4,891 research outputs found
Solvent-Induced Amphiphilic Molecular Baskets: Unimolecular Reversed Micelles with Different Size, Shape, and Flexibility
Amphiphilic molecular baskets were obtained by attaching facially amphiphilic cholate groups to a covalent scaffold (calix[4]arene or 1,3,5-2,4,6-hexasubstituted benzene). In a solvent mixture consisting of mostly a nonpolar solvent (i.e., CCl4) and a polar solvent (i.e., DMSO), the hydrophilic faces of cholates turned inward to form a reversed-micelle-like conformer whose stability was strongly influenced by the number of the cholates and the topology of the scaffold. Preferential solvation of the hydrophilic faces of cholates within the molecule by the polar solvent was cooperative and gave the fundamental driving force to the conformational change. The reversed-micelle-like conformer was most stable in structures that allowed multiple cholates to form a microenvironment that could efficiently enrich the polar solvent molecules from the bulk solvent mixture
Nuclear superfluidity for antimagnetic rotation in Cd and Cd
The effect of nuclear superfluidity on antimagnetic rotation bands in
Cd and Cd are investigated by the cranked shell model with the
pairing correlations and the blocking effects treated by a particle-number
conserving method. The experimental moments of inertia and the reduced
transition values are excellently reproduced. The nuclear superfluidity is
essential to reproduce the experimental moments of inertia. The two-shears-like
mechanism for the antimagnetic rotation is investigated by examining the shears
angle, i.e., the closing of the two proton hole angular momenta, and its
sensitive dependence on the nuclear superfluidity is revealed.Comment: 14 pages, 4 figure
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