6,698 research outputs found
Beneficial influence of nanocarbon on the aryliminopyridylnickel chloride catalyzed ethylene polymerization
A series of 1-aryliminoethylpyridine ligands (L1―L3) was synthesized by condensation of 2-acetylpyridine with 1-aminonaphthalene, 2-aminoanthracene or 1-aminopyrene, respectively. Reaction with nickel dichloride afforded the corresponding nickel (II) chloride complexes (Ni1–Ni3). All compounds were fully characterized and the molecular structures of Ni1 and Ni3 are reported. Upon activation with methylaluminoxane (MAO), all nickel complexes exhibit high activities for ethylene polymerization, producing waxes of low molecular weight and narrow polydispersity. The presence of multi-walled carbon nanotubes (MWCNTs) or few layer graphene (FLG) in the catalytic medium can lead to an increase of productivity associated to a modification of the polymer structure
Dialkylaluminium 2-imidazolylphenolates: Synthesis, characterization and ring-opening polymerization behavior towards lactides
The stoichiometric reaction of the 2-imidazolylphenols (L1–L9) with the trialkylaluminium reagents AlR₃ (R = Me, Et and iBu), afforded the corresponding dialkylaluminium 2-imidazolylphenolate complexes [R₂Al(L1–L9)] (C1–C11), which were characterized by ¹H/¹³C NMR spectroscopy and by elemental analysis. The molecular structures of the representative complexes C1, C2, C4, C6 and C11 were determined by single-crystal X-Ray diffraction, and revealed a distorted tetrahedral geometry at aluminum. These dialkylaluminium 2-imidazolylphenolates (C1–C11) could efficiently catalyze the ring-opening polymerization of lactides to afford high molecular weight polylactide, both in the presence and absence of BnOH, and as such represent rare examples of the use of bi-dentate ligation at aluminum in such lactide polymerization systems. On the basis of the polymerization results for l-lactide, d-lactide and rac-lactide, the nature of the ligands and the aluminum bound alkyls were found to significantly affect the catalytic activity as well as the properties of the resultant polylactides
Towards Understanding Astrophysical Effects of Nuclear Symmetry Energy
Determining the Equation of State (EOS) of dense neutron-rich nuclear matter
is a shared goal of both nuclear physics and astrophysics. Except possible
phase transitions, the density dependence of nuclear symmetry \esym is the most
uncertain part of the EOS of neutron-rich nucleonic matter especially at
supra-saturation densities. Much progresses have been made in recent years in
predicting the symmetry energy and understanding why it is still very uncertain
using various microscopic nuclear many-body theories and phenomenological
models. Simultaneously, significant progresses have also been made in probing
the symmetry energy in both terrestrial nuclear laboratories and astrophysical
observatories. In light of the GW170817 event as well as ongoing or planned
nuclear experiments and astrophysical observations probing the EOS of dense
neutron-rich matter, we review recent progresses and identify new challenges to
the best knowledge we have on several selected topics critical for
understanding astrophysical effects of the nuclear symmetry energy.Comment: 77 pages. Invited Review Article, EPJA (2019) in pres
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