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    Approximate Capacities of Two-Dimensional Codes by Spatial Mixing

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    We apply several state-of-the-art techniques developed in recent advances of counting algorithms and statistical physics to study the spatial mixing property of the two-dimensional codes arising from local hard (independent set) constraints, including: hard-square, hard-hexagon, read/write isolated memory (RWIM), and non-attacking kings (NAK). For these constraints, the strong spatial mixing would imply the existence of polynomial-time approximation scheme (PTAS) for computing the capacity. It was previously known for the hard-square constraint the existence of strong spatial mixing and PTAS. We show the existence of strong spatial mixing for hard-hexagon and RWIM constraints by establishing the strong spatial mixing along self-avoiding walks, and consequently we give PTAS for computing the capacities of these codes. We also show that for the NAK constraint, the strong spatial mixing does not hold along self-avoiding walks

    Bis(1,10-phenanthroline-κ2 N,N′)(sulfato-κ2 O,O′)cobalt(II) butane-2,3-diol monosolvate

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    In the title compound, [Co(SO4)(C12H8N2)2]·C4H10O2, the Co2+ ion has a distorted octa­hedral coordination environment composed of four N atoms from two chelating 1,10-phenanthroline ligands and two O atoms from an O,O′-bidentate sulfate anion. The dihedral angle between the two chelating N2C2 groups is 83.48 (1)°. The Co2+ ion, the S atom and the mid-point of the central C—C bond of the butane-2,3-diol solvent mol­ecule are situated on twofold rotation axes. The mol­ecules of the complex and the solvent mol­ecules are held together by pairs of symmetry-related O—H⋯O hydrogen bonds with the uncoordinated O atoms of the sulfate ions as acceptors. The solvent mol­ecule is disordered over two sets of sites with site occupancies of 0.40 and 0.60
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