245 research outputs found

    1,4-Bis(imidazol-1-yl)benzene–terephthalic acid (1/1)

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    In the title compound, C12H10N4·C8H6O4, 1,4-bis­(imidazol-1-yl)benzene and terephthalic acid mol­ecules are joined via strong O—H⋯N hydrogen bonds to form infinite zigzag chains. Both mol­ecules are located on crystallographic inversion centers. The O—H⋯N hydrogen-bonded chains are assembled into two-dimensional layers through weak C—H⋯O and strong π–π stacking inter­actions [centroid–centroid distance = 3.818 (2) Å], leading to the formation of a three-dimensional supra­molecular structure

    Study on the Variation of Annual Runoff and Influencing Factors in Kuye River during the Past 60 Years

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    In this study, observed runoff series from a hydro-station respectively named Wenjiachuan station in the Kuye river was manipulated for monthly annual variation analysis assisted by using nonuniformity coefficient and concentration degree(period).the cumulative filter methods was employed to detect the trend of inner-annual runoff. Based on meteorological and hydrological data of the Wenjiachuan hydrologic station from 1955 to 2015, the paper studied the variation tendency, the abrupt and periodic changes of annual runoff using the Mann-Kendall non-parametric test and accumulation anomaly curve. Double mass curve was used to estimate the impact of human activities and climate change on the runoff variation. The curve of seasonal runoff distribution for Wenjiachuan station appeared two peak patterns. The annual runoff declined markedly, the effect of climate on runoff decreased, the influence of human activities on runoff gradually increased the human activities are the primary factors leading to the reduction of annual runoff. In human activities, large-scale water and soil conservation measures and high-strength coal mining have produced significant effects on the annual runoff reduction in Kuye River

    ERCC2, ERCC1 polymorphisms and haplotypes, cooking oil fume and lung adenocarcinoma risk in Chinese non-smoking females

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    <p>Abstract</p> <p>Background</p> <p>Excision repair cross-complementing group 1 (ERCC1) and group 2 (ERCC2) proteins play important roles in the repair of DNA damage and adducts. Single nucleotide polymorphisms (SNPs) of DNA repair genes are suspected to influence the risk of lung cancer. This study aimed to investigate the association between the <it>ERCC2 </it>751, 312 and <it>ERCC1 </it>118 polymorphisms and the risk of lung adenocarcinoma in Chinese non-smoking females.</p> <p>Methods</p> <p>A hospital-based case-control study of 285 patients and 285 matched controls was conducted. Information concerning demographic and risk factors was obtained for each case and control by a trained interviewer. After informed consent was obtained, each person donated 10 ml blood for biomarker testing. Three polymorphisms were determined by polymerase chain reaction-restriction fragment length polymorphism (PCR-RFLP) method.</p> <p>Results</p> <p>This study showed that the individuals with the combined <it>ERCC2 </it>751AC/CC genotypes were at an increased risk for lung adenocarcinoma compared with those carrying the AA genotype [adjusted odds ratios (OR) 1.64, 95% confidence interval (CI) 1.06-2.52]. The stratified analysis suggested that increased risk associated with <it>ERCC2 </it>751 variant genotypes (AC/CC) was more pronounced in individuals without exposure to cooking oil fume (OR 1.98, 95%CI 1.18-3.32) and those without exposure to fuel smoke (OR 2.47, 95%CI 1.46-4.18). Haplotype analysis showed that the A-G-T and C-G-C haplotypes were associated with increased risk of lung adenocarcinoma among non-smoking females (ORs were 1.43 and 2.28, 95%CIs were 1.07-1.91 and 1.34-3.89, respectively).</p> <p>Conclusion</p> <p><it>ERCC2 </it>751 polymorphism may be a genetic risk modifier for lung adenocarcinoma in non-smoking females in China.</p

    Photoinduced oxygen release and persistent photoconductivity in ZnO nanowires

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    Photoconductivity is studied in individual ZnO nanowires. Under ultraviolet (UV) illumination, the induced photocurrents are observed to persist both in air and in vacuum. Their dependence on UV intensity in air is explained by means of photoinduced surface depletion depth decrease caused by oxygen desorption induced by photogenerated holes. The observed photoresponse is much greater in vacuum and proceeds beyond the air photoresponse at a much slower rate of increase. After reaching a maximum, it typically persists indefinitely, as long as good vacuum is maintained. Once vacuum is broken and air is let in, the photocurrent quickly decays down to the typical air-photoresponse values. The extra photoconductivity in vacuum is explained by desorption of adsorbed surface oxygen which is readily pumped out, followed by a further slower desorption of lattice oxygen, resulting in a Zn-rich surface of increased conductivity. The adsorption-desorption balance is fully recovered after the ZnO surface is exposed to air, which suggests that under UV illumination, the ZnO surface is actively "breathing" oxygen, a process that is further enhanced in nanowires by their high surface to volume ratio

    5-Benzyl-2-phenyl-6,8-dihydro-5H-1,2,4-triazolo[3,4-c][1,4]oxazin-2-ium hexa­fluoridophosphate

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    The title compound, C18H18N3O+·PF6 −, is a chiral bicyclic 1,2,4-triazolium salt which contains four rings, viz. a triazolium, a morpholine and two phenyl rings. Analysis of bond lengths shows that the N—CH—N group in the triazolium ring conforms to a typical three-center/four-electron bond (also known as the Pimentel–Rundle three-center model). The structure is completed by a disordered PF6 − counter-ion [occupancies of F atoms 0.678 (8):0.322 (8)], which inter­acts with the main mol­ecule through weak inter­molecular P—F⋯π inter­actions

    Research on online public opinion dissemination and emergency countermeasures of food safety in universities—take the rat head and duck neck incident in China as an example

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    In recent years, food safety accidents have occurred frequently in colleges and universities, and students are prone to emotional resonance with food safety. It triggered heated discussions among the whole society and gradually formed a unique online public opinion on food safety in universities. After food safety incidents broke out in universities, some universities deliberately avoided responsibility or made mistakes in handling the incidents, which will create greater risks of online public opinion. Therefore, this paper takes the “Rat Head and Duck Neck” incident at Jiangxi Institute of Technology in China as an example. The purpose is to study the dissemination of public opinion on food safety online in universities and propose emergency countermeasures. Above all, the food safety online public opinion is divided into five stages: incubation period, burst period, spreading period, recurring period and dissipation period. Then, methods such as text mining and cluster analysis were used to deeply analyze the influencing factors at each stage of the development of food safety online public opinion. And analyze the role of different subjects in the development of public opinion based on the perspective of stakeholders. Finally, this paper provides corresponding countermeasures for different stages of online public opinion on food safety in universities, which provides suggestions and references for university governance. This study found that: (1) The resonance effect of online public opinion media on food safety in universities is significant. (2) Public opinion on food safety in universities is repetitive. (3) Improper response to food safety incidents in universities can easily trigger negative secondary public opinion
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