12,093 research outputs found
Hollow Gaussian Schell-model beam and its propagation
In this paper, we present a new model, hollow Gaussian-Schell model beams
(HGSMBs), to describe the practical dark hollow beams. An analytical
propagation formula for HGSMBs passing through a paraxial first-order optical
system is derived based on the theory of coherence. Based on the derived
formula, an application example showing the influence of spatial coherence on
the propagation of beams is illustrated. It is found that the beam propagating
properties of HGSMBs will be greatly affected by their spatial coherence. Our
model provides a very convenient way for analyzing the propagation properties
of partially coherent dark hollow beams.Comment: 13pages, 2 figure
Spin-Phonon Coupling in Iron Pnictide Superconductors
The magnetic moment in the parent phase of the iron-pnictide superconductors
varies with composition even when the nominal charge of iron is unchanged. We
propose the spin-lattice coupling due to the magneto-volume effect as the
primary origin of this effect, and formulate a Landau theory to describe the
dependence of the moment to the Fe-As layer separation. We then compare the
superconductive critical temperature of doped iron pnictides to the local
moment predicted by the theory, and suggest that the spin-phonon coupling may
play a role in the superconductivity of this compound
SYNTHESIS OF CYCLOBUTANE ANALOGUES
2-(3-Acetyl-2,2-dimethylcyclobutyl)acetic acid (pinonic acid) was synthesized using α-pinene as raw material and potassium permanganate as oxidant. This compound reacted with substituted aniline to produce eight kinds of derivatives with cyclobutane moiety. The yields of the cyclobutane analogues ranged from 24.9 to 78.2 %.
KEY WORDS: Cyclobutane analogues, Pinonic acid, Oxidation
Bull. Chem. Soc. Ethiop. 2009, 23(1), 135-139
Kinetic frustration and the nature of the magnetic and paramagnetic states in iron pnictides and iron chalcogenides
The iron pnictide and chalcogenide compounds are a subject of intensive
investigations due to their high temperature superconductivity.\cite{a-LaFeAsO}
They all share the same structure, but there is significant variation in their
physical properties, such as magnetic ordered moments, effective masses,
superconducting gaps and T. Many theoretical techniques have been applied
to individual compounds but no consistent description of the trends is
available \cite{np-review}. We carry out a comparative theoretical study of a
large number of iron-based compounds in both their magnetic and paramagnetic
states. We show that the nature of both states is well described by our method
and the trends in all the calculated physical properties such as the ordered
moments, effective masses and Fermi surfaces are in good agreement with
experiments across the compounds. The variation of these properties can be
traced to variations in the key structural parameters, rather than changes in
the screening of the Coulomb interactions. Our results provide a natural
explanation of the strongly Fermi surface dependent superconducting gaps
observed in experiments\cite{Ding}. We propose a specific optimization of the
crystal structure to look for higher T superconductors.Comment: 5 pages, 3 figures with a 5-page supplementary materia
Structural and magnetic phase diagram of CeFeAsO1-xFx and its relationship to high-temperature superconductivity
We use neutron scattering to study the structural and magnetic phase
transitions in the iron pnictides CeFeAsO1-xFx as the system is tuned from a
semimetal to a high-transition-temperature (high-Tc) superconductor through
Fluorine (F) doping x. In the undoped state, CeFeAsO develops a structural
lattice distortion followed by a stripe like commensurate antiferromagnetic
order with decreasing temperature. With increasing Fluorine doping, the
structural phase transition decreases gradually while the antiferromagnetic
order is suppressed before the appearance of superconductivity, resulting an
electronic phase diagram remarkably similar to that of the high-Tc copper
oxides. Comparison of the structural evolution of CeFeAsO1-xFx with other
Fe-based superconductors reveals that the effective electronic band width
decreases systematically for materials with higher Tc. The results suggest that
electron correlation effects are important for the mechanism of high-Tc
superconductivity in these Fe pnictides.Comment: 19 pages, 5 figure
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