Phase Composition and Microstructure of Crystallization Products of Molten Bi2O3 . GeO2 under Various Cooling Conditions : научное издание

Статья из журнала. Научное издание.-We have studied the influence of melt heat treatment, initial cooling temperature (t(cooling0)), and cooling schedule for a melt containing 50 mol % Bi2O3 and 50 mol % GeO2 on the phase composition, macrostructure, and microstructure of crystallizing sol Abstract—: We have studied the influence of melt heat treatment, initial cooling temperature (tcooling 0), and cooling schedule for a melt containing 50 mol % Bi2O3 and 50 mol % GeO2 on the phase composition, macrostructure, and microstructure of crystallAbstract—: We have studied the influence of melt heat treatment, initial cooling temperature (tcooling 0), and cooling schedule for a melt containing 50 mol % Bi2O3 and 50 mol % GeO2 on the phase composition, macrostructure, and microstructure of crystal

The charge-assisted hydrogen-bonded organic framework (CAHOF) self-assembled from the conjugated acid of tetrakis(4-aminophenyl)methane and 2,6-naphthalenedisulfonate as a new class of recyclable Brønsted acid catalysts

The acid–base neutralization reaction of commercially available disodium 2,6-naphthalenedisulfonate (NDS, 2 equivalents) and the tetrahydrochloride salt of tetrakis(4-aminophenyl)methane (TAPM, 1 equivalent) in water gave a novel three-dimensional charge-assisted hydrogen-bonded framework (CAHOF, F-1). The framework F-1 was characterized by X-ray diffraction, TGA, elemental analysis, and 1H NMR spectroscopy. The framework was supported by hydrogen bonds between the sulfonate anions and the ammonium cations of NDS and protonated TAPM moieties, respectively. The CAHOF material functioned as a new type of catalytically active Brønsted acid in a series of reactions, including the ring opening of epoxides by water and alcohols. A Diels–Alder reaction between cyclopentadiene and methyl vinyl ketone was also catalyzed by F-1 in heptane. Depending on the polarity of the solvent mixture, the CAHOF F-1 could function as a purely heterogeneous catalyst or partly dissociate, providing some dissolved F-1 as the real catalyst. In all cases, the catalyst could easily be recovered and recycled. © 2020 Kuznetsova et al