Structures and Stabilities of Carbon Chain Clusters Influenced by Atomic Antimony

The C-C bond lengths of the linear magnetic neutral CnSb, CnSb+ cations and CnSb− anions are within 1.255–1.336 Å, which is typical for cumulene structures with moderately strong double-bonds. In this report, we found that the adiabatic ionization energy (IE) of CnSb decreased with n. When comparing the IE~n relationship of CnSb with that of pure Cn, we found that the latter exhibited a stair-step pattern (n ≥ 6), but the IE~n relationship of CnSb chains took the shape of a flat curve. The IEs of CnSb were lower than those of corresponding pure carbon chains. Different from pure carbon chains, the adiabatic electron affinity of CnSb does not exhibit a parity effect. There is an even-odd alternation for the incremental binding energies of the open chain CnSb (for n = 1–16) and CnSb+ (n = 1–10, when n > 10, the incremental binding energies of odd (n) chain of CnSb+ are larger than adjacent clusters). The difference in the incremental binding energies between the even and odd chains of both CnSb and pure Cn diminishes with the increase in n. The incremental binding energies for CnSb- anions do not exhibit a parity effect. For carbon chain clusters, the most favorable binding site of atomic antimony is the terminal carbon of the carbon cluster because the terminal carbon with a large spin density bonds in an unsaturated way. The C-Sb bond is a double bond with Wiberg bond index (WBI) between 1.41 and 2.13, which is obviously stronger for a carbon chain cluster with odd-number carbon atoms. The WBI of all C-C bonds was determined to be between 1.63 and 2.01, indicating the cumulene character of the carbon chain. Generally, the alteration of WBI and, in particular, the carbon chain cluster is consistent with the bond length alteration. However, the shorter C-C distance did not indicate a larger WBI. Rather than relying on the empirical comparison of bond distance, the WBI is a meaningful quantitative indicator for predicting the bonding strength in the carbon chain

A Novel Approach to Recovering Depth from Defocus

This paper proposes a novel approach to recovering depth from defocus, which is a deterministic approach in spatial domain. Two defocused gray images from the same scene are obtained by changing two parameters (image distance and focal length of camera) other than only parameter (image distance). The idea of this approach is to convert the gray images into the gradient images by Canny operator other than Sobel operator, then calculate the ratio of the area of region with large gradient value to that of the whole image region in each block for each defocused image by moment-preserving method, and recover depth from scene according to the ratio of the ratio of one gradient image to that of the other gradient image. The experimental results show that the proposed approach is more accurate and efficient than the traditional approach

Integrated Navigation Fusion Strategy of INS/UWB for Indoor Carrier Attitude Angle and Position Synchronous Tracking

In some GPS failure conditions, positioning for mobile target is difficult. This paper proposed a new method based on INS/UWB for attitude angle and position synchronous tracking of indoor carrier. Firstly, error model of INS/UWB integrated system is built, including error equation of INS and UWB. And combined filtering model of INS/UWB is researched. Simulation results show that the two subsystems are complementary. Secondly, integrated navigation data fusion strategy of INS/UWB based on Kalman filtering theory is proposed. Simulation results show that FAKF method is better than the conventional Kalman filtering. Finally, an indoor experiment platform is established to verify the integrated navigation theory of INS/UWB, which is geared to the needs of coal mine working environment. Static and dynamic positioning results show that the INS/UWB integrated navigation system is stable and real-time, positioning precision meets the requirements of working condition and is better than any independent subsystem

Second harmonic and cascaded third harmonic generation in generalized quasi-periodic poled lithium niobate waveguides

Lithium niobate (LN) thin film has recently emerged as an important platform for nonlinear optical investigations for its large $\chi^{(2)}$ nonlinear coefficients and ability of light localization. In this paper, we report the first fabrication of LN on insulator (LNOI) ridge waveguides with generalized quasi-periodic poled superlattices using the electric field polarization technique and microfabrication techniques. Benefiting from the abundant reciprocal vectors, we observed efficient second-harmonic and cascaded third-harmonic signals in the same device, with the normalized conversion efficiency 1735% W$^{-1}$cm$^{-2}$ and 0.41% W$^{-2}$cm$^{-4}$, respectively. This work opens a new direction of nonlinear integrated photonics based on LN thin film.Comment: 4 pages, 4 figure