Adsorption of thallium(I) on rutile nano-titanium dioxide and environmental implications

Rutile nano-titanium dioxide (RNTD) characterized by loose particles with diameter in 20–50 nm has a very large surface area for adsorption of Tl, a typical trace metal that has severe toxicity. The increasing application of RNTD and widespread discharge of Tl-bearing effluents from various industrial activities would increase the risk of their co-exposure in aquatic environments. The adsorption behavior of Tl(I) (a prevalent form of Tl in nature) on RNTD was studied as a function of solution pH, temperature, and ion strength. Adsorption isotherms, kinetics, and thermodynamics for Tl(I) were also investigated. The adsorption of Tl(I) on RNTD started at very low pH values and increased abruptly, then maintained at high level with increasing pH >9. Uptake of Tl(I) was very fast on RNTD in the first 15 min then slowed down. The adsorption of Tl(I) on RNTD was an exothermic process; and the adsorption isotherm of Tl(I) followed the Langmuir model, with the maximum adsorption amount of 51.2 mg/g at room temperature. The kinetics of Tl adsorption can be described by a pseudo-second-order equation. FT-IR spectroscopy revealed that -OH and -TiOO-H play an important role in the adsorption. All these results indicate that RNTD has a fast adsorption rate and excellent adsorption amount for Tl(I), which can thus alter the transport, bioavailability and fate of Tl(I) in aqueous environment

Forecasting the Energy and Economic Benefits of Photovoltaic Technology in China’s Rural Areas

In recent years, with the rapid development of China’s economy, China’s energy demand has also been growing rapidly. Promoting the use of renewable energy in China has become an urgent need. This study evaluates the potential of solar photovoltaic (PV) power generation on the roofs of residential buildings in rural areas of mainland China and calculates the area that can used for generating energy, the installed capacity, and the power generation, and conducts a comprehensive analysis of the economic benefits of investing in the construction of distributed PV systems in various provinces. The findings unveiled in this study indicate that China still has more than 6.4 billion m2 of rural construction area available for the installation of PV modules. If this is all used for solar power generation, the annual power generation can reach up to 1.55 times the electricity consumption of urban and rural residents for the whole society. Through a comprehensive evaluation of energy efficiency and economic benefits, the Chinese mainland can be divided into three types of resource areas. The three types of resource areas have their own advantages and disadvantages. According to their own characteristics and advantages, we can reasonably formulate relevant policies to accelerate the development of PV system application in rural areas

Study of the Application Characteristics of Photovoltaic-Thermoelectric Radiant Windows

Through experiments and numerical simulation, this paper studies the related performance of a photovoltaic thermoelectric radiation cooling window structure, verifies the accuracy of the established solar thermoelectric radiation window calculation model, and analyzes the cooling performance of different parameters of thermoelectric sheet, radiation plate, and photovoltaic panel. On the basis of considering the relationship between the power generation and power consumption of the structure, the numerical calculation results show that the solar thermoelectric radiation window with non-transparent photovoltaic module (NTPV) has a total cooling capacity of 50.2 kWh, power consumption of 71.8 kWh, and power generation of 83.9 kWh from June to August. The solar thermoelectric radiation window with translucent photovoltaic module (STPV) has a total cooling capacity of 50.7 kWh, power consumption of 71.7 kWh, and power generation of 45.4 kWh from June to August. If the operation time of the thermoelectric module is limited, when the daily operation time of TEM is less than 8 h, the power generation of STPV can meet the power consumption demand of the thermoelectric radiation window from June to August

The development characteristics of the discontinuous leader under the positive switching impulse with low rate of voltage rising

Discontinuous leader development is the most important discharge process under the application of the switching impulse voltage with the low rate of voltage rising, which is of great significance to study the external insulation characteristics of ultra-high voltage (UHV) large scale air gap. Based on the CMOS high-speed camera, a discharge test with different operating impulse voltage is carried out by constructing a comprehensive observation platform of rod-plate air gap discharge, and a clear discontinuous leader development process picture is captured. Moreover, the leader current, injection charge and leader channel unit length charge, and their characteristics of the change trend are also obtained. Further analysis based on the experimental results shows that the discontinuous leader development under the action of the impulse voltage with low rate of voltage rising has two different laws. Finally, this paper uses the thermodynamic equation, combined with the test results, the channel temperature changes in the discontinuous leader development stagnation stage were calculated. The results show that the leader channel temperature is still greater than 1500 K in the hundreds of microsecond time scales in the leader stagnation stage, and the subsequent leader can continue to develop on the original leader channel

Performance investigation on DCSFCL considering different magnetic materials

In order to protect high voltage direct current (HVDC) system from destructive consequences caused by fault current, a novel concept of HVDC system fault current limiter (DCSFCL) was proposed previously. Since DCSFCL is based on saturable core reactor theory, iron core becomes the key to the final performance of it. Therefore, three typical kinds of soft magnetic materials were chosen to find out their impact on performances of DCSFCL. Different characteristics of materials were compared and their theoretical deductions were carried out, too. In the meanwhile, 3D models applying those three materials were built separately and finite element analysis simulations were performed to compare these results and further verify the assumptions. It turns out that materials with large saturation flux density value Bs like silicon steel and short demagnetization time like ferrite might be the best choice for DCSFCL, which can be a future research direction of magnetic materials