(Acetato-κO)bis­(2,2′-bipyridyl-κ2 N,N′)copper(II)–ethyl sulfate–methyl sulfate (1/0.5/0.5)

In the title complex, [Cu(C2H3O2)(C10H8N2)2](CH3CH2OSO3)0.5(CH3OSO3)0.5, the CuII ion is bis-chelated by two 2,2′-bipyridine lignds and coordinated by an O atom of an acetate ligand in a CuN4O disorted square-pyramidal environment. In the structure, equal amounts of methyl sulfate and ethyl sulfate anions are disordered on the same crystallographic sites. The crystal structure is stabilized by weak inter­molecular C—H⋯O inter­actions

Large-field inflation and the cosmological collider

Large-field inflation is a major class of inflation models featuring a near- or super-Planckian excursion of the inflaton field. We point out that the large excursion generically introduces significant scale dependence to spectator fields through inflaton couplings, which in turn induces characteristic distortions to the oscillatory shape dependence in the primordial bispectrum mediated by a spectator field. This so-called cosmological collider signal can thus be a useful indicator of large field excursions. We show an explicit example with signals from the "tower states"motivated by the swampland distance conjecture