Complex electronic states in double layered ruthenates (Sr1-xCax)3Ru2O7

The magnetic ground state of (Sr$_{1-x}$Ca$_x$)$_3$Ru$_2$O$_7$ (0 $\leq x \leq$ 1) is complex, ranging from an itinerant metamagnetic state (0 $\leq x <$ 0.08), to an unusual heavy-mass, nearly ferromagnetic (FM) state (0.08 $< x <$ 0.4), and finally to an antiferromagnetic (AFM) state (0.4 $\leq x \leq$ 1). In this report we elucidate the electronic properties for these magnetic states, and show that the electronic and magnetic properties are strongly coupled in this system. The electronic ground state evolves from an AFM quasi-two-dimensional metal for $x =$ 1.0, to an Anderson localized state for $0.4 \leq x < 1.0$ (the AFM region). When the magnetic state undergoes a transition from the AFM to the nearly FM state, the electronic ground state switches to a weakly localized state induced by magnetic scattering for $0.25 \leq x < 0.4$, and then to a magnetic metallic state with the in-plane resistivity $\rho_{ab} \propto T^\alpha$ ($\alpha >$ 2) for $0.08 < x < 0.25$. The system eventually transforms into a Fermi liquid ground state when the magnetic ground state enters the itinerant metamagnetic state for $x < 0.08$. When $x$ approaches the critical composition ($x \sim$ 0.08), the Fermi liquid temperature is suppressed to zero Kelvin, and non-Fermi liquid behavior is observed. These results demonstrate the strong interplay between charge and spin degrees of freedom in the double layered ruthenates.Comment: 10 figures. To be published in Phys. Rev.

Studies of Novel Quantum Phenomena in Ruthenates

Strongly correlated oxides have been the subject of intense study in contemporary condensed matter physics, and perovskite ruthenates (Sr,Ca)n+1RunO3n+1 have become a new focus in this field. One of important characteristics of ruthenates is that both lattice and orbital degrees of freedom are active and are strongly coupled to charge and spin degrees of freedom. Such a complex interplay of multiple degrees of freedom causes the properties of ruthenates to exhibit a gigantic response to external stimuli under certain circumstances. Magnetic field, pressure, and chemical composition all have been demonstrated to be effective in inducing electronic/magnetic phase transitions in ruthenates. Therefore, ruthenates are ideal candidates for searching for novel quantum phenomena through controlling external parameters. The objective of this project is to search for novel quantum phenomena in ruthenate materials using high-quality single crystals grown by the floating-zone technique, and investigate the underlying physics. The following summarizes our accomplishments. We have focused on trilayered Sr4Ru3O10 and bilayered (Ca1-xSrx)3Ru2O7. We have succeeded in growing high-quality single crystals of these materials using the floating-zone technique and performed systematic studies on their electronic and magnetic properties through a variety of measurements, including resistivity, Hall coefficient, angle-resolved magnetoresistivity, Hall probe microscopy, and specific heat. We have also studied microscopic magnetic properties for some of these materials using neutron scattering in collaboration with Los Alamos National Laboratory. We have observed a number of unusual exotic quantum phenomena through these studies, such as an orbital selective metamagnetic transition, bulk spin valve effect, and a heavy-mass nearly ferromagnetic state with a surprisingly large Wilson ratio. Our work has also revealed underlying physics of these exotic phenomena. Exotic phenomena of correlated electron has been among central topics of contempary condensed matter physics. Ultrfast phase transitions accompanied by switching of conductivity or magnetization in stronly correlated materials are believed to be promising in developing next generation of transistors. Our work on layered ruthenates has remarkably advanced our understanding of how the exotic phenomena of correlated electrons is governed by the complex interplay between charge, spin, lattice and orbital degrees of freedom. In addition to studies on ruthenates, we have also expanded our research to the emerging field of Fe-based superconductors, focusing on the iron chalcogenide Fe1+y(Te1-xSex) superconductor system. We first studied the superconductivity of this alloy system following the discovery of superconductivity in FeSe using polycrystalline samples. Later, we successfuly grew high-quality single crystals of these materials. Using these single crystals, we have determined the magnetic structure of the parent compound Fe1+yTe, observed spin resonance of superconducting state in optimally doped samples, and established a phase diagram. Our work has produced an important impact in this burgeoning field. The PI presented an invited talk on this topic at APS March meeting in 2010. We have published 19 papers in these two areas (one in Nature materials, five in Physical Review Letters, and nine in Physical Review B) and submitted two (see the list of publications attached below)