83 research outputs found
Correlation between intercalated magnetic layers and superconductivity in pressurized EuFe2(As0.81P0.19)2
We report comprehensive high pressure studies on correlation between
intercalated magnetic layers and superconductivity in EuFe2(As0.81P0.19)2
single crystal through in-situ high pressure resistance, specific heat, X-ray
diffraction and X-ray absorption measurements. We find that an unconfirmed
magnetic order of the intercalated layers coexists with superconductivity in a
narrow pressure range 0-0.5GPa, and then it converts to a ferromagnetic (FM)
order at pressure above 0.5 GPa, where its superconductivity is absent. The
obtained temperature-pressure phase diagram clearly demonstrates that the
unconfirmed magnetic order can emerge from the superconducting state. In stark
contrast, the superconductivity cannot develop from the FM state that is
evolved from the unconfirmed magnetic state. High pressure X-ray absorption
(XAS) measurements reveal that the pressure-induced enhancement of Eu's mean
valence plays an important role in suppressing the superconductivity and tuning
the transition from the unconfirmed magnetic state to a FM state. The unusual
interplay among valence state of Eu ions, magnetism and superconductivity under
pressure may shed new light on understanding the role of the intercalated
magnetic layers in Fe-based superconductors
Lattice and Magnetic structures of PrFeAsO, PrFeAsO0.85F0.15 and PrFeAsO0.85
We use powder neutron diffraction to study the spin and lattice structures of
polycrystalline samples of nonsuperconducting PrFeAsO and superconducting
PrFeAsO0.85F0.15 and PrFeAsO0.85. We find that PrFeAsO exhibits an abrupt
structural phase transitions at 153 K, followed by static long range
antiferromagnetic order at 127 K. Both the structural distortion and magnetic
order are identical to other rare-earth oxypnictides. Electron-doping the
system with either Fluorine or oxygen deficiency suppresses the structural
distortion and static long range antiferromagnetic order, therefore placing
these materials into the same class of FeAs-based superconductors.Comment: 14 pages, 3 figures, 1 tabl
(Li0.84Fe0.16)OHFe0.98Se superconductor: Ion-exchange synthesis of large single crystal and highly two-dimensional electron properties
A large and high-quality single crystal (Li0.84Fe0.16)OHFe0.98Se, the optimal
superconductor of newly reported (Li1-xFex)OHFe1-ySe system, has been
successfully synthesized via a hydrothermal ion-exchange technique. The
superconducting transition temperature (Tc) of 42 K is determined by magnetic
susceptibility and electric resistivity measurements, and the zero-temperature
upper critical magnetic fields are evaluated as 79 and 313 Tesla for the field
along the c-axis and the ab-plane, respectively. The ratio of out-of-plane to
in-plane electric resistivity,\r{ho}c/\r{ho}ab, is found to increases with
decreasing temperature and to reach a high value of 2500 at 50 K, with an
evident kink occurring at a characteristic temperature T*=120 K. The negative
in-plane Hall coefficient indicates that electron carriers dominate in the
charge transport, and the hole contribution is significantly reduced as the
temperature is lowered to approach T*. From T* down to Tc, we observe the
linear temperature dependences of the in-plane electric resistivity and the
magnetic susceptibility for the FeSe layers. Our findings thus reveal that the
normal state of (Li0.84Fe0.16)OHFe0.98Se becomes highly two-dimensional and
anomalous prior to the superconducting transition, providing a new insight into
the mechanism of high-Tc superconductivity.Comment: 11 pages, 4 figures, supplementary information is not uploade
Reemerging superconductivity at 48 K across quantum criticality in iron chalcogenides
Pressure plays an essential role in the induction1 and control2,3 of
superconductivity in iron-based superconductors. Substitution of a smaller
rare-earth ion for the bigger one to simulate the pressure effects has
surprisingly raised the superconducting transition temperature Tc to the record
high 55 K in these materials4,5. However, Tc always goes down after passing
through a maximum at some pressure and the superconductivity eventually tends
to disappear at sufficiently high pressures1-3. Here we show that the
superconductivity can reemerge with a much higher Tc after its destruction upon
compression from the ambient-condition value of around 31 K in newly discovered
iron chalcogenide superconductors. We find that in the second superconducting
phase the maximum Tc is as high as 48.7 K for K0.8Fe1.70Se2 and 48 K for
(Tl0.6Rb0.4)Fe1.67Se2, setting the new Tc record in chalcogenide
superconductors. The presence of the second superconducting phase is proposed
to be related to pressure-induced quantum criticality. Our findings point to
the potential route to the further achievement of high-Tc superconductivity in
iron-based and other superconductors.Comment: 20 pages and 7 figure
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