Observation of room-temperature ferroelectricity in elemental Te nanowires

Ferroelectrics are essential in low-dimensional memory devices for multi-bit storage and high-density integration. A polar structure is a necessary premise for ferroelectricity, mainly existing in compounds. However, it is usually rare in elemental materials, causing a lack of spontaneous electric polarization. Here, we report an unexpected room-temperature ferroelectricity in few-chain Te nanowires. Out-of-plane ferroelectric loops and domain reversal are observed by piezoresponse force microscopy. Through density functional theory, we attribute the ferroelectricity to the ion-displacement created by the interlayer interaction between lone pair electrons. Ferroelectric polarization can induce a strong field effect on the transport along the Te chain, supporting a self-gated field-effect transistor. It enables a nonvolatile memory with high in-plane mobility, zero supply voltage, multilevel resistive states, and a high on/off ratio. Our work provides new opportunities for elemental ferroelectrics with polar structures and paves a way towards applications such as low-power dissipation electronics and computing-in-memory devices

A Chinese SCA36 pedigree analysis of NOP56 expansion region based on long-read sequencing

Introduction: Spinocerebellar ataxias 36 (SCA36) is the neurodegenerative disease caused by the GGCCTG Hexanucleotide repeat expansions in NOP56, which is too long to sequence using short-read sequencing. Single molecule real time (SMRT) sequencing can sequence across disease-causing repeat expansion. We report the first long-read sequencing data across the expansion region in SCA36.Methods: We collected and described the clinical manifestations and imaging features of Han Chinese pedigree with three generations of SCA36. Also, we focused on structural variation analysis for intron 1 of the NOP56 gene by SMRT sequencing in the assembled genome.Results: The main clinical features of this pedigree are late-onset ataxia symptoms, with a presymptomatic presence of affective and sleep disorders. In addition, the results of SMRT sequencing showed the specific repeat expansion region and demonstrated that the region was not composed of single GGCCTG hexanucleotides and there were random interruptions.Discussion: We extended the phenotypic spectrum of SCA36. We applied SMRT sequencing to reveal the correlation between genotype and phenotype of SCA36. Our findings indicated that long-read sequencing is well suited to characterize known repeat expansion

Potassium poisoning impact on FeCu selective catalytic reduction catalyst: Structure and mechanism

Alkali metals bring great challenges to the elimination of NOx from stationary emissions in the selective catalytic reduction (SCR) reaction. The FeCu catalyst, as an eco-friendly and high-efficiency catalyst for NOx removal possesses wide application prospects. However, the poisoning effect of potassium is not clear. Therefore, the potassium poisoning catalyst was obtained by the wet impregnation means. The XRD, H2-TPR, NH3-TPD, XPS and DRIFT technologies were performed to study the influence of K poisoning. The results indicate that potassium causes damage to Cu-O-Fe construction. Then the Cu2+ in lattice of Fe2O3 separate out from Fe2O3 and form CuO which leads to the decline of acid sites and excessive NH3 oxidation. And it finally leads to the catalyst deactivation. After K poisoning, NO2, monodentate nitrates and nitrites cannot generate. Only bidentate nitrates can generate and then react with NH3 species on the Lewis acid sites to produce H2O and N2. Hence, the reaction rate has a slide

An Estimation Model for Hydraulic Conductivity of Low-Permeability and Unfilled Fractured Granite in Underground Water-Sealed Storage Caverns

The permeability of rock mass is closely related to the stability and safety of underground structure, especially in underground water-sealed storage caverns. With regard to the estimation approaches in predicting the hydraulic conductivity of fractured granite in water-sealed storage caverns, there are some limitations of parameter selection leading to poor applicability. Focusing on the contribution of the water conduction fractures (WCF) to the hydraulic conductivity, we attempted to propose a novel model, the CA model, for estimating its hydraulic conductivity based on the fracture orientation index and the normal stress index by analyzing the borehole wall imaging results and borehole water-pressure test results in the site of underground water-sealed storage caverns. The results indicated that the proposed model is suitable for low-permeability and unfilled fractured granite, exhibiting good effectiveness by clarifying the relation between geomechanical parameters and hydraulic behavior. Further, the parameters upon which the proposed model is based are representative and easy to obtain, which has certain guiding significance and reference value for analyzing the permeability characteristics of similar rock masses

