl ester groups are in an axial conformation with respect to the outer tetrhydro­furan ring. In the crystal, mol­ecules are linked by two weak C—H⋯O hydrogen bonds, forming a chain running parallel to the a axis

Surface plasmon-enhanced zeolite catalysis under light irradiation and its correlation with molecular polarity of reactants

Enhanced catalytic performance of zeolites via the plasmonic effect of gold nanoparticles has been discovered to be closely correlated with the molecular polarity of reactants. The intensified polarised electrostatic field of Na+ in NaY plays a critical role in stretching the C=O bond of aldehydes to improve the reaction rate

Retrospective seroepidemiology indicated that human enterovirus 71 and coxsackievirus A16 circulated wildly in central and southern China before large-scale outbreaks from 2008

<p>Abstract</p> <p>Background</p> <p>Large nationwide outbreaks of hand, foot, and mouth disease (HFMD) occurred in China from 2008; most of the cases were in children under 5 years. This study aims to identify the situation of natural human enterovirus 71 (HEV71) and coxsackievirus A16 (CVA16) infections in children before 2008 in China.</p> <p>Results</p> <p>Retrospective seroepidemiologic studies of HEV71 and CVA16 were performed with 900 serum samples collected from children ≤5 years of age in 2005. The samples were collected from 6 different geographical areas (Anhui, Guangdong, Hunan, Xinjiang, Yunnan, and Heilongjiang provinces) in mainland China. Of the 900 samples, 288 were positive for HEV71; the total positive rate was 32.0% and the geometric mean titer (GMT) was 1:8.5. Guangdong (43.7% and 1:10.8), Xinjiang (45.4% and 1:11.1), and Yunnan (43.4% and 1:12.0) provinces had relatively high rates of infection, while Heilongjiang province (8.1% and 1:4.9) had the lowest rate of infection. On the other hand, 390 samples were positive for CVA16; the total positive rate was 43.4% and the GMT was 1:9.5. Anhui (62.2% and 1:16.0) and Hunan (61.1% and 1:23.1) had relatively high rates, while Heilongjiang (8.0% and 1:4.6) had the lowest rate. Although there is a geographical difference in HEV71 and CVA16 infections, low neutralizing antibody positive rate and titer of both viruses were found in all 6 provinces.</p> <p>Conclusions</p> <p>This report confirmed that HEV71 and CVA16 had wildly circulated in a couple provinces in China before the large-scale outbreaks from 2008. This finding also suggests that public health measures to control the spread of HEV71 and CVA16 should be devised according to the different regional characteristics.</p

DNA Checkpoint and Repair Factors Are Nuclear Sensors for Intracellular Organelle Stresses-Inflammations and Cancers Can Have High Genomic Risks.

Under inflammatory conditions, inflammatory cells release reactive oxygen species (ROS) and reactive nitrogen species (RNS) which cause DNA damage. If not appropriately repaired, DNA damage leads to gene mutations and genomic instability. DNA damage checkpoint factors (DDCF) and DNA damage repair factors (DDRF) play a vital role in maintaining genomic integrity. However, how DDCFs and DDRFs are modulated under physiological and pathological conditions are not fully known. We took an experimental database analysis to determine the expression of 26 DNA D

Study on damage mechanism and treatment of water sprayed roof in Jurassic stratum roadway

The roof of the Jurassic main coal seam in western China generally contained low level weak rich water layer, which led to the long-term watering of the roof of the coal roadway especially the roof anchor cable hole and the reduction of the roof surrounding rock strength and the roof support effect, and affected the safety of the coal roadway roof. In order to study the damage mechanism and control measures of the water sprayed roof, the No.414106 auxiliary transportation water spraying area of Yangjiacun Coal Mine of Shuangxin Mining in Inner Mongolia was taken as the research object. Through field investigation and roof drilling sampling, it could be seen that there were obvious water conducting cracks in the area 4m above the roof of the roadway in the synclinal area. The water flowing from the anchor cable hole was in a linear water spraying state. The roof surrounding rock had a large degree of deflection, and some anchor cable anchorage sections were separated from the surrounding rock. The mineral composition analysis and water physical test showed that the clay minerals in the roof sandy mudstone contain up to 73% kaolinite, and the softening coefficient is 0.162, which had obvious water softening characteristics. At the initial stage, the roof of the coal roadway in the water spraying area was mainly destroyed by hydrostatic pressure, and the water softening property reduced the mechanical properties of the fracture structural plane, which led to the expansion of the size of the surrounding rock fractures in shear under the action of hydrostatic pressure. In the later stage, the roof surrounding rock was mainly destroyed by hydrodynamic pressure, which was mainly manifested in the deformation and expansion of fracture structural plane, displacement of fracture fillings, piping, etc. The destruction speed of roof surrounding rock was gradually accelerated. The whole process of surrounding rock of water drenching roadway roof from ground pressure appearance deformation and crack softening expansion to piping corrosion failure was analyzed. According to the main forms of the surrounding rock failure of roof drilling (physical softening, seepage failure, suction corrosion expansion failure, scouring deformation failure), it was divided into four different stages. The criteria for determining the development stage of roof failure of roadway drenching water had been formed with the main forms of roof drilling surrounding rock failure, the flow state of the roof anchor cable hole, roof surrounding rock fracture development characteristics and water control reinforcement principles as the key indicators. Combined with the site conditions, the 414106 auxiliary transportation water spraying area was the Ⅲ stage of the development of spraying roof damage. The structural form of anchor cable sealing grouting (drainage) and the principle of “deep hole drainage + shallow water sealing + deep reinforcement + high pressures support” were proposed for the roof of the roadway in the spraying area. An integrated reinforcement scheme of anchoring, sealing and grouting, which combined the reinforcement of high pre-tightened long anchor cables and sealing and grouting on the roof of the roadway in the water-spraying area, had been formulated. According to the field industrial test and rock pressure monitoring, the effect of roof water control and surrounding rock reinforcement was achieved