4-Nitro­phenyl 2-chloro­benzoate

The aromatic rings in the title compound, C13H8ClNO4, enclose a dihedral angle of 39.53 (3)°. The nitro group is almost coplanar with the ring to which it is attached [dihedral angle = 4.31 (1)°]. In the crystal, molecules are connected by C-H...O hydrogen bonds into chains running along [001]. Key indicators: single-crystal X-ray study; T = 173 K; mean σ(C–C) = 0.002 A°; R factor = 0.044; wR factor = 0.105; data-to-parameter ratio = 18.9

4-(4-Nitrophenoxy)biphenyl

The two phenyl rings of the biphenyl unit of the title compound, C18H13NO3, are almost coplanar [dihedral angle 6.70 (9)°]. The nitrophenyl ring, on the other hand, is significantly twisted out of the plane of the these two rings, making dihedral angles of 68.83 (4)° with the middle ring and 62.86 (4)° with the end ring. The nitro group is twisted by 12.1 (2)° out of the plane of the phenyl ring to which it is attached. Key indicators: single-crystal X-ray study; T = 173 K; mean σ(C–C) = 0.002 A° ; R factor = 0.040; wR factor = 0.118; data-to-parameter ratio = 12.8

N-[4-(4-Nitrophenoxy)phenyl]-propionamide

The title compound, C15H14N2O4, is an important intermediate for the synthesis of thermotropic liquid crystals. The dihedral angle between the two aromatic rings is 84.29 (4)°. An N-H...O hydrogen bond connects the molecules into chains running along the b axis. In addition, the crystal packing is stabilized by weak C-H...O hydrogen bonds. Key indicators: single-crystal X-ray study; T = 173 K; mean σ(C–C) = 0.002 Å; R factor = 0.036; wR factor = 0.096; data-to-parameter ratio = 14.3

4-[(E)-({4-[(4-Amino­phen­yl)sulfon­yl]phen­yl}imino)­meth­yl]phenol ethanol monosolvate

In the title compound, C19H16N2O3S·C2H6O, the 4-hy­droxy­benzyl­idene group is oriented at dihedral angles of 73.17 (7) and 77.06 (7)° with respect to the aniline groups. The sulfonyl group make dihedral angles of 44.89 (13) and 59.16 (12)° with the adjacent aniline groups. In the crystal, a two-dimensional polymeric network parallel to (010) is formed by N—H⋯O, O—H⋯N and O—H⋯O hydrogen bonds. There also exist π–π inter­actions with a distance of 3.5976 (18) Å between the centroids of hy­droxy­phenyl rings

4,4′-[4,4′-(Perfluoro­propane-2,2-di­yl)bis­(4,1-phenyl­eneoxy)]dianiline

In the title compound, C27H20F6N2O2, the dihedral angles between the planes of the aromatic rings connected by the ether O atoms are 84.13 (8) and 75.06 (9)°. The crystal structure is stabilized by N—H⋯O and N—H⋯F hydrogen bonds

4-Nitro­phenyl 2-methyl­benzoate

The title compound, C14H11NO4, crystallizes with two mol­ecules in the asymmetric unit. The major conformational difference between these two mol­ecules is the dihedral angle between the aromatic rings, namely 36.99 (5) and 55.04 (5)°. The nitro groups are coplanar with the phenyl rings to which they are attached, the O—N—C—C torsion angles being −1.9 (3) and 1.0 (3)° in the two mol­ecules

1,1,1,3,3,3-Hexafluoro-2,2-bis­[4-(4-nitro­phen­oxy)phen­yl]propane

In the title compound, C27H16F6N2O6, the nitro groups are almost coplanar with the aromatic rings to which they are attached [dihedral angles = 3.5 (5) and 6.2 (3)°]. The dihedral angles between adjacent aromatic rings are 78.07 (8) and 71.11 (8)° for nitro­phen­yl/phenyl and 69.50 (8)° for phen­yl/phenyl. An inter­molecular C—H⋯π inter­action seems to be effective in the stabilization of the structure

1,10-Bis(4-nitro­phen­oxy)deca­ne

The title compound, C22H28N2O6, crystallizes with four half-mol­ecules in the asymmetric unit: each mol­ecule is located about a crystallographic inversion centre. The central methyl­ene groups of two mol­ecules are disordered over two sets of equally occupied sites. The crystal packing is characterized by sheets of mol­ecules parallel to (14)

1,4-Bis(4-amino­phen­oxy)benzene

The title compound, C18H16N2O2, is a precusor for the synthesis of polyimides. The mol­ecule is located on a crystallographic inversion center and the terminal amino­phen­oxy rings are almost perpendicular to the central benzene ring with a dihedral angle of 85.40 (4)°. The mol­ecular conformation is stabilized by N—H⋯O and N—H⋯N inter­molecular hydrogen-bonding inter­actions