The relationship between internode elongation of soybean stems and spectral distribution of light in the canopy under different plant densities

The present study carried out with a field plot experiment and light environment simulation experiment in 2017 to assess the effect of spectral distribution on internode elongation in soybean canopy. Henong 60 and Heinong 48 were used as the experimental materials. The spectral distribution in the soybean canopy was studied under four planting densities 200,000(D20), 300,000(D30), 400,000(D40) and 500,000(D50) plant ha−1. Meanwhile, a pot experiment of light environment simulation with light-emitting diode (LED) was carried out to further analyze the effects of light quantity and quality on the elongation of soybean seedlings. The results showed that the intensity of PAR, blue light, red light and far-red light in soybean canopy decreased by varying degrees with density and canopy depth increasing, and the decrease of PAR and R/FR led to significant elongation of internodes and plant height in high density. The spectral intensity in the middle and base of the canopy was strongly reduced, resulting in the strongest internode elongation in the middle of soybean stem. The increase in soybean plant height was also mainly due to the internode elongation in the middle at high density. In addition, the mono-light of far-red light could promote the internode elongation, while the red light and blue light acted as inhibitors and the inhibitory effect of blue light was even greater

Coherent and Noncoherent Joint Processing of Sonar for Detection of Small Targets in Shallow Water

A coherent-noncoherent joint processing framework is proposed for active sonar to combine diversity gain and beamforming gain for detection of a small target in shallow water environments. Sonar utilizes widely-spaced arrays to sense environments and illuminate a target of interest from multiple angles. Meanwhile, it exploits spatial diversity for time-reversal focusing to suppress reverberation, mainly strong bottom reverberation. For enhancement of robustness of time-reversal focusing, an adaptive iterative strategy is utilized in the processing framework. A probing signal is firstly transmitted and echoes of a likely target are utilized as steering vectors for the second transmission. With spatial diversity, target bearing and range are estimated using a broadband signal model. Numerical simulations show that the novel sonar outperforms the traditional phased-array sonar due to benefits of spatial diversity. The effectiveness of the proposed framework has been validated by localization of a small target in at-lake experiments

Experimental Study on the Influence of Hydromechanical Boundary Conditions on Shear-Flow Coupling Characteristics of Granite Joints

The instability of jointed rock mass is usually the shear process of the rock mass along discontinuities under the influence of groundwater flow. By conducting laboratory tests and numerical experiments on the shear-flow coupling of rock joints under constant normal stiffness (CNS) and constant normal stress (CNL) boundary conditions, the influence of normal boundary conditions and seepage pressure on the shear mechanical and flow characteristics of joints were investigated. The test results were as follows: The joint shear stiffness, peak, and residual shear strength under the CNS boundary condition were predominantly larger than those under the CNL boundary condition. Overall, these parameters were positively correlated with the initial normal stress σn0. When σn0>2 MPa, the postpeak shear stress of the CNS boundary condition showed a sharp decrease, whereas that of the CNL boundary condition changed from a slowly decreasing type (σn0=4 MPa, 6 MPa) to a sharply decreasing type at σn0=8 MPa. The peak dilation rate under the CNS boundary condition at all levels of normal stress was lower than that of CNL, and the strain softening in postpeak of the latter was more remarkable. In the process of joint shear, the hydraulic aperture displayed a four-stage variation law of “steady-sudden increase-slow increase-basically stable.” Moreover, the hydraulic aperture under the CNS boundary condition was always lower than that under the CNL boundary condition. The seepage pressure increased from 0.5 MPa to 1.5 MPa, and the average hydraulic aperture in the stable stage under normal stress at all levels increased from 0.146 mm to 0.187 mm. In addition, the average peak shear stress and average shear stiffness decreased by 0.9 MPa and 0.83 GPa/m, respectively. We also established a numerical model of a real rough three-dimensional joint, compiled a calculation program for the shear-flow process of a joint under CNS boundary conditions, and visualized the flow channel inside the joint. The seepage flow bypassed the area where the joints contacted each other, forming obvious flow channels. The flow rate increased at the intersection of the flow channels

Effect of Short-Term Organic Matter Returns on Soil Organic Carbon Fractions, Phosphorus Fractions and Microbial Community in Cold Region of China

To investigate the effect of different organic matter returns on soil organic carbon (SOC) fractions, phosphorus (P) fractions and microbial communities, a pot experiment was conducted in a cold region of China for three years. There were six treatments in this study, including no rice straw return (S0), rice straw return (SR), decomposed rice straw return (DS), rice-straw-burned return (BS), rice root return (RR) and decomposed cattle manure return (DM). The results indicated that the organic matter returns had no significant effect on the rice yield after three years. The SR, DS and DM treatments significantly increased the content of the soil’s total organic carbon (TOC), light fraction organic carbon (LFOC), particulate organic carbon (POC), dissolved organic carbon (DOC) and microbial biomass carbon (MBC). The BS treatment decreased the soil MBC content. The SR, DS, BS and DM treatments significantly increased the content of the soil’s total P, NaHCO3-P, NaOH-P and residual-P. The proportion of nonlabile P (HCl-P and residual-P) was reduced by the organic matter returns. The SOC fractions were positively correlated to the soil P fractions (except HCl-P). The organic matter returns did not affect the microbial diversity but did change the microbial community composition. The dominant phyla included Proteobacteria, Firmicutes, Chloroflexi, and Bacteroidetes. Compared with the S0 treatment, the organic matter returns increased the relative abundance of Actinobacteria, Anaerolineae and Alphaproteobacteria and decreased the relative abundance of Bacteroidetes, Clostridia and Bacteroidia. The contents of MBC, DOC and NaOH-P were the main factors affecting the microbial community composition, and the soil’s P fractions had a larger influence on the microbial community than the SOC fractions. These results indicated that the incorporation of rice straw, decomposed rice straw and decomposed cattle manure might be an effective practice for maintaining soil fertility in the cold region of China

Assessing the Systematic Effects of the Concentration of Nitrogen Supplied to Dual-Root Systems of Soybean Plants on Nodulation and Nitrogen Fixation

The specific mechanisms by which nitrogen affects the nodulation and nitrogen fixation of soybean plants are unclear. Investigating the relationship between nitrogen, nodulation and nitrogen fixation can provide new insights for the rational and proper use of nitrogen fertilizer in soybean plants. In this study, we grafted soybean roots to construct a dual-root system with a single nodulated side. Experiment I was performed at the third trifoliate leaf to initial seed filling (V3-R3) growth stages (for 30 days) for long-term nitrogen supply, and Experiment II was performed at the third trifoliate leaf to fourth trifoliate leaf (V3-V4) growth stages (for 5 days) for short-term nitrogen supply. For the two experiments, a nutrient solution providing 15NH415NO3 or NH4NO3 as the nitrogen source was added to the non-nodulated side, while a nitrogen-free nutrient solution was added to the nodulated side. The concentrations of nitrogen supplied were 0 mg/L, 25 mg/L, 50 mg/L, 75 mg/L, and 100 mg/L. The results showed the following: (1) Short-term nitrogen supply systematically regulated the specific nitrogenase activity (SNA), thereby inhibiting the acetylene reduction activity (ARA). Under long-term nitrogen supply, the recovery of SNA was generally consistent across treatments, and the concentration of nitrogen supplied systematically regulated the growth of root nodules, thereby inhibiting the ARA. (2) Using the 15N tracer method, the concentration of fertilizer nitrogen was positively correlated with the amount of nitrogen redistributed to other organs. Although the percentage of nitrogen derived from the atmosphere (Ndfa%) decreased significantly with increasing concentrations of nitrogen supplied, the effect on the accumulation of nitrogen fixed by nodules (Naccumulation of nodules) was not significant. By establishing the relationships between the ARA (measured by the acetylene reduction method), Ndfa% (based on 15N calculations), and Naccumulation nodules (based on 15N calculations), it was found that the ARA reliably reflected the Ndfa% but not the Naccumulation of nodules